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171.
Reetu Yadav Mulayam Singh Gaur Seema Bhadauria Anna N. Berlina Boris B. Dzantiev 《International journal of environmental analytical chemistry》2018,98(6):570-581
This article deals with the detection of Co(II) in real water sample using aptamer – reactant platform combination with activated Ag–Au alloy nanoparticles (NPs) by chemiluminescence (CL) method. CL is attributed to a catalytically enhanced decomposition of H2O2 by aptamer conjugated Ag–Au alloy NPs to produce reactive oxygen species. The Ag–Au alloy NPs were prepared by chemical method using double reducing agent (i.e. trisodium citrate and polyethylenimine) and used for detection of Co(II) from water by CL method. CL experiments were carried out with the variation of different parameters such as pH, concentration of luminol, concentration of H2O2 and Ag–Au alloy NPs. We found that Ag–Au alloy NPs have very good efficiency towards Co(II) detection. Analytical parameters and kinetics were studied in detail to know the nature and mechanism of CL in presence of aptamer conjugated Ag–Au alloy NPs. The linear range of the CL sensor of Co(II) is covered concentration from 0.01 to 10 µg/L with detection limit of 0.001 µg/L. The relative standard deviation for determination of Co(II) was 6.65 in 10 replicated measurements. CL method is first time applied to detect the Co(II) in real water samples at very low level using aptamer conjugated Ag–Au NPs as a catalyst. 相似文献
172.
Bhardwaj V Trabelsi K Singh JB Choi SK Olsen SL Adachi I Adamczyk K Asner DM Aulchenko V Aushev T Aziz T Bakich AM Barberio E Belous K Bhuyan B Bischofberger M Bondar A Bračko M Brodzicka J Browder TE Chen A Chen P Cheon BG Cho K Choi Y Dalseno J Doležal Z Eidelman S Epifanov D Gaur V Gabyshev N Golob B Haba J Hayasaka K Hayashii H Horii Y Hoshi Y Hou WS Hsiung YB Hyun HJ Iijima T Inami K Ishikawa A Iwabuchi M Iwasaki Y Iwashita T Joshi NJ Julius T Kang JH Kawasaki T Kiesling C Kim HO Kim JB 《Physical review letters》2011,107(9):091803
We report a study of B→(J/ψγ)K and B→(ψ'γ)K decay modes using 772×10? B ?B events collected at the Υ(4S) resonance with the Belle detector at the KEKB energy-asymmetric e(+)e(-) collider. We observe X(3872)→J/ψγ and report the first evidence for χ(c2)→J/ψγ in B→(X_{c ?cγ)K decays, while in a search for X(3872)→ψ'γ no significant signal is found. We measure the branching fractions, B(B(±)→X(3872)K(±))B(X(3872)→J/ψγ)=(1.78(-0.44)(+0.48)±0.12)×10(-6), B(B(±)→χ(c2)K(±))=(1.11(-0.34)(+0.36)±0.09)×10(-5), B(B(±)→X(3872)K(±))B(X(3872)→ψ'γ)<3.45×10? (upper limit at 90% C.L.), and also provide upper limits for other searches. 相似文献
173.
The temperature dependence of Gibb's free energy difference (ΔG), entropy difference (ΔS) and enthalpy difference (ΔH) between the undercooled melt and the corresponding equilibrium solid phases of bulk metallic glass (BMG) forming melts has been proved to be very useful in the study of their thermodynamical behavior. The present study is made by calculating ΔG, ΔS and ΔH in the entire temperature range Tm (melting temperature) to Tg (glass transition temperature) for three Zr-based samples of BMGs: Zr57Cu15.4Ni12.6Al10Nb5, Zr41.2Ti13.8Ni10Cu12.5Be22.5 and Zr58.5Cu15.6Ni12.8Al10.3Nb2.8. The study is made on the basis of Taylor's series expansion and a comparative study is also performed between the present result and the result obtained in the framework of expansions proposed by earlier workers, and also with the experimental results. An attempt has also been made to study the glass forming ability for BMGs. 相似文献
174.
