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21.
22.
Harry Biron Christiane Grller-Walrand Stephan De Jaegere 《Chemical physics letters》1973,20(6):581-585
A quantitative comparison between the excitation and absorption spectra of Eu3+ in aqueous solution is given which leads to the conclusion that fluorescence quantum yields are independent of the excitation wavelength. Use is made therefore of the series of homologous lines 5D3, 5D2, 5D1, 5D0 → 7F1. 相似文献
23.
24.
The rate of the Wolff-Kishner reaction of benzophenone hydrazone in butyl carbitol increases as the cation of the alkoxide base is varied in the order K>Na>Li>Mg. The replacement of butyl carbitol by 1-decanol also accelerates the reaction, and an additional increase is caused by the presence of crown ether. On the basis of changes in the activation parameters, it is concluded that the reactivity of the hydrazone anion increases as the contact ion pair becomes more fully solvated and dissociated. 相似文献
25.
A supramolecular poly[3]pseudorotaxane was prepared by self-assembly of a homoditopic cylindrical bis(crown ether) host and a bisparaquat derivative in solution by host-guest complexation. 相似文献
26.
Two new synthetic approaches to the title compounds are reported. In the first of these, starting with N-carbobenzyloxysarcosine, four synthetic steps are employed to finally assemble the C3? C4 bond of the 1,2-benzothiazine ring. In the second approach, an enol ether is employed as a protecting group to allow formation of the 3-carboxamide function, which is followed by cleavage of the ether function to yield the desired 4-hydroxy-1,2-benzothiazine-3-carboxamide 1,1-dioxide. 相似文献
27.
Yasri A Berthelot D Gijsen H Thielemans T Marichal P Engels M Hoflack J 《Journal of chemical information and computer sciences》2004,44(6):2199-2206
REALISIS is a software system for reagent selection, library design, and profiling, developed to fit the workflow of bench chemists and medicinal chemists. Designed to be portable, the software offers a comprehensive graphical user interface and rapid, integrated functionalities required for reagent retrieval and filtering, product enumeration, and library profiling. REALISIS is component-based, consisting of four main modules: reagent searching; reagent filtering; library enumeration; and library profiling. Each module allows the chemist to access specific functionalities and diverse filtering and profiling mechanisms. By implementing the entire process of reagent selection, library design, and profiling and by integrating all the necessary functionalities for this process, REALISIS cuts the time required to design combinatorial and noncombinatorial libraries from several days to a few hours. 相似文献
28.
Photosynthesis is one of the fascinating fields of current interdisciplinary research. It seems miraculous that nature, in the process of evolution, has managed to bring about the process of photosynthesis. The first step involves a charge separation at the reaction centers, which proceeds with 100% quantum yield from the photoexcited singlet state of the bacteriochlorophyll donor, despite the fact that the wasteful deactivation of the electron into the ground state should be highly favored. Biomimetic model compounds (that is, those which resemble the pigments nature has developed) have been constructed from porphyrins and quinones. These model systems have allowed the study of the factors contributing to the highly efficient charge separation. This report focuses on recent developments in the study of electron transfer in porphyrinoquinones. Some of the results of these investigations may not be not fully understood and are often the subject of controversial discussions. 相似文献
29.
Anion excess colorless fluorite-type strontium-yttrium chloride has been prepared. Single crystals of the SrY compound exhibit a primitive cubic lattice with a = 6.967(1)Å. Two mutually exclusive structural models for solutions, neither of which is exact, are discussed. The first is a vacancy model in which the extra charge which results from substitution of Y3+ for Sr2+ is balanced by the simultaneous removal of a Sr2+Cl? ion pair. This model requires individual ion sites to be partially occupied and nonequivalent and is strongly suggestive of vacancy ordering. Refinement in space group P1, with sites refined independenty, led to R = 0.1096. The second model describes the structure in terms of a Willis cluster of defects and includes both anion vacancies and interstitial anions. Full-matrix least squares refinement in space group Fm3m, with positions analogous to those in UO2.12 and (Ca,Y)F2.10, converged at R = 0.0633 for the 114 face-centered parent structure reflections whose |F|;2 > σ(F2). This second model is discussed in relation to a probable true solution which involves longrange order. 相似文献
30.
Harry W. Gibson Dennis K. Chesney Frank D. Popp 《Journal of heterocyclic chemistry》1972,9(3):541-544
Treatment of 2-(4-chlorobutanoyl)- and 2-(5-chloropentanoyl)-1, 2-dihydroisoquinaldonitrile with sodium hydride gave rise to tricyclic benzoquinolizone and azepino[1,2-α]isoquinoline derivatives. A similar reaction was observed in the quinoline series. Several reactions of 1,2,3,4-tetrahydro-4-oxo-11bH-benzo[α]quinolizine-11b-carbonitrile are reported. 相似文献