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31.
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Kim GN Kim EJ Son D Bacala A Imlay R Kirk P McNeil RR Metcalf W Cheng CP Mao ZP Yan Y Xu YT Zhu YC Abashian A Gotow K Kajino F Low E Naito F Piilonen L Childers R Darden C Lusin S Rosenfeld C Wilson S Frautschi M Kagan H Kass R Trahern CG Ko W Lander RL Maeshima K Malchow RL Higashi JR Kurihara Y Maki A Nozaki T Omori T Perez P Sagawa H Sakai Y Sugimoto Y Takaiwa Y Terada S Tsuchiya K Poling R Green J Park IH Sakamoto S Sannes F Schnetzer S Stone R Trentalange S Zimmerman D Miyano K Miyata H 《Physical review letters》1988,61(8):911-914
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Geoffrey B Edwards Kaoru Yamanouchi Kozo Kuchitsu Masaaki Sugie Harutoshi Takeo Chi Matsumura Keiichiro Ogawa Yoshito Takeuchi 《Journal of Molecular Spectroscopy》1985,111(2):301-319
The microwave spectrum of 1-pyrroline has been measured from 8 to 48 GHz. The transitions have been assigned to those of the ground state and the four lowest excited states of the ring-puckering vibration of monomer, which is a five-membered ring molecule with one CN double bond. The trimer, which exists in the liquid phase, has not been detected in the gas phase. The geometrical structure of the monomer has been estimated by an ab initio calculation and the trimer by a molecular mechanics calculation. The former is consistent with the experimental rotational constants. A gas-phase infrared spectrum has also been measured, and the ring-puckering potential has been determined by an analysis of the combination bands of the ring-puckering mode and the ring-stretching modes. The potential is described using a puckering coordinate, z, as V(z) = az2 + bz4, where and ; these values are intermediate of the corresponding values for cyclopentene and 1-pyrazoline. The nuclear quadrupole coupling constants, χaa = ?4.39(10), χbb = 1.04(10), and χcc = 3.35(10) MHz, have been determined by an analysis of well-resolved hyperfine splittings. These constants have been reproduced by an ab initio calculation with a 4-31G(N1) basis set. 相似文献
36.
Osamu Kido Mami Kurumada Katsuya Kamitsuji Toshiaki Tanigaki Takeshi Sato Yuki Kimura Hitoshi Suzuki Yoshio Saito Chihiro Kaito 《Physica E: Low-dimensional Systems and Nanostructures》2006,31(2):169-173
The synthesis of Al–Cr single quasicrystal (QC) nanoparticles of the decagonal phase was achieved by introducing an advanced gas flow evaporation method. By obtaining successive electron diffraction patterns for single-QC nanoparticles, the phase transformation temperature of a single-QC nanoparticle was determined to be 700 °C. It was also determined that part of the QC nanoparticle decomposed into hex-Al8Cr5 and Al during the phase transformation. Since the grain growth did not occur during the phase transformation in the present experiment, the inherent phase transformation temperature could be measured. 相似文献
37.
Hitoshi Osawa Toshiaki IwazumiHiroko Tokoro Shin-ichi OhkoshiKazuhito Hashimoto Hironobu ShojiEiju Hirai Tetsuya NakamuraSusumu Nanao Yasuhito Isozumi 《Solid State Communications》2003,125(5):237-241
The thermal phase transition of RbMnFe(CN)6 has been observed by Mn and Fe 3p-1s X-ray emission spectroscopy (XES) and 1s X-ray absorption spectroscopy (XAS). The thermal variations of the spin states and the valences of Mn and Fe were determined to be Mn2+(S=5/2)-NC-Fe3+(S=1/2) for the high-temperature (HT) phase and Mn3+(S=2)-NC-Fe2+(S=0) for the low-temperature (LT) phase. These transitions are thus caused by charge transfer between Mn and Fe. The temperature dependences of Mn and Fe 3p-1s XES and 1s XAS were observed as the composition of the spectra of the HT and LT phases. The ratios of the HT component in each spectrum show good agreement with the thermal transition curves observed with magnetic susceptibility measurements. 相似文献
38.
Qixin Guo Mitsuhiro NishioHiroshi Ogawa Akira Yoshida 《Solid State Communications》2003,126(11):601-604
Temperature dependence of optical reflectance spectra in vacuum ultraviolet region for aluminum nitride has been measured on high-quality single crystal with synchrotron radiation. The dominant structure due to the interband transition is observed at photon energy around 7.7 eV. With decreasing temperature, the energy position of the dominant structure in the reflectance spectra shifts towards higher energy. The experimental data has been fitted to the Bose-Einstein expression and the obtained parameter related to the strength of the electron-phonon interactions is much smaller than that for the peak at 6.2 eV, suggesting that the higher-lying interband transition energy decreases more slowly with increasing temperature in aluminum nitride (AlN). 相似文献
39.
T. Idehara K. Yoshida N. Nishida I. Ogawa M. L. Pereyaslavets T. Tatsukawa 《International Journal of Infrared and Millimeter Waves》1998,19(6):793-801
The first cw operation of our submillimeter wave gyrotron (Gyrotron FU IV) using a 12 T superconducting magnet has been successfully carried out. Output power is more than 20 W at a frequency of 301 GHz in the TE031 resonant cavity mode. Time-resolved frequency measurement s shows that the frequency fluctuation of the gyrotron output is smaller than 2 MHz. This frequency fluctuation is mainly due to the fluctuation in the output voltage of the power supply. 相似文献
40.
A.M. El-Badry T. Kuroyanagi S. Mitarai A. Odahara Y. Gono S. Morinobu K. Ogawa 《The European Physical Journal A - Hadrons and Nuclei》1998,3(2):133-138
A recoil distance method was used to measure half-lives of the excited states of 145Sm. The reaction used was 139La(10B, 4n)145Sm. A plunger system was used. Half-lives were determined for two excited states for the first time. The yrast 27/2+ state was found to have a half-life of 1.1 ± 0.2 ns corresponding to the retardation of 3.1 × 10−4 comparing with the single particle estimate of M1. The excitation energy of this state was well reproduced by the shell model
calculation having a mixed configuration of [π{h11/2(g7/2)−2 (d5/2)−1}10−, νf7/2] + [π{h11/2(g7/2)−1}9−,νh9/2]. Another retarded E1 transition was also found in a decay of a 21/2+ state. Its retardation was 1.6 × 10−4 comparing with the single particle value.
Received: 9 September 1997 / Revised version: 12 June 1998 相似文献