Bhupendra Singh Rathore Mulayam Singh Gaur Kripa Shanker Singh 《Journal of Thermal Analysis and Calorimetry》2013,111(1):647-653
Swift heavy ion beam irradiation induces modification in the dielectric properties and surface morphologies of polycarbonate (PC) films. The PC films were irradiated by 55 MeV energy of C5+ beam at various ions fluences ranging from 1 × 1011 to 1 × 1013 ions cm?2. The dielectric properties (i.e., dielectric constant, dielectric loss, and AC conductivity) and surface morphologies of pristine and SHI beam irradiated PC films were investigated by dielectric measurements, atomic force microscopy (AFM), and optical microscopy. The dielectric measurements show that the dielectric constant, dielectric loss, and AC conductivity increase with ion fluences and temperature, however, the dielectric constant and AC conductivity decrease while dielectric loss increases with frequency. AFM shows the increase in average roughness values with ion fluences. The change of color in PC films has been observed from colorless to yellowish and then dark brown with increases of ion fluence by using optical microscopy. 相似文献
175.
We carried out the heat capacity calculation of the magnetoresistance compounds EuMnO3 and Eu0.7A0.3MnO3 (where A=Ca and Sr) as a function of temperature from 5 to 100 K, using the Rigid Ion Model (RIM). The results on heat capacity for EuMnO3 and Eu0.7A0.3MnO3 (A=Ca and Sr) obtained by us are in good agreement with the measured values. Although strong electron–phonon interactions are present in these compounds but the lattice part of the specific heat also deserves proper attention. The parent compound EuMnO3 exhibits two magnetic transitions at 35 and 47 K due to weak ferromagnetic (FM) component and antiferromagnetic (AF) ordering. In addition, we have reported cohesive energy (φ), molecular force constant (f), compressibility (β), Restrahalen frequency (υ0), Debye temperature (θD) and Gruneisen parameter (γ) in the temperature range 5 K?T?100 K. 相似文献
176.
We report on the specific heat C(T) of doped manganites Nd0.5Sr0.5MnO3, Nd0.5Ca0.5MnO3, Sm0.5Ca0.5MnO3, Dy0.5Ca0.5MnO3 and Ho0.5Ca0.5MnO3 in the temperature range 2?T?300 K using modified rigid ion model (MRIM). The present specific heat results are in general satisfactory agreement with experimental data except at very low temperatures (i.e. T?12 K). Also a sharp peak observed in the experimental results for these compounds around 5 K could not be revealed by our computed results as they arise due to Schottky-like anomaly. Besides, we have reported the cohesive and the thermal properties of these compounds. The results obtained by us are discussed in detail. 相似文献
177.
Jaya Lohani Manoj Gaur Upendra Kumar V. R. Balakrishnan Harsh S. V. Eswaran 《中国物理快报》2010,27(4):234-237
In order to conduct electrical studies on organic thin film transistors, top-contact devices are fabricated by growing polycrystalline films of freshly synthesized pentacene over Si/SiO2 substrates with two different channel widths under identical conditions. Reasonable field effect mobilities in order of 10^-2-10^-3 cm^2V^-1s^-1 are obtained in these devices. An elaborative electrical characterization of all the devices is undertaken to study the variance in output saturation current, field effect mobility, and leakage current with aging under ambient conditions. As compared to the devices with longer channel width, the devices with shorter channel width exhibit better electrical performance initially. However, the former devices sustain the moderate performance much longer than the latter ones. 相似文献
178.
Kushwah Mamta Yadav Reetu Berlina Anna N. Gaur Karuna Gaur M. S. 《Journal of Solid State Electrochemistry》2023,27(3):559-574
Journal of Solid State Electrochemistry - The present work is performed on Pb2+ detection via electrochemical sensor. The novel aptasensor was developed by modification of glassy carbon... 相似文献
179.