A Control Volume Radial Basis Function Techniques for the Numerical Simulation of Saturated Flows in Semi-confined Aquifer

In this work, a Control Volume Radial Basis Function technique (CV-RBF) is adapted to solve ground water flow in the saturated zone of the semi-confined aquifer. The CV-RBF method differs from classical CV methods in the way that the flux at the cell surfaces is computed. A local RBF interpolation of the field variable is performed at the centres of the cell being integrated and its neighbours. This interpolation is then used to reconstruct the solution and its gradient in the integration points which support the flux computation. In addition, it is required that such interpolation satisfies the governing equation in a certain number of points placed around the cell centres. In this way, the local interpolations become equivalent to local boundary-value problems. The CV-RBF method is combined with a local remeshing technique in order to track the phreatic surface, where the gradients required to satisfy the kinematic condition are computed by the same local RBF interpolations used for the flux computation. The proposed numerical approach is validated in a series of three-dimensional groundwater flow problems where the operations of recharging and extracting water from a semi-confined aquifer are modelled.     

Modeling the electrophoresis of highly charged peptides: application to oligolysines

The “coarse‐grained” bead modeling methodology, BMM, is generalized to treat electrostatics at the level of the nonlinear Poisson–Boltzmann equation. This improvement makes it more applicable to the important class of highly charged macroions and highly charged peptides in particular. In the present study, the new nonlinear Poisson–Boltzmann, NLPB‐BMM procedure is applied to the free solution electrophoretic mobility of low molecular mass oligolysines (degree of polymerization 1–8) in lithium phosphate buffer at pH 2.5. The ionic strength is varied from 0.01 to 0.10 M) and the temperature is varied from 25 to 50°C. In order to obtain quantitative agreement between modeling and experiment, a small amount of specific phosphate binding must be included in modeling. This binding is predicted to increase with increasing temperature and ionic strength.     

Numerical Simulation of Coherent Structures over Plant Canopy

This paper reports large eddy simulations of the interaction between an atmospheric boundary layer and a canopy (representing a forest cover). The problem is studied for a homogeneous configuration representing the situation encountered above a continuous forest cover, as well as for a heterogeneous configuration representing the situation similar to an edge or a clearing in a forest. The numerical results reproduces correctly all the main characteristics of this flow as reported in the literature: the formation of a first generation of coherent structures aligned transversally with the wind flow direction, the reorganization and the deformation of these vortex tubes into horse-shoe structures. The results obtained when introducing a discontinuity in the canopy (reproducing a clearing or a fuel break in a forest), are compared with the experimental data collected in a wind tunnel; here, the results confirm the existence of a strong turbulence activity inside the canopy at a distance equal to 8 times the height of the canopy, referenced in the literature as the Enhance Gust Zone (EGZ) characterized by a local peak of the skewness factor.     

Solids behavior in dilute zone of a CFB riser under turbulent conditions

The behavior of the solid phase in the upper zone of a circulating fluidized bed riser was studied using a phase Doppler anemometer. Glass particles of mean diameter 107 μm and superficial gas velocities U_g covering the turbulent and the beginning of the fast fluidization regime were investigated. Three static bed heights were tested. Ascending and descending particles were found co-existing under all operating conditions tested, and at all measurement locations. Superficial gas velocity proved/happened to have a larger effect on descending particles at the wall and on ascending particles in the central region. Transversal particle velocities in both directions (toward the center and toward the wall) behaved relatively equivalently, with only slight difference observed at the wall. However, observation of the number of particles moving in either transversal direction showed a change in bed structure when increasing U_g. Furthermore, a balance was constantly observed between the core zone and the annulus zone where the mutual mass transfer between these two zones occurred continuously. Transition from a slow to a fast particle motion was accompanied by a transition to high levels of velocity fluctuations, and was found corresponding to the appearance of significant solid particle flow rate.     

Rotational inelastic scattering of Li-N2 and Li-CO systems

A non-perturbative approach to rotationally inelastic scattering is discussed. The method is applicable regardless of the magnitude of the coupling strength for a certain class of potential functions if the energy transfer is either small or equal to zero. Various cross sections for rotational transition (0 → 2) are calculated for Li-N₂ and Li-CO systems with an assumption that the diatomic molecules are rigid. With reasonable choice of potential parameters, the calculated elastic differential cross sections agree well with the available experimental results. The inelastic differential cross sections are found peaked in the backward hemisphere for both systems.     

Numerical simulation of two‐dimensional Kelvin–Helmholtz instability using weakly compressible smoothed particle hydrodynamics

The growth of the Kelvin–Helmholtz instability generated at the interface between two ideal gases is studied by means of a Smoothed Particle Hydrodynamics (SPH) scheme suitable for multi‐fluids. The SPH scheme is based on the continuity equation approach where the densities of SPH particles are evolved during the simulation, in combination with a momentum equation previously proposed in the literature. A series of simulations were carried out to investigate the influence of viscosity, smoothing, the thickness of density and velocity transition layers. It was found that the effective viscosity of the presented results are strongly dependent on the artificial viscosity parameter α_AV, with a linear dependence of 0.15. The utilisation of a viscosity switch is found to significantly reduce the spurious viscosity dependence to 1.68 × 10^?4 and generated qualitatively improved behaviour for inviscid fluids. The linear growth rate in the numerical solutions is found to be in satisfactory agreement with analytical expectations, with an average relative error 〈η_smooth〉=13%. In addition, the role played by velocity and density transition layers is also in general agreement with the analytical theory, except for the sharp‐velocity, finite‐density gradient cases where the larger growth rate than the classical growth rate is expected. We argue the inherited smoothing properties of the velocity field during the simulations are responsible for causing this discrepancy. Finally, the SPH results are in good agreement for finite velocity and density gradient scenarios, where an average relative error of 〈η_smooth〉=11.5% is found in our work. Copyright © 2015 John Wiley & Sons, Ltd.     

Flavonol Glycoside from Psorospermum androsaemifolium

A new flavonol glycoside, 3′‐(4′''‐(3′''',4′'''‐dihydroxyphenoxy)‐2′''‐hydroxyphenoxy)acanthophorin B ( 1a ) together with 3′‐(2′'',4′''‐dihydroxyphenoxy)acanthophorin B ( 1 ), acanthophorin B ( 2 ), vismiaquinone ( 3 ), rheochrysidin ( 3a ), lupeol acetate and fatty acid were isolated from the chloroform extract of the stem bark of Psorospermum androsaemifolium Baker (Clusiaceae). The structure of 1a was determined on the basis of detailed spectroscopic analysis and comparison with the literature. Compounds 1a and 3a showed moderate antimicrobial activity.     

Passive harmonic mode locking of soliton crystals

We report experimental observation of passive harmonic mode locking (HML) in which the basic pattern is a soliton crystal. Several crystal states were generated from an initial large bound state by increasing the pump power. The soliton crystals are identical and progressively span along the cavity to finally take a regular spacing leading to HML of solitons crystal.