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91.
92.
We introduce a class of function algebras, that we call unimodular,
and study Toeplitz operators on the Hardy spaces associated to representing
measures on these algebras.We show that our class of function algebras is very
extensive and that a number of important results for Toeplitz operators and
their associated C*-algebras extend to the very general setting we consider.
Submitted: July 1. 2001. 相似文献
93.
Let M be a simply connected Riemannian symmetric space, with at most one flat direction. We show that every Riemannian (or
unitary) vector bundle with parallel curvature over M is an associated vector bundle of a canonical principal bundle, with
the connection inherited from the principal bundle. The problem of finding Riemannian (or unitary) vector bundles with parallel
curvature then reduces to finding representations of the structure group of the canonical principal bundle. 相似文献
94.
[reaction: see text] To facilitate the access to unique models for biological processes, we examined six different synthetic routes to octi(p-phenylene) rods with lateral and terminal substituents R(L) and R(T). This systematic study allowed us to increase to overall yield for the synthesis of a new class of oligo(p-phenylene) ionophores about 20 times and to provide general insights into the practicability of synthetic routes to multiply substituted molecular rods. 相似文献
95.
Gerard A. van Albada Nora Veldman Anthony L. Spek Jan Reedijk 《Journal of chemical crystallography》2000,30(1):69-72
The title compound, catena-[bis(azido-N)-copper(II)-(bis(2-benzimidazolyl)butane), [Cu(C18H18N4)(N3)2]n, was obtained from the reaction of the ligand bis(2-benzimidazolyl)butane and Cu(N3)2. The x-ray crystal structure is reported. The compound crystallizes in the monoclinic space group P21/c with a = 8.2524(10), b = 12.765(5), c = 9.1125(15) Å, = 106.423(12)°, Z = 2. The Cu(II) ions are square-planar coordinated with trans-oriented end-on binding azido ligands. The structure is a polynuclear chain with the benzimidazole bridging at each end. In addition a N(ligand)-H···N(azido) H-bridge [N(ligand)···N(azido) = 2.994(7) Å] is present, resulting in a pseudo 2-dimensional lattice. The characteristic azido infrared vibrations are found at 2060 and 2077 cm–1 (as(N3)) and 1284 and 1297 cm–1 ((N3)). 相似文献
96.
Hamida Maachou Kheireddine Bal Youcef Bal Alexandre Chagnes Gerard Cote Djamel Aliouche 《Applied biochemistry and biotechnology》2012,168(6):1459-1475
Chitosan/hydroxyapatite composite microparticles were prepared by a solid-in-water-in-oil emulsification cross-linking method. The characteristics and activity in presence of simulated body fluid for 14 and 21?days were investigated. The size distribution, surface morphology, and microstructure of these biomaterials were evaluated. The scanning electron microscopy revealed an aggregate of microparticles with a particle size, ranged from 4 to 10???m. The deposited calcium phosphate was studied using X-ray diffraction analysis, Fourier transform infrared spectroscopy, and inductively coupled plasma/atomic emission?spectroscopy analysis of phosphorus. These results show that the mineral, formed on microparticles, was a mixture of carbonated hydroxyapatite and calcite. Scanning electron microscopy revealed that calcium phosphate crystals growth was in form of rods organized as concentric triangular packets interconnected to each other by junctions. Interaction between chitosan and growing carbonated hydroxyapatite and calcite crystals are responsible for a composite growth into triangular and spherical shapes. The results demonstrated that these microparticles were potential materials for bone repair. 相似文献
97.
Melanie Schnell Dr. Gerard Meijer Prof. Dr. 《Angewandte Chemie (International ed. in English)》2009,48(33):6010-6031
Research with cold molecules has developed rapidly in recent years. There is now a variety of established methods for cooling molecules into the millikelvin range. Nevertheless, a focal point of current research is directed toward finding new ways to bring the temperature of molecules even closer to absolute zero. Samples of cold molecules offer not only important applications for high‐resolution spectroscopy, which benefit from the increased interaction time of slow molecules with electromagnetic radiation; they also promise access to an exotic regime of chemical reactivity, in which phenomena such as quantum tunneling and quantum resonances predominate. This review begins with an introduction to the methods by which cold molecules can be prepared, with special emphasis on Stark deceleration and traps. In addition to applications of cold molecules that have already been partially achieved, an important focus of the review concentrates on possible future applications, and both aspects are illustrated with selected examples. 相似文献
98.
Sipke H. Wadman Remco W.A. Havenith Robertus J.M. Klein Gebbink Gerard van Koten 《Journal of organometallic chemistry》2008,693(19):3188-3190
The nature of the first excited state of [Fe(terpyridine)2]2+ has been reinvestigated. In contrast to previous findings, it is metal-to-ligand charge transfer in nature, thus fitting in the series of the Ru and Os complexes. 相似文献
99.
100.