首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   5567篇
  免费   1008篇
  国内免费   562篇
化学   3624篇
晶体学   54篇
力学   247篇
综合类   30篇
数学   743篇
物理学   2439篇
  2024年   11篇
  2023年   126篇
  2022年   130篇
  2021年   186篇
  2020年   224篇
  2019年   189篇
  2018年   178篇
  2017年   170篇
  2016年   282篇
  2015年   236篇
  2014年   304篇
  2013年   374篇
  2012年   472篇
  2011年   546篇
  2010年   331篇
  2009年   329篇
  2008年   355篇
  2007年   329篇
  2006年   315篇
  2005年   260篇
  2004年   193篇
  2003年   168篇
  2002年   194篇
  2001年   150篇
  2000年   125篇
  1999年   156篇
  1998年   128篇
  1997年   111篇
  1996年   106篇
  1995年   73篇
  1994年   55篇
  1993年   53篇
  1992年   47篇
  1991年   59篇
  1990年   32篇
  1989年   28篇
  1988年   22篇
  1987年   18篇
  1986年   23篇
  1985年   17篇
  1984年   5篇
  1983年   5篇
  1982年   6篇
  1981年   6篇
  1980年   1篇
  1979年   2篇
  1978年   4篇
  1977年   1篇
  1976年   1篇
  1957年   1篇
排序方式: 共有7137条查询结果,搜索用时 562 毫秒
941.
Hou  Gaoyuan  Zhao  Sishun  Peng  Liyuan  Fang  Zhiqiang  Isogai  Akira 《Cellulose (London, England)》2022,29(13):7365-7376
Cellulose - A bleached softwood kraft pulp was phosphorylated with (NH4)2HPO4 and urea at 150 ℃ for 0‒40 min, and the structures and properties of the resulting...  相似文献   
942.
943.
Han  Jing  Sun  Youhong  Guo  Wei  Deng  Sunhua  Hou  Chuanbin  Qu  Lili  Li  Qiang 《Journal of Thermal Analysis and Calorimetry》2019,135(4):2287-2296
Journal of Thermal Analysis and Calorimetry - In this study, the non-isothermal pyrolysis method was used to investigate the pyrolysis characteristics of oil shale from four areas: namely Nongan,...  相似文献   
944.
The N–N bond is present in many important organic compounds, such as hydrazines, pyrazoles, azos, etc. Many methods based on transition metal catalyzed N–N coupling or functionalization of hydrazine have been reported for the synthesis of N–N containing organic compounds. In recent years, electrochemical dehydrogenative N–H/N–H coupling has become a powerful tool for the construction of N–N bearing organic compounds. The electrochemical methods employ electrons as traceless redox reagents instead of chemicals and produce hydrogen as the only byproduct. In this review, we summarize the recent advances in the electrochemical dehydrogenative N–H/N–H coupling reactions with focus on the mechanistic insights and synthetic applications of these transformations.  相似文献   
945.
A sensitive, rapid and novel measurement method for cytokeratin 19 fragment (CYFRA 21–1) in human serum by magnetic particle-based time-resolved fluoroimmunoassay (TRFIA) is described. Built on a sandwich-type immunoassay format, analytes in samples were captured by one monoclonal antibody coating onto the surface of magnetic beads and “sandwiched” by another monoclonal antibody labeled with europium chelates. The coefficient variations of the method were lower than 7 %, and the recoveries were in the range of 90–110 % for serum samples. The lower limit of quantitation of the present method for CYFRA 21–1 was 0.78 ng/ml. The correlation coefficient of CYFRA 21–1 values obtained by our novel TRFIA and CLIA was 0.980. The present novel TRFIA demonstrated high sensitivity, wider effective detection range and excellent reproducibility for determination of CYFRA 21–1 can be useful for early screening and prognosis evaluation of patients with non-small cell lung cancer.  相似文献   
946.
Xiao  Y. -H.  Wu  H. -Y.  Sun  C.  Hou  J. -L. 《Journal of Structural Chemistry》2022,63(4):647-657
Journal of Structural Chemistry - The self-assembly reaction of the bis-Schiff base N,N′-bis(4-Bromosalicylidene)-1,3-pentanediamine (H2L) with nickel chloride and sodium azide in methanol...  相似文献   
947.
