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71.
Metallic Na formation in/on NaCl crystals with irradiation by electron or vacuum ultraviolet photons
Shigehiro Owaki Shigeko Koyama Masao Takahashi Masao Kamada Ryouichi Suzuki 《Radiation Physics and Chemistry》1997,49(6):609-615
Metallic Na was formed in/on NaCl single crystals by irradiating them with a variety of radiation sources, namely, 21 MeV electron pulses, an electron beam of 30 keV and photon fluxes in the VUV region. The physical states were analysed using several methods, optical absorption, lifetime measurement of positron annihilation, Auger electron spectroscopy and UV photoelectron spectroscopy. Metallic Na was obtained in different physical states; clusters were formed in bulk, thin layers (islands) and thick layers on the surface. 相似文献
72.
Todoroki K Hayama T Ijiri S Kazuta A Yoshida H Nohta H Yamaguchi M 《Journal of chromatography. A》2004,1038(1-2):113-120
6-Rhodamine B amine functions as a highly sensitive fluorescence derivatization reagent for mono- and oligosaccharides; it reacts with the reducing end of saccharides under acidic conditions. The fluorescent derivatives of five monosaccharides can be separated within 25 min by reversed-phase liquid chromatography with isocratic elution. The detection limits (S/N = 3) for mono-, di-, and oligosaccharides are 7-51, 13, and 9-35 fmol/20 microl injection, which correspond to analyte concentrations of 35-255, 65, 45-175 nM, respectively. We have applied this derivatization method successfully to the analysis of the components of oligosaccharides in glycoproteins (ribonuclease B and fetuin) following their acidic or enzymatic hydrolysis. The results from these analyses are in good agreements with the reported values established previously. 相似文献
73.
Tsuneyuki Sato Naoki Morita Hitoshi Tanaka Tadatoshi Ota 《Journal of polymer science. Part A, Polymer chemistry》1989,27(8):2497-2508
Solvent effect on the polymerization of di-n-butyl itaconate (DBI) with dimethyl azobisisobutyrate (MAIB) was investigated at 50 and 61°C. The solvents used were found to affect significantly the polymerization. The polymerization rate (Rp) and the molecular weight of the resulting polymer are lower in more polar solvents. The initiation rate (Ri) by MAIB, however, shows a trend of being rather higher in polar solvents. The stationary state concentration of propagating poly(DBI) radical was determined by ESR in seven solvents. The rate constants of propagation (kp) and termination (kt) were evaluated by using Rp, Ri, and the polymer radical concentration observed. The kp value decreases fairly with increasing polarity of the solvent used, whereas kt is not so influenced by the solvents. The solvent effect on kp is explained in terms of a difference in the environment around the terminal radical center of the growing chain. Copolymerization of DBI with styrene (St) was also examined in three solvents with different physical properties. The poly(DBI) radical shows a lower reactivity toward St in a more polar solvent. 相似文献
74.
Harayama T Akiyama T Nakano Y Nishioka H Abe H Takeuchi Y 《Chemical & pharmaceutical bulletin》2002,50(4):519-522
A palladium-assisted coupling reaction of aryl triflate with arene was investigated, and a novel Pd reagent prepared from equimolar Pd(OAc)2, 1,3-Bis[diphenylphosphino]propane (DPPP), and Bu3P was developed. This method is useful for intramolecular biaryl coupling reactions, not only between aryl triflate and arene (triflate-amide), but also between aryl halide and arene (halo-amide). 相似文献
75.
Some of the ascidians belonging to the suborder Phlebobranchia accumulate vanadium ion efficiently from seawater. Clarification of the mechanism of this surprisingly efficient metal-accumulation system is desirable. Two mutually similar vanadium-binding proteins (vanabin1 and vanabin2) have recently been isolated from a vanadium-rich ascidian Ascidia sydneiensis samea. In this study, the vanadium-binding properties of vanabin2 have been investigated by X-band CW EPR and pulsed EPR spectroscopy. CW EPR spectra of samples containing various ratios of VO2+ and vanabin2 invariably exhibited a usual mononuclear-type VO2+ EPR signal with the intensity dependent on the ratio [vanabin]/[V]. EPR titration has shown that vanabin2 can bind up to approximately 23.9 vanadium ions per one molecule, almost all of which ( approximately 84%) are in a mononuclear VO2+ state as estimated by EPR quantitation. Electron spin-echo envelope modulation (ESEEM) spectra of VO-vanabin2 exhibited reasonably intense peaks attributable to amine nitrogen. This is consistent with the fact that vanabin2 is a lysine-rich protein (14 lysines out of 91 amino acids). The present study reveals the uniqueness of vanabin2, which can bind a large number of metal ions in a mononuclear fashion in contrast to the situation for ferritin and metallothionein. 相似文献
76.
