全文获取类型
收费全文 | 5348篇 |
免费 | 1224篇 |
国内免费 | 1471篇 |
专业分类
化学 | 3675篇 |
晶体学 | 193篇 |
力学 | 375篇 |
综合类 | 175篇 |
数学 | 591篇 |
物理学 | 3034篇 |
出版年
2024年 | 17篇 |
2023年 | 55篇 |
2022年 | 175篇 |
2021年 | 163篇 |
2020年 | 154篇 |
2019年 | 164篇 |
2018年 | 155篇 |
2017年 | 220篇 |
2016年 | 175篇 |
2015年 | 247篇 |
2014年 | 308篇 |
2013年 | 360篇 |
2012年 | 354篇 |
2011年 | 443篇 |
2010年 | 411篇 |
2009年 | 434篇 |
2008年 | 454篇 |
2007年 | 388篇 |
2006年 | 408篇 |
2005年 | 402篇 |
2004年 | 310篇 |
2003年 | 302篇 |
2002年 | 374篇 |
2001年 | 288篇 |
2000年 | 257篇 |
1999年 | 182篇 |
1998年 | 105篇 |
1997年 | 61篇 |
1996年 | 62篇 |
1995年 | 69篇 |
1994年 | 52篇 |
1993年 | 66篇 |
1992年 | 33篇 |
1991年 | 44篇 |
1990年 | 46篇 |
1989年 | 45篇 |
1988年 | 43篇 |
1987年 | 37篇 |
1986年 | 21篇 |
1985年 | 12篇 |
1984年 | 24篇 |
1983年 | 16篇 |
1982年 | 21篇 |
1981年 | 28篇 |
1980年 | 15篇 |
1979年 | 16篇 |
1978年 | 6篇 |
1976年 | 3篇 |
1965年 | 3篇 |
1936年 | 3篇 |
排序方式: 共有8043条查询结果,搜索用时 0 毫秒
41.
N-(α-Alkoxyalkyl)benzotriazoles were synthesized via the condensation of benzotriazole with various aldehydes and alcohols catalyzed by acidic ionic liquid [hmim]HSO4 at room temperature. The yield was up to 99%. This novel method was effective when triethoxymethane was utilized instead of alcohols. Moreover, acidic ionic liquid could be reused easily with no significant degradation of its catalytic activity. 相似文献
42.
水合醋酸铈直接热分解制备超细氧化铈及其抛光性能 总被引:3,自引:0,他引:3
Ultra fine ceria was prepared by calcining hydrate cerium acetate. The effects of pyrolysis temperature on the particle size, morphology, specific surface area and loose packing density of ceria were investigated, and the removal rate of optical glasses polishing by ceria was determined. The results show that with the increase of pyrolysis temperature, the loose deposit density and crystallinity increases and the specific surface area decreases, however, the particle size decreases firstly and then increases, the minimum medium particle size D50 is 0.47 μm at pyrolysis temperature of 1 000 ℃. The SEM images of ceria prepared by the decomposition at 800 ℃ or at 1 100 ℃ show porous powders or quasi-sphere small particles with loosely agglomeration, respectively. It was found that the removal rate varied with pyrolysis temperature in preparation of ceria and the property of glass polished. The removal rate for three kinds of glasses was in the order of ZF7> F1> K9, and the maximum value appeared at around 1 000 ℃ for ZF7 and F1, and at around 1 100 ℃ for K9. 相似文献
43.
顺磁性聚酯金属配合物的合成及其驰豫性能的研究 总被引:2,自引:0,他引:2
本文通过二乙三胺五乙酸(DTPA)或乙二胺四乙酸(EDTA)的双酸酐与二元醇或二元酚进行聚合反应,制备了两个系列共15种新的聚酯型大分子配体及其顺磁性金属配合物,用核磁、红外光谱以及元素分析表征了配体和配合物的结构。初步试验结果表明,与相应的小分子金属配合物相比,聚酯金属配合物具有较高的弛豫性能。 相似文献
44.
