平板湍流边界层底层的不稳定波

湍流边界层底层的相干结构及猝发现象对决定边界层的特性有很重要的意义,但直至现在对相干结构的性质及起因仍不清楚。在本文中,对湍流边界层的底层进行了非线性稳定性分析,发现该处确可产生不稳定波,可能用以说明相干结构的起因。     

Stability analysis and control synthesis of uncertain Roesser-type discrete-time two-dimensional systems

We study the stability analysis and control synthesis of uncertain discrete-time two-dimensional(2D) systems.The mathematical model of the discrete-time 2D system is established upon the well-known Roesser model,and the uncertainty phenomenon,which appears typically in practical environments,is modeled by a convex bounded(polytope type) uncertain domain.The stability analysis and control synthesis of uncertain discrete-time 2D systems are then developed by applying the Lyapunov stability theory.In the processes of stability analysis and control synthesis,the obtained stability/stabilzaition conditions become less conservative by applying some novel relaxed techniques.Moreover,the obtained results are formulated in the form of linear matrix inequalities,which can be easily solved via standard numerical software.Finally,numerical examples are given to demonstrate the effectiveness of the obtained results.     

“Hopf/homoclinic”簇放电和“SubHopf/homoclinic"簇放电之间的同步

以修正过的Morris-Lecar神经元模型为例,讨论了“Hopf/homoclinic”簇放电和“SubHopf/homoclinic"簇放电之间的同步行为.首先,分别考察了同一拓扑类型的两个耦合簇放电神经元的同步行为,发现“Hopf/homoclinic”簇放电比“SubHopf/homoclinic”簇放电达到膜电位完全同步所需要的耦合强度小,即前者比后者更容易达到膜电位完全同步.其次,对这两个不同拓扑类型的簇放电神经元的耦合同步行为进行了讨论.通过数值分析发现随着耦合强度的增加,两种不同类型的簇放电首先达到簇放电同步,然后当耦合强度足够大时甚至可以达到膜电位完全同步,并且同步后的放电类型更接近容易同步的簇放电类型,即“Hopf/homoclinic”簇放电.然而令人奇怪的是此时慢变量并没有达到完全同步,而是相位同步;慢变量之间呈现为一种线性关系.这一点和现有文献的结果截然不同.     

光晶格中双组分玻色-爱因斯坦凝聚系统的调制不稳定性

利用线性稳定分析的方法,在不满足原子流相等的条件下,对光晶格中双组分玻色-爱因斯坦凝聚原子(BEC)系统的调制不稳定性区域与不同BEC组分的波长和不同的调制波长,以及两组分BEC间相互作用大小之间的关系进行了研究.结果显示,光晶格中双组分BEC系统的调制稳定性的区域在不满足原子流相等的条件下,随不同的波长,不同的调制和相互作用之间的大小会出现了较大的变化.相应结果可为实际应用中如何操控双组分BEC提供有用的信息.     

Enhanced electrocatalytic oxidation of hydroxylamine on Pt/polypyrrole composite modified glassy carbon electrode

A sensitive hydroxylamine sensor is developed by electrodeposition of Pt nanoparticles on pre-synthesized polypyrrole nanoparticles modified glassy carbon electrode. The modified electrode presents distinctly electrocatalytic activity toward hydroxylamine oxidation. The kinetic parameters such as the overall numbers of electrons involved in hydroxylamine oxidation, the electron transfer coefficient, standard heterogeneous rate constant, and diffusion coefficient are evaluated. The current response increases linearly with increasing hydroxylamine concentrations and exhibits two wide linear ranges of 5.0?×?10^?7–1.1?×?10^?3 and 1.1?×?10^?3–18.8?×?10^?3 M with a detection limit of 0.08 μM (s/n?=?3). The proposed electrode presents excellent operational and storage ability for determining hydroxylamine. Moreover, the sensor shows good sensitivity, selectivity, and reproducibility properties.     

