全文获取类型
收费全文 | 4611篇 |
免费 | 729篇 |
国内免费 | 619篇 |
专业分类
化学 | 3069篇 |
晶体学 | 72篇 |
力学 | 310篇 |
综合类 | 59篇 |
数学 | 713篇 |
物理学 | 1736篇 |
出版年
2024年 | 15篇 |
2023年 | 95篇 |
2022年 | 164篇 |
2021年 | 196篇 |
2020年 | 213篇 |
2019年 | 176篇 |
2018年 | 196篇 |
2017年 | 209篇 |
2016年 | 214篇 |
2015年 | 213篇 |
2014年 | 262篇 |
2013年 | 346篇 |
2012年 | 398篇 |
2011年 | 412篇 |
2010年 | 279篇 |
2009年 | 307篇 |
2008年 | 309篇 |
2007年 | 262篇 |
2006年 | 287篇 |
2005年 | 201篇 |
2004年 | 139篇 |
2003年 | 118篇 |
2002年 | 124篇 |
2001年 | 93篇 |
2000年 | 88篇 |
1999年 | 94篇 |
1998年 | 79篇 |
1997年 | 65篇 |
1996年 | 68篇 |
1995年 | 52篇 |
1994年 | 46篇 |
1993年 | 37篇 |
1992年 | 35篇 |
1991年 | 33篇 |
1990年 | 37篇 |
1989年 | 16篇 |
1988年 | 12篇 |
1987年 | 13篇 |
1986年 | 8篇 |
1985年 | 7篇 |
1983年 | 7篇 |
1982年 | 4篇 |
1981年 | 6篇 |
1980年 | 3篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1973年 | 2篇 |
1957年 | 2篇 |
1929年 | 2篇 |
1926年 | 2篇 |
排序方式: 共有5959条查询结果,搜索用时 28 毫秒
21.
研究结果表明,只有当以k>3)为奇数时,偶q相干态呈现振幅k次方压缩性质;无论k为偶数还是奇数,奇q相干态均不呈现压缩性质。 相似文献
22.
Angelika Jungmann R. Claessen R. Zimmermann Ge Meng P. Steiner S. Hüfner S. Tratzky K. Stöwe H. P. Beck 《Zeitschrift für Physik B Condensed Matter》1995,97(1):25-34
The electronic structure of the layered compounds LaI2 and CeI2 was investigated by photoemission and electron energy loss spectroscopy. From the experimental results we are able to confirm the metallic nature of these compounds, and by using photon energy dependent measurements of the valence band we can identify the orbital character of the conduction band as essentially 5d1-like. A detailed analysis of the Ce 3d and 4f spectra yields a remarkably small 4f-5d hybridization strength, almost completely decoupling the f-electron from the conduction band, which makes CeI2 a somewhat unusual system compared to other metallic Ce compounds. Band structure calculations by Jepsen and Andersen [1] confirm these experimental results. 相似文献
23.
The adsorption of L-alanine on Cu(111) surface is studied by means of scanning tunnelling microscopy under ultra-high vacuum conditions. The results show that the adsorbates are chemisorbed on the surface, and can form a two-dimensional gas phase, chain phase and solid phase, depending on deposition rate and amount. The adsorbed molecules can be imaged as individual protrusions and parallel chains in gas and chain phases respectively. It is also found that alanine can form (2 × 2) superstructure on Cu(111) and copper step facet to (110) directions in solid phase. On the basis of our scanning tunnelling microscopic images, a model is proposed for the Cu(111)(2 ×2)-alanine superstructure. In the model, we point out the close link between (110)-direction hydrogen bond chains with the same direction copper step faceting. 相似文献
24.
The dynamical properties of Rydberg hydrogen atom near a metal surface are presented by using the methods of phase space analysis
and closed orbit theory. Transforming the coordinates of the Hamiltonian, we find that the phase space of the system is divided
into vibrational and rotational region. Both the Poincaré surface of section and the closed orbit theory verify the same conclusion
clearly. In this paper we choose the atomic principal quantum number asn=20. The dynamical character of the exited hydrogen atom depends sensitively on the atom-surface distanced. Whend is sufficiently large, the atom-surface potential can be expressed by the traditional van der Waals force and the system
is integrable. Whend becomes smaller, there exists a critical valued
c. Ford>d
c, the system is near-integrable and the motion is regular. While chaotic motion appears ford<d
c, and the system tends to be non-integrable. The trajectories become unstable and the electron might be captured onto the
metal surface. 相似文献
25.
