Large second-order optical nonlinearities of s-triazine derivatives: View from micro molecules to macro crystals

Organic nonlinear optics (NLO) is also called mo-lecular nonlinear optics. In recent years organic mate-rials have been intensively studied because of their large NLO coefficients and structural diversities[1―3]. Second harmonic generation (SHG) is a bas…     

颗粒速度在颗粒流稀疏流-密集流转变中的作用

用实验和计算模拟的方法研究了颗粒流中的颗粒速度与颗粒流特性的关系.实验研究发现当入口流量固定时，在出口上方高速运动的颗粒会使颗粒流由稀疏流向密集流转变的临界出口尺寸变小.当颗粒流转变为密集流后，颗粒速度的作用被出口上方的颗粒堆积区所消耗，最终变得与颗粒速度无关.二维分子动力学模拟计算得到了与实验相同的结论.通过二维分子动力学模拟计算，还给出了不同颗粒速度下体系的密度和速率在空间的分布图.这些分布图显示随着颗粒到达出口上方的瞬间速度的不同，颗粒堆积区的密度和高度均会改变，并最终导致颗粒流流动状态的改变. 关键词： 颗粒流 颗粒气体 分子动力学模拟     

von Neumann代数中套子代数上的Lie同构

本文给出因子von Neumann代数中的幂等算子在广义Lie积下的一个刻画; 得到因子von Neumann代数中套子代数的幂等算子在Lie积下的一个特征．作为应用, 研究了因子von Neumann代数中套子代数上的Lie同构,并证明因子von Neumann 代数中套子代数之间的Lie同构,要么是同构与广义迹之和,要么是负反同构与广义迹之和．     

GPS/SINS组合导航系统在运载火箭中的应用

针对运载火箭特点,着重研究在发射惯性坐标系下,位置、速度组合模式的GPS/SINS组合导航算法,推导了该坐标系下的惯导一阶误差传播方程,建立了该坐标系下GPS/SINS组合导航系统的状态方程和观测方程,并进行了相关数学仿真验证。仿真结果表明,在该坐标系中,GPS/SINS组合导航算法能较准确地给出运载火箭的位置、速度和姿态信息,提高运载火箭制导精度。     

热力膨胀阀在空气源热泵热水器系统中稳定特性的实验研究

本文对热力膨胀阀在空气源热泵热水器的稳定特性进行了实验研究.通过不同热力膨胀阀开度下的实验数据,分析了热力膨胀阀在系统中的稳定特性.分析了热力膨胀阀在空气源热泵热水器全年运行工况中存在的局限性.提出保证系统稳定运行的方法与建议;指出制冷剂充注量是系统稳定运行的另一个重要因素,只有同时很好地把握住热力膨胀阀开度和制冷剂充注量,才可能使系统运行在最佳工况.     

Boiling heat transfer characteristics of nanofluids in a flat heat pipe evaporator with micro-grooved heating surface

An experimental study was performed to understand the nucleate boiling heat transfer of water–CuO nanoparticles suspension (nanofluids) at different operating pressures and different nanoparticle mass concentrations. The experimental apparatus is a miniature flat heat pipe (MFHP) with micro-grooved heat transfer surface of its evaporator. The experimental results indicate that the operating pressure has great influence on the nucleate boiling characteristics in the MFHP evaporator. The heat transfer coefficient and the critical heat flux (CHF) of nanofluids increase greatly with decreasing pressure as compared with those of water. The heat transfer coefficient and the CHF of nanofluids can increase about 25% and 50%, respectively, at atmospheric pressure whereas about 100% and 150%, respectively, at the pressure of 7.4 kPa. Nanoparticle mass concentration also has significant influence on the boiling heat transfer and the CHF of nanofluids. The heat transfer coefficient and the CHF increase slowly with the increase of the nanoparticle mass concentration at low concentration conditions. However, when the nanoparticle mass concentration is over 1.0 wt%, the CHF enhancement is close to a constant number and the heat transfer coefficient deteriorates. There exists an optimum mass concentration for nanofluids which corresponds to the maximum heat transfer enhancement and this optimum mass concentration is 1.0 wt% at all test pressures. The experiment confirmed that the boiling heat transfer characteristics of the MFHP evaporator can evidently be strengthened by using water/CuO nanofluids.     

A high-resolution MAS NMR study on the potential catalysts Mo/HBeta for olefin metathesis: The interaction of Mo species with HBeta zeolite

The interfacial interaction of Mo species with the HBeta zeolite was studied by multinuclear MAS NMR, XRD and N₂ adsorption. As proved by the quantitative ²⁷Al MAS NMR, this interaction is so strong as to dealuminate the framework of HBeta, and leads to a new peak appearing at −14 ppm, which indicates the formation of crystalline Al₂(MoO₄)₃. This can also be detected by XRD measurements when the Mo loading is as high as 9.0 wt.%. The corresponding quantitative ²⁹Si and ¹H MAS NMR spectra show that the amount of silanols and Brønsted acidic sites decrease obviously with increasing Mo loading. This also reveals an interaction between Mo species and HBeta support through an oxygen bridge resulting from condensation with the hydroxyls on the support. At higher Mo loadings, the interaction is so strong that it results in an extraction of aluminum from the zeolite framework, and subsequently appearance of Al₂(MoO₄)₃ and loss of Brønsted acidic sites. These can be correlated to the low catalytic activity of Mo/HBeta in metathesis of ethylene and 2-butylene to propylene.     

STRONG LAW OF LARGE NUMBERS AND ASYMPTOTIC EQUIPARTITION PROPERTY FOR NONSYMMETRIC MARKOV CHAIN FIELDS ON CAYLEY TREES

Some strong laws of large numbers for the frequcncies of occurrence of states and ordered couples of states for nonsymmetric Markov chain fields(NSMC)on Cayley trees are studied.In the proof,a new technique for the study of strong liinit theorems of Markov chains is extended to the case of Markov chain fields.The asymptotic equiparti- tion properties with almost everywhere(a.e.)convergence for NSMC on Cayley trees are obtained.     

DIRICHLET BOUNDARY VALUE PROBLEMS FOR SECOND-ORDER QUASI-LINEAR DIFFERENTIAL EQUATIONS WITH CHANGING SIGN NONLINEARITIES

This paper is concerned with the existence of positive solutions of two-point Dirichlet singular and nonsingular boundary problems for second-order quasi-linear differential equations with changing sign nonlinearities.