Characterization of microchip electrophoresis devices fabricated by direct‐printing process with colored toner

This paper reports for the first time the use of colored toner to produce polyester toner (PT) ME devices. Colored PT devices were designed in drawing software and printed on a polyester film using a color laser printer with 3600 dpi resolution. The colored toner is composed of a copolymer mixture (styrene and acrylate), wax, silicon dioxide, and pigments. The presence of silica in the toner composition has enhanced the EOF magnitude and improved the analytical performance. For a pH range between 2 and 12, the EOF measured on a magenta PT chip, for example, ranged from 3.8 to 5.8 (× 10^?4 cm² V^?1 s^?1). Typical separations of inorganic cations (K⁺, Na⁺, and Li⁺) were used as model system to investigate the analytical feasibility of the proposed devices. The repeatability for the migration times of all analytes exhibited RSD values lower than 1% (n = 10). The separation efficiencies found on colored PT devices ranged from 10 000 to 49 000 plates/m, which means between 7 and 23% of the maximum theoretical efficiency on this microfluidic platform (1.85 × 10⁵ plates/m). The improvements achieved on the proposed devices are associated with the small additional amount of silica on the toner composition as well as the printing of channels with smoother surfaces and better uniformity when compared to the conventional PT chips printed with monochromatic laser printers.     

The interaction between atoms of Au and Cu with clean Si(1 1 1) surface: A study combining synchrotron radiation grazing incidence X-ray fluorescence analysis and theoretical calculations

In order to evaluate the interactions between Au/Cu atoms and clean Si(1 1 1) surface, we used synchrotron radiation grazing incidence X-ray fluorescence analysis and theoretical calculations. Optimized geometries and energies on different adsorption sites indicate that the binding energies at different adsorption sites are high, suggesting a strong interaction between metal atom and silicon surface. The Au atom showed higher interaction than Cu atom. The theoretical and experimental data showed good agreement.     

The PbPb collision

The reaction ²⁰⁸Pb on ²⁰⁸Pb was studied at bombarding energies of 7.0 and 7.57 MeV/u. One-particle inclusive measurements using a large-area position-sensitive ionisation chamber delivered the kinetic energy, charge and scattering angle of the reaction products. A precise calibration of the stopping power for very heavy ions in the detector gas was performed. The measured Wilczynski diagrams show, for increasing loss of kinetic energy, an increase of the mean scattering angle. It is attributed to the dominance of the repulsive Coulomb forces with respect to the attractive nuclear forces. The element distribution for the ²⁰⁸Pb on ²³⁸U reaction at 7.5 MeV/u was also measured and compared to the PbPb and UU reactions. Fission probabilities are derived as a function of charge and total kinetic energy loss. The most striking result is seen in the σ_z² versus TKEL correlation: the average rate of energy loss per nucleon exchange is abnormally large. It is shown that this behaviour is associated with the double magic closed shell character of the colliding nuclei. Nuclear structure information is extracted through a simple parametrisation.     

Structure in momentum-transfer for (pπ−) systems produced in diffractive dissociation of neutrons on protons

The four-momentum transfer distribution of (pπ^?) systems produced in the neutron dissociation reaction n + p → (pπ^?) + p has substantial structure which depends strongly on the mass and on the angular decay properties of the produced (pπ^?) system. No significant energy dependence is observed in the data for incident neutrons in the momentum range between 50 GeV/c and 300 GeV/c. The results are compared with a Deck-type of model.     

The (18O,16O) reaction on even tin isotopes

The two-neutron transfer reaction^ASn(¹⁸O,¹⁶O)^A+2Sn has been measured for the isotopes A=112, 116, 118, 120, 122 and 124 at bombarding energies of 57 and 60 MeV together with the elastic scattering. Angular distributions have been analysed for the transitions to the ground state and to the first excited 2⁺ state. The observed ground state transition is strongly enhanced. The theoretical DWBA analysis is performed with a finite range 2n-transfer form factor including recoil correction. The calculated cross section reproduces the observed systematic change over all isotopes. The absolute cross sections are normalized by a factor of 4.7 and 7.5, depending on the two different sets of 2n-wave functions used in the analysis. The results confirm the prediction of the pairing model that the transition strengths of a neutron pair between the ground states of even tin isotopes are the same.     

Analysis of the sequential fission observed in collisions of100Mo +100Mo and120Sn +120Sn around 20 A·MeV

Events with 2, 3 and 4 heavy fragments (A≥20) detected in the reactions¹⁰⁰Mo +¹⁰⁰Mo at 18.7, 23.7 A·MeV and¹²⁰Sn +¹²⁰Sn at 18.4 A·MeV were analyzed by means of an improved version of the kinematic coincidence method. The phase-space distributions prove that 3- (and possibly 4-) body events predominantly originate from a two-step mechanism and are compatible with the hypothesis of a binary deep-inelastic interaction followed by the further fissionlike decay of one (or both) of the primary fragments. The characteristics of the fission step — mass asymmetry, relative velocity, in-plane and out-of-plane angles — have been reconstructed for the 3-body events and indications are found that nonequilibrium effects at the end of the deep-inelastic phase may influence the fissionlike decay.     

Reflecting polarizing beam splitter

We propose and experimentally demonstrate the use of metal-covered lamellar relief gratings as a polarizing beam splitter operating at a single wavelength near Littrow incidence. We report the characteristics of a grating produced by holography and reactive ion etching that was calculated for operation as beam splitter at lambda = 633 nm (for a He-Ne laser).     

Optimal design of a beam subject to bending: a basic application

The minimisation of both the mass and deflection of a beam in bending is addressed in the paper. To solve the minimisation problem, a multi-objective approach is adopted by imposing the Fritz John conditions for Pareto-optimality. Constraints on the maximum stress and elastic stability (buckling) of the structure are taken into account. Additional constraints are set on the beam cross section dimensions. Three different cross sections of the beam are analysed and compared, namely the hollow square, the I-shaped and the hollow rectangular cross sections. The analytical expressions of the Pareto-optimal sets are derived. As expected, the I-shaped beam exhibits the best compromise in structural performance, which is related on the particular loading considered.