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61.
In the first part of this paper we show that the Castelnuovo-Mumford regularity of a monomial ideal is bounded above by its arithmetic degree. The second part gives upper bounds for the Castelnuovo-Mumford regularity and the arithmetic degree of a monomial ideal in terms of the degrees of its generators. These bounds can be formulated for an arbitrary homogeneous ideal in terms of any Gröbner basis. 相似文献
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Le Tuan Hoa 《Mathematische Nachrichten》1991,154(1):183-188
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Dian Kharismadewi Yuvaraj Haldorai Van Hoa Nguyen Dirk Tuma 《Composite Interfaces》2016,23(7):719-739
The use of a biocompatible and thermoresponsive polymer, poly(2-hydroxyethyl methacrylate) (PHEMA) grafted onto the surface of graphene oxide (GO) as an adsorbent for the removal of a cationic dye (methylene blue [MB]) from an aqueous solution is examined in this work. GO–PHEMA forms a hydrogel in water thus overcoming the problem faced by carbon-based adsorbent materials during post-treatment (i.e., separation of adsorbent from the aqueous phase). The GO–PHEMA composite was synthesized using a green approach through dispersion polymerization in supercritical CO2. The successful preparation of this composite was confirmed by a series of characterization techniques. The adsorption behavior of the composite toward MB such as the effect of the adsorbent dosage, pH, contact time, dye concentration, and recyclability were observed. In addition, the adsorption isotherm, kinetics and thermodynamics were investigated. According to the experimental data, the adsorption parameters were found to fit well into the Freundlich adsorption isotherm with a correlation coefficient of 0.975 and a maximum predicted adsorption capacity of 39.41 mg g?1 at 25 °C. The adsorption kinetics studies showed that the adsorption behavior followed a pseudo-second-order reaction. On the other hand, the thermodynamics studies showed that the adsorption of MB on GO–PHEMA composite followed spontaneous and endothermic adsorption process with an efficient adsorption temperature at 45 °C. The experimental results also showed that the GO–PHEMA composite could remove 99.8% of the dye in 45 min. Therefore, GO–PHEMA composite is a favorable green adsorbent for environmental applications. 相似文献
66.
A light-controlled reversible binding switch based on photochromic 3H-naphtho[2,1-b]pyran is under development for studying cellular oscillatory calcium signals. The binding affinities of the closed and open forms of substituted naphthopyran 1 for Ca(2+), Mg(2+), and Sr(2+) in buffer were determined. The photochemically ring-opened form of the receptor exhibited increased affinity compared to the thermally stable closed form of the receptor. The binding affinity difference for Ca(2+) was approximately 77-fold at pH 7.6. 相似文献
67.
Let M be a finitely generated module of dimension d and depth t over a Noetherian local ring (A, \({\mathfrak{m}}\)) and I an \({\mathfrak{m}}\)-primary ideal. In the main result it is shown that the last t Hilbert coefficients \({e_{d-t+1}(I,M),\ldots, e_{d}(I,M)}\) are bounded below and above in terms of the first d ? t + 1 Hilbert coefficients \({e_{0}(I,M),\ldots,e_{d-t}(I,M)}\) and d. 相似文献
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Thuy Bui Thi Phuong My Tran Thi Ai Hai Nguyen Thi Thanh Loan Huynh Thi Phuong Hieu Le Trung Hoa Tran Thai Bui Thanh Q. Tuong Ho Nhat Thuy Nguyen Thi Thu Dung Doan Kim Van Tat Pham Quy Phan Tu Nhung Nguyen Thi Ai 《Structural chemistry》2021,32(1):135-148
Structural Chemistry - Rice, well known as the most important staple food source worldwide, is highly susceptible to many infectious diseases, especially rice sheath blight caused by fungus... 相似文献
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Can Tetrylone Act in a Similar Fashion to Tetrylene in Ni(CO)2 Complexes? A Theoretical Study based on a Comparison using DFT Calculations 下载免费PDF全文
Thi Ai Nhung Nguyen Duc Sy Tran Thi Phuong Loan Huynh Thi Hoa Le Tuan Quang Duong Tien Trung Nguyen Thanh Cong Vo Van Tat Pham Tan Hiep Dang 《无机化学与普通化学杂志》2017,643(13):826-838
A comparison was made to investigate the structures and bonding of nickel complex that carry tetrylone and tetrylene ligands [(CO)2Ni‐{E(PH3)2}] ( Ni1E ) and [(CO)2Ni‐{NHEMe}] ( Ni2E ) (E = C to Pb) using quantum chemical calculations at the BP86 level with various basis sets (SVP, TZVPP, TZ2P+). The nature of the Ni–E bonds was analyzed with charge‐ and energy decomposition methods. The structures of tetrylone complexes Ni1E exhibit an interesting trend with the ligands E(PH3)2 are bonded in a tilted orientation relative to the fragment Ni(CO)2. In contrast, the calculated equilibrium structures of complexes Ni2E exhibit the NHEMe ligands (E = C to Sn) bonded in a head‐on way to the Ni(CO)2 fragment, while the bending angle gives the strongest side‐on bonded ligand NHPbMe when E = Pb. The interesting trend of the bond dissociation energy (BDE) is observed for the tetrylone, which has the same trend BDEs compared with tetrylene complexes. The EDA‐NOCV results indicate that the tetrylone ligands {E(PH3)2} in complexes are similar to the tetrylene ligands NHEMe as strong σ‐donors and weak π‐acceptors. The BDEs calculated for the Ni–E bonds in Ni1E and Ni2E show that the effect of bulky ligands may obscure the intrinsic Ni–E bond strength. The bonding analysis shows that the tetrylone ligands in Ni1E may act in a similar fashion to the tetrylene ligands in Ni2E . All complexes Ni1E and Ni2E are suitable targets for synthesis. 相似文献