A reversed-phase liquid chromatographic method for the determination of trace amounts of vanadium is described. Metal ions are converted into 2-(8-quinolylazo)-5-N,N-diethylaminophenol chelates in an off-line system. The chelates are injected onto a Zorbax CN column and separated with an aqueous acetonitrile mobile phase containing no chromogenic reagent. Unter these conditions, only vanadium(V) is spectrophotometrically detected at 540 nm among the metal ions Al(III), Ba(II), Ca(II), Cd(II), Co(II), Cr(III), Cu(II), Fe(III), Ga(III), Hg(II), Mg(II), Mn(II), Ni(II), Pb(II), V(V) and Zn(II). Amounts of 8.0–200 pg of vanadium(V) in 100-μl injections can be determined without interference from 10-fold molar excesses of many cations. At 0.001 a.u.f.s., the detection limit (twice the peak-to-peak noise) for vanadium(V) is 8.0 pg in 100 μl of injected solution and the relative standard deviation at 120 pg of vanadium(V) in a 100-μl injection is 3.5%. The proposed method is applied to the determination of vanadium in rain water and airborne particulates. 相似文献
77.
Yamada K Yagishita S Tanaka H Tohyama K Adachi K Kaizaki S Kumagai H Inoue K Kitaura R Chang HC Kitagawa S Kawata S 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(11):2647-2660
Novel metal-complex assemblies constructed from the flexible hinge-like ligand H(2)bhnq (H(2)bhnq=2,2'-bi(3-hydroxy-1,4-naphthoquinone)) have been synthesized. The X-ray crystal structures of these compounds reveal that four types of architectures are accessible by variation of the metal ions. In copper(II) compounds 1-3, the chelating bhnq(2-) ions bridge copper(II) centers to form one-dimensional zigzag chains. The chains of 1-3 are arranged by hydrogen-bonding interactions and stacking interactions to produce porous structures. Cobalt(II) and zinc(II) compounds 4 and 5 form one-dimensional helical chains. In 4 and 5, the crystal packing induces spontaneous resolution of the helical chains with chiral cavities formed perpendicular to the helices. Nickel(II) compounds 6 and 7 form cyclic tetramers. The fourth architecture, a dimer (compound 8), is obtained by the reaction of zinc(II) and bhnq(2-) in MeOH. In these compounds, changes of the dihedral angles and the metal-coordination mode of the bhnq(2-) ion induce the structural versatility. The assemblies of the zigzag chains of the copper(II) compounds exhibit reversible vapochromic behavior. UV/Vis, powder X-ray diffraction, EPR, and adsorption isotherm measurements indicate that this vapochromic behavior is based on the hinge-like flexibility of the bhnq(2-) ion. 相似文献
78.
Yahachi Saito Tadao Koyama Kenichiro Kawabata 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1997,40(1):421-424
Single-layer (SL) carbon tubes were produced by arc evaporation of graphite rods containing iron-group metals (Fe, Co, Ni, Fe/Co, Co/Ni, Fe/Ni) under He and Ar gas. Transmission electron microscopy (TEM) revealed that these elemental and binary metals, excluding Fe which need a special atmosphere (a mixture of Ar and CH4), showed catalytic activity producing SL tubes under pure inactive gases. Fe/Ni alloy was the most effectual catalysts for producing SL tubes. The highest abundance of SL tubes in raw soot was estimated to be ~ 10% from TEM observation. Smoke particles directly caught on TEM grids near an evaporation source during arcburning were also investigated, and it was suggested that small metal particles were first formed in the gas phase and then SL tubes grew from them. 相似文献
79.
A method of free energy calculation is proposed, which enables to cover a wide range of pressure and temperature. The free energies of proton-disordered hexagonal ice (ice Ih) and liquid water are calculated for the TIP4P [J. Chem. Phys. 79, 926 (1983)] model and the TIP5P [J. Chem. Phys. 112, 8910 (2000)] model. From the calculated free energy curves, we determine the melting point of the proton-disordered hexagonal ice at 0.1 MPa (atmospheric pressure), 50 MPa, 100 MPa, and 200 MPa. The melting temperatures at atmospheric pressure for the TIP4P ice and the TIP5P ice are found to be about T(m)=229 K and T(m)=268 K, respectively. The melting temperatures decrease as the pressure is increased, a feature consistent with the pressure dependence of the melting point for realistic proton-disordered hexagonal ice. We also calculate the thermal expansivity of the model ices. Negative thermal expansivity is observed at the low temperature region for the TIP4P ice, but not for the TIP5P ice at the ambient pressure. 相似文献
80.
A convenient synthesis of peripherally substituted or unsubstituted phthalocyanines having a variety of metals is described. Phthalocyanines can be obtained by heating phthalimides or phthalic anhydride with metal salts, hexamethyldisilazane, a catalytic amount of p-TsOH, and DMF at 150 degrees C. 相似文献