首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   24404篇
  免费   4148篇
  国内免费   2505篇
化学   16406篇
晶体学   286篇
力学   1653篇
综合类   201篇
数学   2930篇
物理学   9581篇
  2024年   90篇
  2023年   533篇
  2022年   900篇
  2021年   906篇
  2020年   1049篇
  2019年   935篇
  2018年   857篇
  2017年   791篇
  2016年   1191篇
  2015年   1155篇
  2014年   1391篇
  2013年   1758篇
  2012年   2031篇
  2011年   2211篇
  2010年   1452篇
  2009年   1309篇
  2008年   1545篇
  2007年   1330篇
  2006年   1277篇
  2005年   1013篇
  2004年   762篇
  2003年   680篇
  2002年   641篇
  2001年   519篇
  2000年   488篇
  1999年   525篇
  1998年   469篇
  1997年   439篇
  1996年   463篇
  1995年   351篇
  1994年   311篇
  1993年   269篇
  1992年   243篇
  1991年   216篇
  1990年   198篇
  1989年   143篇
  1988年   123篇
  1987年   91篇
  1986年   96篇
  1985年   70篇
  1984年   45篇
  1983年   35篇
  1982年   39篇
  1981年   24篇
  1980年   18篇
  1979年   12篇
  1978年   6篇
  1975年   6篇
  1970年   12篇
  1937年   5篇
排序方式: 共有10000条查询结果,搜索用时 531 毫秒
81.
Previous researchers have designed shared control schemes with a view to minimising the likelihood that participants will conspire to perform an unauthorised act. But, human nature being what it is, systems inevitably fail; so shared control schemes should also be designed so that the police can identify conspirators after the fact. This requirement leads us to search for schemes with sparse access structures. We show how this can be done using ideas from coding theory. In particular, secret sharing schemes based on geometric codes whose dual [n,k,d] codes have d and n as their only nonzero weights are suitable. We determine their access structures and analyse their properties. We have found almost all of them, and established some relations among codes, designs and secret-sharing schemes.  相似文献   
82.
High-level ab initio calculations are carried out to study the relative stability of the two hydrogen bonded structures of water-hydrogen sulfide complex, one with water as the proton donor (A) and the other with hydrogen sulfide as the proton donor (B). The results show that structure A is considerably more stable than B at the correlated level, which is in contrast with previous results obtained from Hartree-Fock calculations.  相似文献   
83.
In this paper, a construction of optimal constant composition codes is developed, and used to derive some series of new optimal constant composition codes meeting the upper bound given by [13].  相似文献   
84.
Using X-ray photoemission measurements, we have determined the attenuation length of C 1s photoelectrons in C60 film to be 21.5 Å with the incident photon energy of Mg Kα radiation. The inelastic mean free path calculated with the TPP-2M algorithm coincides fairly well with the experimentally determined attenuation length, indicating the validity of the algorithm to fullerene and fullerides. The inelastic mean free paths for some fullerides, i.e. K3C60, K6C60, Ba4C60, Sm2.75C60 and Sm6C60 are calculated to help the quantitative analyses of the photoemission spectra for these compounds.  相似文献   
85.
For approximate wave functions, we prove the theorem that there is a one‐to‐one correspondence between the constraints of normalization and of the Fermi–Coulomb and Coulomb hole charge sum rules at each electron position. This correspondence is surprising in light of the fact that normalization depends on the probability of finding an electron at some position. In contrast, the Fermi–Coulomb hole sum rule depends on the probability of two electrons staying apart because of correlations due to the Pauli exclusion principle and Coulomb repulsion, while the Coulomb hole sum rule depends on Coulomb repulsion. We demonstrate the theorem for the ground state of the He atom by the use of two different approximate wave functions that are functionals rather than functions. The first of these wave function functionals is constructed to satisfy the constraint of normalization, and the second that of the Coulomb hole sum rule for each electron position. Each is then shown to satisfy the other corresponding sum rule. The significance of the theorem for the construction of approximate “exchange‐correlation” and “correlation” energy functionals of density functional theory is also discussed. © 2006 Wiley Periodicals, Inc. Int J Quantum Chem, 2007  相似文献   
86.
BRD96N光调制吸收增强现象的实验研究   总被引:1,自引:0,他引:1       下载免费PDF全文
杨文正  侯洵  陈烽  杨青 《物理学报》2004,53(1):296-300
通过光谱响应特性实验和记录/读出图像实验,研究了基因变异型细菌视紫红质(BRD96N)分子膜对单色光的光调制特性.发现BRD96N分子膜在550nm—600nm范围内对调制光有吸收增强的现象,且对此范围内不同波长的单色光其调制程度有差异.利用曲线拟和方法发现550nm—600nm吸收增强的变化过程分为快过程和慢过程,其对应的时间常数分别为30s和5min.利用强度调制器的吸收强度与图像灰度之间的关系,分析了560nm—600nm范围内出现图像反转的实验现象. 关键词: 细菌视紫红质D96N分子膜 光谱响应 吸收增强现象 图像反转现象  相似文献   
87.
We present a semimonolithic frequency-doubler from 1080 to 540 nm with 80% doubling efficiency and up to 849-mW output power of green light.  相似文献   
88.
ZrO2 nanoparticles was uniformly co-deposited into a nickel matrix by electroplating of nickel from a Watts bath containing particles in suspension which were monodispersed with dispersant under DC electrodeposition condition. It was found that morphology, orientation and hardness of the nanocomposite coatings with monodispersed ZrO2 nanoparticles had lots of difference from the nanocomposite coatings with agglomerated ZrO2 nanoparticles and pure nickel coatings. Especially, the result of hardness showed that only a very low volume percent (less than 1 wt.%) of monodispered ZrO2 nanoparticles in Ni-ZrO2 nanocomposite coatings would result in higher hardness of the coatings. The hardness of Ni-ZrO2 nanocomposite coatings with monodispersed and agglomerated ZrO2 nanoparticles were 529 and 393 HV, respectively. The hardness value of the former composite coatings was over 1.3 times higher than that of the later. All these composite coatings were two-three times higher than that of pure nickel plating (207 HV) prepared under the same condition. The strengthening mechanisms of the Ni-ZrO2 nanocomposite coatings based on a combination of grain refinement strengthening from nickel matrix grain refining and dispersion strengthening from dispersion state of ZrO2 nanoparticles in the coatings.  相似文献   
89.
For vertical-cavity surface-emitting lasers (VCSELs) with polarization-rotated feedback, there exist several synchronization types such as synchronizations between total powers and synchronizations between separate polarization modes. Based on the two-mode rate equations, we study and compare numerically the performances of different synchronization types. Our results show that three synchronization types exhibit good performances when their synchronization conditions are satisfied. They are the complete synchronization between total powers, complete synchronization between x-polarized modes, and generalized synchronization between x-polarized and y-polarized modes. The former two types are sensitive to the injection rate and spontaneous emission, while the third type is contrary. Synchronization type with the best performance may switch from one to another, with changing of injection rate and spontaneous emission factor.  相似文献   
90.
Seventeen unsymmetrical curcumin derivatives were synthesized in good yield and purity by a facile solid phase synthesis strategy.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号