Y. Kobayashi S. Tokonami Y. Narazaki W. Zhuo M. Furukawa 《Journal of Radioanalytical and Nuclear Chemistry》2005,266(3):389-396
Summary Radon measurements were carried out in a Japanese wooden house built on granitic geology, where radon-rich well water is used.
Atmospheric radon concentrations were measured over one year with passive integrated radon monitors. The monitors were distributed
at several locations in the house and were replaced every two months. In order to confirm the diurnal variation and heterogeneous
distribution of radon, short-term measurements were carried out accordingly. Radon, its decay products and terrestrial gamma-radiations
were measured in this survey. From the long-term measurement, the radon concentration in the house ranged from 14 to 184 Bq. m-3with an arithmetic mean of 45 Bq. m-3. A radon concentration of 184 Bq. m-3was observed in the bathroom in spring (March-May) though the radon level was normal in the living room and bedroom. In order
to characterize the house, similar measurements were conducted in several surrounding houses. There was a significant difference
in radon concentration between the investigated houses. There was a spatial distribution of the radon concentration and the
highest value was found in the bathroom. Radon and its decay products concentrations varied with time, which increased from
midnight to morning whereas they decreased during daytime. Although the radon concentration in tap water was 1 Bq. l-1, a high level of 353 Bq. l-1was found in the well water.While well water was being used, the indoor radon concentration near the bathroom increased rapidly
with a maximum value of 964 Bq. m-3. It is clear that the use of well water enhanced the radon level around the bathroom. 相似文献
45.
层状锑磷酸嵌接式卟啉锰制备与模拟细胞色素氧化催化研究 总被引:1,自引:0,他引:1
层状锑磷酸嵌接式卟啉锰制备与模拟细胞色素氧化催化研究胡希明,皮宗新,梅治乾,古国榜,黄仲涛(华南理工大学应用化学系,华南理工大学化学工程系,广州,510641)关键词卟啉锰,层状锑磷酸,嵌接,催化性能细胞色素P450是一种含血红素的单充氧化酶,在室温... 相似文献
46.
Polymeric micelles based on amphiphilic diblock copolymers methoxy poly(ethylene glycol)-polylactide with various hydrophobic lengths were designed as carriers of poorly water-soluble anticancer drug methotrexate (MTX). Relationship between physicochemical characteristics of micelles and release behavior was explored. The critical micelle concentration was determined by fluorescence spectroscopy using 9-chloromethyl anthracene as fluorescence probe. Core-shell type polymeric micelles were prepared by free-surfactant dialysis technique. The mean size of micelles loaded with MTX was 50-200 nm with narrow polydispersity. Physicochemical properties of drug-loaded micelles were evaluated. In vitro release behavior of MTX was also investigated. MTX was continuously released from micelles and less than 50% MTX was released in 5 days. Release rate was dependent on chemical structures of micelles and enhanced by decreasing polylactide lengths. 相似文献
47.
48.
49.
50.
采用重量-容量法制备丙酮中除虫脲溶液标准物质。准确称量国家二级标准物质除虫脲溶解到色谱纯丙酮中,通过A级容量瓶定容至500 mL,摇匀后分装到2 mL安瓿瓶内共460瓶,每瓶为1 mL,保持低温迅速封口,配制过程中室温保持在(20±2)℃。采用液相色谱法进行均匀性、稳定性检验和定值结果验证。从样品中随机抽取16瓶进行均匀性检验,经F检验表明,在95%的置信区间范围内该标准物质均匀性良好;采用t检验对标准物质稳定性进行检验,标准物质在12月内稳定性良好。对该标准物质的不确定度进行了评定,研制的丙酮中除虫脲溶液标准物质定值结果为100μg/mL,相对扩展不确定度为2%(k=2)。结果表明,该标准物质均匀性与稳定性良好,量值准确,可用于日常分析检测中的方法评价和仪器校准。 相似文献