Semiconductor metal oxides (SMO)-based gas-sensing materials suffer from insufficient detection of a specific target gas. Reliable selectivity, high sensitivity, and rapid response–recovery times under various working conditions are the main requirements for optimal gas sensors. Chemical warfare agents (CWA) such as sarin are fatal inhibitors of acetylcholinesterase in the nerve system. So, sensing materials with high sensitivity and selectivity toward CWA are urgently needed. Herein, micro-nano octahedral Co3O4 functionalized with hexafluoroisopropanol (HFIP) were deposited on a layer of reduced graphene oxide (rGO) as a double-layer sensing materials. The Co3O4 micro-nano octahedra were synthesized by direct growth from electrospun fiber templates calcined in ambient air. The double-layer rGO/Co3O4-HFIP sensing materials presented high selectivity toward DMMP (sarin agent simulant, dimethyl methyl phosphonate) versus rGO/Co3O4 and Co3O4 sensors after the exposure to various gases owing to hydrogen bonding between the DMMP molecules and Co3O4-HFIP. The rGO/Co3O4-HFIP sensors showed high stability with a response signal around 11.8 toward 0.5 ppm DMMP at 125 °C, and more than 75 % of the initial response was maintained under a saturated humid environment (85 % relative humidity). These results prove that these double-layer inorganic–organic composite sensing materials are excellent candidates to serve as optimal gas-sensing materials.  相似文献   
948.
The exploration of anode materials with a high degree of electrochemical utilization for Li-ion batteries (LIBs) still remains a huge challenge despite pioneering breakthroughs. Rational engineering of electrode structures/components by facile strategies would offer infinite possibilities for the development of LIBs. In this study, one-dimensional ultralong nanohybrids of ultrafine NiCoO2 nanoparticles dispersed in situ in and/or on the surface of amorphous N-doped carbon nanofibers (NCO@ANCNFs) were fabricated by a bottom-up electrospinning protocol. By virtue of synergistic structural/component features, the obtained ultralong NCO@ANCNFs with low NCO loading (≈33.6 wt %) show highly efficient Li+ storage performance with high reversible capacity, high rate capability, and long cycle life. The unusual reversible crystalline transformation during cycling was analyzed. Quantitative analysis revealed that the pseudocapacitive contribution mainly accounts for the superior lithium storage of the NCO@ANCNFs. Besides, the ability of the hybrid anode to deliver competitive Li-storage properties even without conductive carbon greatly enhances its commercial applicability. An NCO@ANCNFs//LiNi0.8Co0.15Al0.05O2 full battery was assembled and exhibited striking electrochemical properties. This contribution offers a scalable methodology to fabricate highly efficient hybrid anodes for advanced next-generation LIBs.  相似文献   
949.
The alkylative carboxylation of allenamide catalyzed by an N‐heterocyclic carbene (NHC)–copper(I) complex [(IPr)CuCl] with CO2 and dialkylzinc reagents was investigated. The reaction of allenamides with dialkylzinc reagents (1.5 equiv) and CO2 (1 atm.) proceeded smoothly in the presence of a catalytic quantity of [(IPr)CuCl] to afford (Z)‐α,β‐dehydro‐β‐amino acid esters in good yields. The reaction is regioselective, with the alkyl group introduced onto the less hindered γ‐carbon, and the carboxyl group introduced onto the β‐carbon atom of the allenamides. The first step of the reaction was alkylative zincation of the allenamides to give an alkenylzinc intermediate followed by nucleophilic addition to CO2. A variety of cyclic and acyclic allenamides were found to be applicable to this transformation. Dialkylzinc reagents bearing β‐hydrogen atoms, such as Et2Zn or Bu2Zn, also gave the corresponding alkylative carboxylation products without β‐hydride elimination. The present methodology provides an easy route to alkyl‐substituted α,β‐dehydro‐β‐amino acid ester derivatives under mild reaction conditions with high regio‐ and stereoselectivtiy.  相似文献   
950.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号