Boundary layer development of pulsatile blood flow in a tapered vessel

Assuming that the tapered angle is small,the problems of developing flow under unsteady oscillatory condition are studied in this paper.The formula of velocity distribution is obtained.The analyses for the results show that the blood flow in a converging tapered vessel remains a developing flow throughout the length,and the effects of tapered angle on the developing flow are increased with the increment of the tapered angle.     

在水槽中的加速平板问题

本文利用Lagrange方法分析在水槽中平板水平地向静止流体运动的问题,非线性自由面条件能精确满足,所得的结果大致与[2]符合。     

气固两相流动的湍流脉动扩散数学模型及其应用

本文提出了气固两相流动的湍流扩展数学模型，本模型用k-ε双方程模型求解气相湍流场，并根据气流脉动的频谱、能谱曲线提出了随机富工级数来模拟气相脉动速度，用拉氏方法描述颗粒的运动，故称为脉动频谱随机颗粒轨道模型。本文还给出了本模型在气固多相射流和流化床内应用的实例。     

平面无穷方格网络上的热传导问题

讨论了平面无穷方格网络上的热传导问题，并将结果推广到其他形状的无穷网络上。     

Free vibration analyses by boundary element method using component mode synthesis

The boundary element method for dynamic analysis of two dimensional structures was developed by Nardini and Brebbia in 1983. Free vibration analysis of structures by BEM results in a generalized eigenproblem with coefficient matrices nonsymmetric and full. So, it costs a lot of CPU time to solve the eigenproblem. In order to reduce the cost the improved free interface coupling method has been adopted. By aid of lower eigenvectors and residual modes the degrees of freedom of substructure equaion of dynamic equilibrium can be reduced. By assembling the reduced substructure equations, the system of equations for the whole structure will be obtained. By using the traction and displacement compatibility conditions on the interface, the second transformation matrix has been developed for further reduction of system equations. The technique has been applied to some specific examples which give the evidence that the method is satisfactory and efficient.     

Actinium coordination chemistry: A density functional theory study with monodentate and bidentate ligands

In the current study, the coordination chemistry of nine-coordinate Ac(III) complexes with 35 monodentate and bidentate ligands was investigated using density functional theory (DFT) in terms of their geometries, charges, reaction energies, and bonding interactions. The energy decomposition analysis with naturals orbitals for chemical valence (EDA-NOCV) and the quantum theory of atoms in molecules (QTAIM) were employed as analysis methods. Trivalent Ac exhibits the highest affinities toward hard acids (such as charged oxophilic donors, fluoride), so its classification as a hard acid is justified. Natural population analysis quantified the involvement of 5f orbitals on Ac to be about 30% of total valence electron natural configuration indicating that Ac is a member of the actinide series. Pearson correlation coefficients were used to study the pairwise correlations among the bond lengths, ΔG reaction energies, charges on Ac and donor atoms, and data from EDA-NOCV and QTAIM. Strong correlations and anticorrelations were found between Voronoi charges on donor atoms with ΔG, EDA-NOCV interaction energies and QTAIM bond critical point densities.     

Interplay effect on simultaneous catalytic oxidation of NOx and toluene over different crystal types of MnO2 catalysts

This paper firstly investigated the interplay effect on simultaneous catalytic oxidation of NO and toluene. Four tunnel-structure polymorphs, i.e., α-MnO₂, β-MnO₂, γ-MnO₂ and δ-MnO₂, were synthesized to compare individual and simultaneous oxidation of NO and toluene. Results demonstrated that toluene significantly inhibited NO conversion that near zero efficiencies were observed at low temperature over the four catalysts. Subsequently, NO oxidation efficiency climbed rapidly to the equivalent value as absence of toluene. In addition, presence of NO also elevated toluene conversion into higher temperature of 10–20 °C than that without NO. The reaction between toluene and oxygen took the superiority during simultaneous oxidation with NO. NO oxidation efficiency started to increase until toluene degradation approaching to the equilibrium. However, this competition seemed to be negligible at high temperature that both toluene and NO attained high conversion efficiencies. These findings provide a feasible way for simultaneous removal of NO_x and VOCs using catalytic oxidation as well as selecting an optimal temperature window.     

Hybridization of thiol-functionalized poly(phenylacetylene) with cadmium sulfide nanorods: improved miscibility and enhanced photoconductivity

Molecules of a thiol-functionalized phenylacetylene derivative were assembled on the CdS nanorod surface and copolymerized with phenylacetylene, affording an inorganic semiconductor-conjugated polymer hybrid with excellent solubility and high photoconductivity.     

Stochastic Kolmogorov-type system with infinite delay

The paper considers a stochastic functional Kolmogorov-type population system with infinite delay under the general probability measures. Main aim is to show that the environment noise will not only suppress a potential population explosion but also make the solution be stochastically ultimately bounded and asymptotic stable. Moreover, two stochastic functional Lotka-Volterra equations as examples are provided to illustrate the main results.