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991.
Gu R Depraetere S Kotek J Budka J Wagner-Wysiecka E Biernat JF Dehaen W 《Organic & biomolecular chemistry》2005,3(16):2921-2923
The first example of substitution reaction in the free alpha-position of N-confused calix[4]pyrroles is reported: azo-coupling with various arenediazonium salts. The obtained azocompounds were used for studies of their anion-binding properties by UV-Vis spectroscopy. 相似文献
992.
Dr. Wen-Da Zhang Lang Zhou Ya-Xiang Shi Dr. Yong Liu Hanwen Xu Prof. Dr. Xiaodong Yan Yan Zhao Prof. Dr. Yuqin Jiang Prof. Dr. Jiangwei Zhang Prof. Dr. Zhi-Guo Gu 《Angewandte Chemie (International ed. in English)》2023,62(27):e202304412
Dual-atom catalysts (DAC) are deemed as promising electrocatalysts due to the abundant active sites and adjustable electronic structure, but the fabrication of well-defined DAC is still full of challenges. Herein, bonded Fe dual-atom catalysts (Fe2DAC) with Fe2N6C8O2 configuration were developed through one-step carbonization of a preorganized covalent organic framework with bimetallic Fe chelation sites (Fe2COF). The transition from Fe2COF to Fe2DAC involved the dissociation of the nanoparticles and the capture of atoms by carbon defects. Benefitting from the optimized d-band center and enhanced adsorption of OOH* intermediates, Fe2DAC exhibited outstanding oxygen reduction activity with a half-wave potential of 0.898 V vs. RHE. This work will guide more fabrication of dual-atom and even cluster catalysts from preorganized COF in the future. 相似文献
993.
A facile solution-phase method has been developed to synthesize specially hollow and solid ZnS nanospheres. High-resolution TEM images on the nanospheres suggest their formation via the oriented aggregation of the primary ZnS nanocrystals. The morphology and size of the ZnS nanospheres can also be tuned easily by controlling the experimental conditions. These special spherical structures are very easily encapsulated within a uniform silica layer without any surface modification, suggesting potential applications in biochemistry and biodiagnostics. 相似文献
994.
Nan Gan Xuan Wang Huili Ma Anqi Lv He Wang Qian Wang Mingxing Gu Suzhi Cai Yanyun Zhang Lishun Fu Meng Zhang Chaomin Dong Wei Yao Huifang Shi Zhongfu An Wei Huang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(40):14278-14283
Provided here is evidence showing that the stacking between triplet chromophores plays a critical role in ultralong organic phosphorescence (UOP) generation within a crystal. By varying the structure of a functional unit, and different on‐off UOP behavior was observed for each structure. Remarkably, 24CPhCz, having the strongest intermolecular interaction between carbazole units exhibited the most impressive UOP with a long lifetime of 1.06 s and a phosphorescence quantum yield of 2.5 %. 34CPhCz showed dual‐emission UOP and thermally activated delayed fluorescence (TADF) with a moderately decreased phosphorescence lifetime of 770 ms, while 35CPhCz only displayed TADF owing to the absence of strong electronic coupling between triplet chromophores. This study provides an explanation for UOP generation in crystal and new guidelines for obtaining UOP materials. 相似文献
995.
基于结构动力修改的桩基检测方法 总被引:1,自引:0,他引:1
采用结构动力修改技术研究桩身损伤检测,将其转化为在一定约束条件下拟合桩顶频响函数的优化问题。用遗传算法加以求解。文中给出的数值模拟试验和工程应用实例,显示该方法能在较大范围内可靠地反演出桩身横截面积、桩长、波速等参数,达到检测桩身缺陷的目的,实现测试和分析一体化,使桩基检测易于进行并且结果实用可靠。 相似文献
996.
海底边坡稳定分析方法综述 总被引:9,自引:0,他引:9
本文指出海底边坡与陆上边坡的不同点,对一个完整的海底边坡稳定问题从几何形状和载荷情况两个方面进行了描述。由于波浪影响是海底边坡问题的最大特点,因此回顾了计算海底压力的各种方法以及在海底压力作用下海底土层产生的瞬态和残余孔隙压力。然后对极限平衡、静态变形分析和动力分析三大类边坡稳定分析方法进行了评述,并指出各自的适用范围。海底边坡破坏后的行为尤其复杂,指出用流变模型预测泥流性质的可能性。最后提出了海底边坡稳定性课题的当前致力方向。 相似文献
997.
P. B. Li Y. Gu Q. H. Gong G. C. Guo 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2009,55(1):205-209
We propose a scheme for realizing the Ising spin-spin
interaction and atomic cluster states utilizing the trapped
two-level atoms inside a one-dimensional coupled resonator
waveguide. In the strong driving and large detuning conditions, an
effective Ising spin-spin interaction can be generated through
suitably tuning the parameters. Then atomic cluster states are
produced by using this Ising interaction. This scheme need not
initially prepare the superposition states of atoms, and is
insensitive to cavity decay. 相似文献
998.
针孔辅助点投影诊断方法实验研究 总被引:7,自引:0,他引:7
针孔辅助点投影背光成像是近几年国外新兴的等离子体诊断技术,在惯性约束聚变相关物理实验诊断中具有重要的应用前景.为验证这一诊断方法的实用性,在神光Ⅱ第九路平台上开展了演示实验.利用激光驱动平面Ti靶获得约4.7 keV的Ti K壳层X射线,在十几微米的针孔约束下作为次级点源并对Au栅格样品投影成像,并用CCD记录.实验成功获得了清晰的样品二维空间分辨的时间积分图像,空间分辨力优于16.1 μm.实验结果表明针孔辅助点投影具有较高的空间分辨力、较大的视场、较高的图像对比度,将成为瑞利泰勒不稳定性研究、激光状态方程研究等物理实验的重要诊断方法之一. 相似文献
999.
1000.
Size dependence of a magnetopolaron in cylindrical quantum wires at arbitrary magnetic fields 总被引:8,自引:0,他引:8
With the use of variational method to solve the effective mass equation, we have studied the cyclotron resonance of a magnetopolaron in cylindrical quantum wires at arbitrary magnetic fields. The interaction of the electron with surface-optical (SO) phonons is used. Having calculated the ground state energy and the excited state energy of the magnetopolaron, we obtain the hybrid frequency of the magnetopolaron in quantum wires. 相似文献