By using the continuation theorem of coincidence degree theory and constructing suitable Lyapunov functions, we study the existence, uniqueness, and global exponential stability of periodic solution for shunting inhibitory cellular neural networks with impulses, dx(ij)dt=-a(ij)x(ij)- summation operator(C(kl)inN(r)(i,j))C(ij) (kl)f(ij)[x(kl)(t)]x(ij)+L(ij)(t), t>0,t not equal t(k); Deltax(ij)(t(k))=x(ij)(t(k) (+))-x(ij)(t(k) (-))=I(k)[x(ij)(t(k))], k=1,2,...] . Furthermore, the numerical simulation shows that our system can occur in many forms of complexities, including periodic oscillation and chaotic strange attractor. To the best of our knowledge, these results have been obtained for the first time. Some researchers have introduced impulses into their models, but analogous results have never been found. 相似文献
26.
利用Matlab语言将EFIT程序反演计算过程进行优化整合,简化了程序操作步骤,并增加了对计算结果的分析与存储功能。利用整合后的 EFIT 程序,计算分析了 J-TXET 装置放电过程中等离子体磁场位形和其它参数的演变,绘制了等离子体压强剖面图、等离子体电流密度和安全因子分布等磁面信息的重建结果。此外,还将反演结果与软X射线测算数据进行比对。结果表明,改善后的EFIT程序能够初步满足对实验放电的反演计算分析要求,为J-TXET装置的放电控制和运行提供重要的参考数据。 相似文献
27.
28.
A modified distorted-wave Born approximation (DWBA) method is used to calculate the triple differential cross sections (TDCSs) in a coplanar asymmetric geometry for the electron impact single ionization of a He (1s2) atom at intermediate and lower energies. The post-collision interaction and the polarization effect in (e, 2e) collisions of helium are considered in the calculations. The polarization potentials from the damping method and density functional theory (DFT) are compared. Theoretical results are compared with the recent experimental data. 相似文献
29.
In the search for novel natural products in plants, particularly those with potential bioactivity, it is important to efficiently distinguish novel compounds from previously isolated, known compounds, a process known as dereplication. In this study, electrospray ionization-multiple stage tandem mass spectrometry (ESI-MS(n)) was used to study the behaviour of 12 pregnane glycosides and genins previously isolated from Marsdenia tenacissima, a traditional Chinese medicinal plant, as a basis for dereplication of compounds in a plant extract. In addition to [M + Na](+) and [M + NH(4)](+) ions, a characteristic [M-glycosyl + H](+) ion was observed in full-scan mode with in-source fragmentation. Sequential in-trap collision-induced dissociation of [M + Na](+) ions from 11,12-diesters revealed consistent preferred losses of substituents first from C-12, then from C-11, followed by losses of monosaccharide fragments from the C-3 tri- and tetrasaccharide substituents. A crude methanol extract of M. tenacissima stems was analysed using high-performance liquid chromatography coupled to ESI-MS. Several previously isolated pregnane glycosides were dereplicated, and the presence of an additional nine novel pregnane glycosides is predicted on the basis of the primary and fragment ions observed, including two with a previously unreported C(4)H(7)O C-11/C-12 substituent of pregnane glycosides. This study is the first report of prediction of the structures of novel pregnane glycosides in a crude plant extract by a combination of in-source fragmentation and in-trap collision-induced dissociation and supports the usefulness of LC-ESI-MS(n) not only for dereplication of active compounds in extracts of medicinal plants but also for detecting the presence of novel related compounds. 相似文献
30.
LIU Ge LU YuanRong YIN XueJun ZHANG XiaoHu DU Heng JIANG PeiYong LI ZhongShan LI XiaoNi HE Yuan WANG Zhi GAO ShuLi YANG YaQing ZHU Kun YAN XueQing CHEN JiaEr YUAN YouJin XIA JiaWen ZHAO HongWei 《中国科学:物理学 力学 天文学(英文版)》2014,57(7):1311-1317
The 53.667 MHz continuous-wave heavy ion RFQ has been designed and manufactured for the SSC-LINAC project.This four-rod RFQ accelerates ions with maximum mass to charge ratio of 7 from 3.728 keV/u to 143 keV/u.Measurements have been carried out to check the RF performance of the cavity and the quality of the electric field.The S11 of the power coupler is adjusted to better than-44 dB,and the Q0 of the cavity is 6440.The quality of the electric field is evaluated by the perturbation method.The measurement procedure and data analysis will be discussed in detail.The error due to gravity of the perturbation bead has been corrected by averaging the fields in different quadrants.As a result,the unflatness of the electric field is±2.5%,and the dipole field component distributes from 0%to 20%in different longitudinal positions,which indicates the asymmetry of the quadrupole field.The unflatness of the quadrupole field distribution represents a good agreement with the simulation results.High power RF test and beam commissioning of the RFQ are on schedule in early 2014. 相似文献