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51.
A theoretical study of a superconducting transition in many valley semiconductors, allowing interband electron-electron pairing, is presented. The order parameter, at very low temperatures, and the ac-conductivity are calculated and shown to reproduce known results in the limit when the “dielectric gap” is going to zero. 相似文献
52.
The extraction of the Mo(VI)-calmagite complex by adsorption onto active carbon is investigated in the present paper. Thermodynamic and kinetic properties and different adsorption isotherms were determined. The adsorption studies have shown that both the empirical Freundlich and the classical Langmuir isotherms successfully fit the experimental results. The overall adsorption process was exothermic and spontaneous in the temperature range from 283 to 323 K; namely, DeltaH(0) and DeltaS(0) values were found to be -8.15 kJ mol(-1) and -3.86 J mol(-1) K, respectively. The high activation energy demanded for desorption of the Mo(VI)-calmagite complex surface indicated that the overall process was controlled by the slow desorption, while a fast and low activated adsorption of the complex onto active carbon surface was fairly favored. These features indicate that active carbon may be very useful for preconcentration of molybdenum from diluted solutions. 相似文献
53.
Budi Rahadjeng Edy Tri Baskoro Hilda Assiyatun 《Proceedings Mathematical Sciences》2017,127(5):787-792
The notation \(F\rightarrow (G,H)\) means that if the edges of F are colored red and blue, then the red subgraph contains a copy of G or the blue subgraph contains a copy of H. The connected size Ramsey number \(\hat{r}_c(G,H)\) of graphs G and H is the minimum size of a connected graph F satisfying \(F\rightarrow (G,H)\). For \(m \ge 2,\) the graph consisting of m independent edges is called a matching and is denoted by \(mK_2\). In 1981, Erdös and Faudree determined the size Ramsey numbers for the pair \((mK_2, K_{1,t})\). They showed that the disconnected graph \(mK_{1,t} \rightarrow (mK_2,K_{1,t})\) for \( t,m \ge 1\). In this paper, we will determine the connected size Ramsey number \(\hat{r}_c(nK_2, K_{1,3})\) for \(n\ge 2\) and \(\hat{r}_c(3K_2, C_4)\). We also derive an upper bound of the connected size Ramsey number \(\hat{r}_c(nK_2, C_4),\) for \(n\ge 4\). 相似文献
54.
González-San Miguel HM Alpízar-Lorenzo JM Cerdà V 《Analytical and bioanalytical chemistry》2007,387(2):663-671
A technique based on multisyringe chromatography (MSC) was developed to determine three beta-lactamic antibiotics. Amoxicillin (AMOXI), ampicillin (AMPI) and cephalexin (CEPHA) were analyzed using a system with a very simple design and very low-cost equipment consisting of a multisyringe module, three low-pressure solenoid valves, a monolithic Chromolith Flash RP-18e column and a diode array spectrophotometric detector monitoring at 250 nm. Mobile phases containing methanol:acetic acid (0.1 M)-sodium acetate (0.1 M), pH 6.2, were tested for various ratios of methanol:acetic acid-sodium acetate, but a ratio of 10:90 gave optimum results with a flow rate of 2 ml min(-1). Validation parameters were evaluated for amoxicillin. The response to amoxicillin was linear over the range 0.04-0.4 mg/mL, with a correlation coefficient of 0.9996; precisions, evaluated as the repeatability for 0.04, 0.16 and 0.4 mg/mL amoxicillin, were 0.6%, 0.1% and 0.6%, respectively. Recovery from a generic formulation of amoxicillin was evaluated. The method showed selectivity in the presence of excipients commonly used in capsules, and satisfactory specificity was observed for amoxicillin and hydrolytic degradation products. The linearity was also evaluated for cephalexin and ampicillin. The conditions selected for MSC separation were compared with those for a HPLC system, and similar results were obtained in terms of chromatographic parameters but a difference in retention times was observed. 相似文献
55.
Chloroquine base (CQ) reacts with [Ir(COD)Cl]2 and IrCl3 · 3H2O to yield of Ir(CQ)Cl(COD) (1) and Ir2Cl6(CQ) · 3H2O (2), respectively. Reaction of [Ir(COD)Cl]2 with CQ in the presence of NH4PF6 leaded to [Ir(CQ)(Solv)2]PF6 (3). The three new iridium–CQ complexes were characterized by a combination of elemental analysis, IR and NMR spectroscopies and evaluated in vitro against Plasmodium beghei. Comparison of the IC50 values obtained with the experimental compounds with that determined for chloroquine diphosphate indicated a higher activity for complex 2, while complexes 1 and 3 showed a similar and lower activity, respectively. 相似文献
56.
57.
Following the thermodynamic formulation of a multifractal measure that was shown to enable the detection of large fluctuations at an early stage, here we propose a new index which permits us to distinguish events like financial crises in real time. We calculate the partition function from which we can obtain thermodynamic quantities analogous to the free energy and specific heat. The index is defined as the normalized energy variation and it can be used to study the behavior of stochastic time series, such as financial market daily data. Famous financial market crashes–Black Thursday (1929), Black Monday (1987) and the subprime crisis (2008)–are identified with clear and robust results. The method is also applied to the market fluctuations of 2011. From these results it appears as if the apparent crisis of 2011 is of a different nature to the other three. We also show that the analysis has forecasting capabilities. 相似文献
58.
Mystery solved: Using heterologous expression, the activities of two enzymes exclusively belonging to the kanamycin biosynthetic pathway have been identified in vitro. A distinctive reaction mechanism to produce kanamycin is proposed and the previously unknown catalytic deamination activity of KanJ dioxygenase is uncovered. 相似文献
59.
The preparation and oxidative demethylation attempts of podands 3--5, and 9 containing the 2,5-dimethoxyphenyl substituent are described. The reaction of alizarine 13 with chloroethanol afforded compounds 14 and 15. The pathway formation of heterocycle 15 from 14 is proposed. The synthesis of podand 16 containing the cytotoxic 1-hydroxy-9,10-anthraquinone fragment as the terminal groups is reported. 相似文献
60.
Wiogo HT Lim M Bulmus V Yun J Amal R 《Langmuir : the ACS journal of surfaces and colloids》2011,27(2):843-850
A facile method of stabilizing magnetic iron oxide nanoparticles (MNPs) in biological media (RPMI-1640) via surface modification with fetal bovine serum (FBS) is presented herein. Dynamic light scattering (DLS) shows that the size of the MNP aggregates can be maintained at 190 ± 2 nm for up to 16 h in an RPMI 1640 culture medium containing ≥4 vol % FBS. Under transmission electron microscopy (TEM), a layer of protein coating is observed to cover the MNP surface following treatment with FBS. The adsorption of proteins is further confirmed by X-ray photoelectron spectroscopy (XPS). Gel electrophoresis and LC-MS/MS studies reveal that complement factor H, antithrombin, complement factor I, α-1-antiproteinase, and apolipoprotein E are the proteins most strongly attached to the surface of an MNP. These surface-adsorbed proteins serve as a linker that aids the adsorption of other serum proteins, such as albumin, which otherwise adsorb poorly onto MNPs. The size stability of FBS-treated MNPs in biological media is attributed to the secondary adsorbed proteins, and the size stability in biological media can be maintained only when both the surface-adsorbed proteins and the secondary adsorbed proteins are present on the particle's surface. 相似文献