Feasibility Study on Quantitative Measurements of Singlet Oxygen Generation Using Singlet Oxygen Sensor Green

The purpose of this study is to investigate the feasibility for quantitative measurement of singlet oxygen (¹O₂) generation by using a newly developed ¹O₂-specific fluorescence probe Singlet Oxygen Sensor Green reagent (SOSG). ¹O₂ generation from photoirradiation of a model photosensitizer Rose Bengal (RB), in initially air-statured phosphate buffered saline (PBS) was indirectly monitored with SOSG. In the presence of ¹O₂, SOSG can react with ¹O₂ to produce SOSG endoperoxides (SOSG-EP) that emit strong green fluorescence with the maximum at 531 nm. The green fluorescence of SOSG-EP is mainly dependent on the initial concentrations of RB and SOSG, and the photoirradiation time for ¹O₂ generation. Furthermore, kinetic analysis of the RB-sensitized photooxidation of SOSG is performed that, for the first time, allows quantitative measurement of ¹O₂ generation directly from the determination of reaction rate. In addition, the obtained ¹O₂ quantum yield of porphyrin-based photosensitizer hematoporphyrin monomethyl ether (HMME) in PBS by using SOSG is in good agreement with the value that independently determined by using direct measurement of ¹O₂ luminescence. The results of this study clearly demonstrate that the quantitative measurement of ¹O₂ generation using SOSG can be achieved by determining the reaction rate with an appropriate measurement protocol.     

Optimization in Solvent Selection for Chlorin e6 in Photodynamic Therapy

The photophysical properties of chlorin e6 (Ce6) in twelve different protic, aprotic and non-polar solvents were investigated using ultraviolet–visible and fluorescence spectroscopic methods. Solvatochromic effects were determined by the changes in quantum yield, Stokes shift, fluorescence half-life and excited state dipole moments of Ce6 in the different solvents. The absorption shifts observed in different solvents were further analyzed using the Kamlet-Abboud-Taft model and the nature of solute-solvent interactions between Ce6 and different protic and aprotic solvents was elucidated. The quantum yields were found highest in protic solvents (except water), followed by aprotic and non-polar solvents. Solvent polarity parameters showed a linear increasing trend with Stokes shift and fluorescence half-life, which indicated the presence of Ce6-solvent interaction. Using the Kamlet-Abboud-Taft model, a direct correlation between the solvent polarity parameters and absorption shift was observed, which substantiated the existence of Ce6-solvent interaction by hydrogen bond formation. The excited state dipole moments in specific protic and aprotic solvents were found to be higher than the ground state dipole moments, implying a more polar nature of Ce6 during excited state transition.     

柔性有机场效应晶体管研究进展

柔性有机场效应晶体管具有可折叠、质量轻、低成本等优点,在柔性显示、柔性传感器、柔性射频标签和柔性集成电路等方面显示了广阔的应用前景.本文在介绍柔性有机场效应 晶体管最新研究进展的基础上, 总结了柔性有机场效应晶体管的器件结构和柔性有机场效应晶体管所使用的衬底材料、 栅绝缘层材料、有源层材料及电极材料, 阐述了柔性有机场效应晶体管的制备工艺, 并讨论了不同的弯曲方式对柔性有机场效应晶体管性能的影响, 最后总结和展望了柔性有机场效应晶体管的应用领域. 关键词： 柔性 晶体管 有机/聚合物 溶液加工     

量子测量对三维光子晶体中Λ型原子动力学性质的影响

讨论了量子测量对各向异性光子晶体中Λ型激发态原子衰减的影响，主要包括衰减的抑制和加速效应.研究发现，这样的量子测量效应不仅与原子共振频率相对于光子晶体带边的位置有关，还与量子测量本身的频率大小相关.由于各向异性光子晶体的影响，较小频率的量子测量也能得到抑制衰减的效应. 关键词： 量子测量 量子Zeno 和 反Zeno效应 光子晶体