碘化亚铜微晶掺杂硅酸盐玻璃的制备及其光学性质

采用可分相的Na2O－Al2O3－B2O3－SiO2系为基础玻璃，以CuO／SnO、NaI为原料分别引入Cu＋、I－，成功地制备出CuI激晶掺杂硅酸盐玻璃．通过X射线粉末衍射（XRD）和高分辨透射电镜（HRTEM）分析观察到玻璃中的晶相和微晶的分布情况；由玻璃的室温透射光谱研究了玻璃的热处理条件与光吸收性的关系．实验发现，该玻璃对Nd：YAG激光器腔内自由振荡具有脉定压缩效应．     

Magnetic and magneto-optical properties of Cu-doped Bi,Ga:DyIG and Bi,Al:DyIG films prepared by sol-gel

Cu doped Bi,Al:DyIG and Bi,Ga:DyIG thin films have been prepared on glass substrates by sol-gel method. As-deposited films were amorphous, and after annealing polycrystalline magnetic thin films could be obtained. X-ray diffraction pattern showed that the films were garnet phase with no preferred crystal orientation. The H _c value of 7 kOe was obtained in Cu doped Bi, Al:DyIG films, and the Faraday rotation angle was about 7°/µm at the wavelength of 500 nm. An extremely high H _c value of 13 kOe at room temperature has been got in Bi, Ga:DyIG films, and the Faraday rotation angle was 8°/µm at the wavelength of 510 nm for the optimum value of Ga content. The perpendicular magnetic anisotropy (Ku) of garnet films on glass substrate resulted from the inverse magnetostriction. The influence of doping and garnet composition on magnetostriction has been studied. The mechanism of increasing coercive force by Cu doping could be attributed to Cu entering lattice sites.     

Spectroscopy of transition metal ions in inorganic glasses

Transition metal (TM) ions have been used as colouring agents in the glass industry for a long time. Recently, great attention has been paid to the TM ion doped glasses for the development of new lasers or luminescence materials. The absorption spectra of TM ions in different kinds of glasses have been studied extensively, but little work has been done for fluorescence and relaxation spectra. In this paper emphasis is laid on analysing the influence of chemical bond characteristics of the base glass on the spectra and the site structure of transition metal ions in glasses. Recent experimental results about the luminescence characteristics of low valence ions (such as Ti³⁺, Cr³⁺, V²⁺, Mn²⁺, Cu⁺, Mo³⁺) in glasses are also reported.     

Physical properties of glasses containing several glass-forming oxides

Physical properties, such as dielectric loss, acoustic velocity and electrical conductivity of glasses containing several glass-forming oxides were measured at temperatures in the range from −200°C to 200°C. The relationships between the structure and properties of the glasses, and the change in coordination number of individual glass-forming cations in alkali-containing glasses were analysed. It is shown that the glasses containing several glass-forming oxides are characterized by an inhomogeneous structure.     

Femtosecond Laser Induced Rewritable Optical Memory in Silicate Glasses

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Sb掺和对TeOx薄膜光学和静态记录特性的影响

以真空蒸镀法在K9玻璃基底上制备了TeO_x:Sb单层薄膜,对薄膜的结构、光学和静态记录特性进行了研究.结果表明,Sb掺和后TeO_x薄膜的结构、反射光谱和光学常量均发生了明显变化.TeO_x:Sb薄膜具有良好的写入灵敏性并具有了一定的可擦除性能,该类薄膜有望作为可擦除光存储介质.     

Optimization of Axial Intensity Point Spread Function

It is known that for the converged laser beam, the axial intensity distribution corresponds to a Gaussian curve, that is, the intensity on the focal plane is the peak intensity. When it defocuses, the intensity would decrease rapidly. In optical data storage, for instance, we expect the intensity within a certain distance to be almost equal. In this paper, we propose to use a pure phase superresolution apodizer to optimize the axial intensity distribution of the converged laser beam and at the same time improve the resolution. The intensity point spread function remains almost identical in a wide range within the focal depth.     

酞菁掺杂有机改性溶胶凝胶材料的自衍射及限幅特性

实验测得八异戊氧基钯酞菁掺杂有机改性溶胶－凝胶固体材料在Ar^ 激光作用下形成的大的与光强相关的多环衍射图案。研究了不同波长下的光学限幅特性,由于其大的光学限幅效应及其固体的可加工性,这种材料在制备光学限幅器件方面具有潜在的应用前景。     

原子力显微镜对TeOx薄膜中短波长静态记录点结构的分析

以真空蒸镀法在K9基底上制备了TeOx单层薄膜,采用特定的定位方法,使用原子力显微镜对不同记录功率下薄膜中短滤长静态记录点（514．5nm)的结构进行了分析。实验结果表明薄膜具有良好的记录灵敏性,在记录功率1．5mW时就可产生较高的反射率对比度,记录点具有明显的凹陷和凸起结构,随着记录功率的提高,凹陷和凸起增强,记录点增大。记录点的形态结构和记录前后反射率对比度是直接相关的。研究揭示了原子力显微镜在提高薄膜存储特性如信噪比,存储密度等方面的分析功能。     

Synthesis, spectral and thermal properties of some transition metal(II) complexes with a novel ligand derived from thiobarbituric acid

Four novel metal(II) complexes, Ni(L)₂, Co(L)₂, Cu(L)₂, and Zn(L)₂ (L = 5-(2-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)hydrazono)-1,3-diethyl-2-thioxo-dihydropyrimidine-4,6(1H,5H)-dione), were synthesized using the procedure of diazotization, coupling and metallization. Their structures were identified by elemental analyses, ¹H NMR, ESI-MS and FT-IR spectra. The effect of different central metal(II) ions on absorption bands of the metal(II) complexes was researched. The thermal properties of the metal(II) complexes were investigated by thermogravimetry (TG) and differential scanning calorimetry (DSC). Furthermore, the thermodynamic parameters, such as activation energy (E*), enthalpy (?H*), entropy (?S*) and free energy of the decomposition (?G*) are calculated from the TG curves applying Coats–Redfern method. The results show that the metal(II) complexes have suitable electronic absorption spectra with blue-violet light absorption at about 350–450 nm, high thermal stability with sharp thermal decomposition thresholds.