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71.
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74.
Khattabi S Cherrak DE Fischer J Jandera P Guiochon G 《Journal of chromatography. A》2000,877(1-2):95-107
Using single-step frontal analysis, we measured single-component and competitive adsorption isotherm data for the two enantiomers of 1-phenyl-1-propanol (PP). These experimental data were fitted to several competitive bi-Langmuir models (with 8, 6, 5 and 4 parameters) and to the competitive Langmuir model. The latter model accounted well for the behavior of both PP enantiomers on Chiracel OB (cellulose tribenzoate coated on silica gel). The parameters obtained were used in numerical calculations to predict the band profiles of the two single components and of their mixtures under overloaded conditions. The equilibrium-dispersive model provides satisfactory results, with minor differences between the calculated and the experimental profiles. These differences became negligible when a more complex kinetic model was used, with a concentration-dependent rate coefficient. 相似文献
75.
K. Torkar G. W. Herzog W. Schintlmeister Dieter Fischer 《Monatshefte für Chemie / Chemical Monthly》1967,98(2):245-253
It is shown that in the case of thermal decomposition of sodium azide the overall kinetics can be predicted by defined particle size of the decomposed sodium azide crystals. This is always the case if the rate constant is a function of the particle size. Hence this special example can be generalized for similar decomposition reactions. It is necessary that the particles decompose independently which could be proved experimentally with sodium azide. If for this reason we state for true that the pressure/time-function of each particle size add together it is possible to set up a formula for the pressure/time-function of any particle size distribution. With the pressure/time function holding for sodium azide of uniform particle size, the total function for a Gauß distribution can be calculated exactly. Moreover, the trivial case of one single particle size and the case of two different particle sizes are discussed. Furthermore an approximation method for any arbitrary pressure/time-functions and distribution by means of “Schwerpunktdeutung” are discussed which can be carried out graphically as well as numerically. The numerical approximation is illustrated by an example. Pressure/time-functions then loose their characteristic form because of their dependence on the particle size distributions under consideration. In this case, reaction mechanism cannot be derived from pressure/time functions. 相似文献
76.
Walter Fischer Cyril A. Grob Reinhard Hanreich Georg von Sprecher Adrian Waldner 《Helvetica chimica acta》1981,64(7):2298-2311
The solvolysis rates and products of the 6-exo-substituted 2-exo- 1a - 1u , and 2-endo-norbornyl p-toluenesulfonates 2a - 2u , have been determined. In general, the rate constants for 1 and 2 (log k) correlate well with the inductive constants σ of the substitutents at C(6); however, their sensitivity to σ is much larger in the 2-exo-series 1 than in the 2-endo-series 2 . This differential transmission of polar effects is the cause of decreasing 2-exo/2-endo rate ratios from 2388 for R = t-C4H9 to 0.37 for R = Br, i. e. with increasing electron attraction by the substituent. The high sensitivity of the rate constants for the 2-exo-p-toluenesulfonates 1 to σ indicates an unusually strong inductive interaction between C(6) and the incipient cationic center at C(2). This interaction is ascribed to the participation of the pentacoordinate C(6)-atom, i. e. to 1,3-bridging, a consequence of steric hindrance of nucleophilic solvent participation in norbornanes. Donor substituents enhance 1,3-bridging, lead to faster reactions and to the formation of 2-exo substitution products. Conversely, acceptor substituents reduce 1,3-bridging, decrease rates and facilitate the formation of 2-endo substitution products. Graded 1,3-bridging is discussed in the light of Winstein's nonclassical ion concept. 相似文献
77.
R. Fischer 《Mikrochimica acta》1939,26(3):255-263
Zusammenfassung Es wird ein Verfahren beschrieben, mit dem geringste Mengen Veronal in Blut und Liquor bestimmt werden können. Das Untersuchungsmaterial wird mit einer sauren Pufferlösung versetzt, um das Ausfallen des Bluteiweißes zu verhindern, und das Veronal im Perforator mit Äther extrahiert. Der Ätherextrakt wird nach der Trocknung mit Kohle und Magnesiumoxyd gereinigt, filtriert, im Schälchen verdunstet und der Rückstand im Sublimationsapparat der quantitativen Sublimation unterworfen. Die Mikrosublimate werden auf der Mikrowaage gewogen. Der zur Extraktion verwendete Äther muß sorgfältig gereinigt werden. Die Fehlergrenze beträgt 2,5 bis 6,7% bei Blut (verwendet wurde Menschen-, Rinder- und Katzenblut) und 2,5 bis 4,8% bei Liquor, wenn Mengen von 70 bis 300 Veronal Verwendung fanden. Durch dieses Verfahren ist die Möglichkeit gegeben, abgesehen von tierexperimentellen Untersuchungen bei Vergiftungsfällen aus den in Liquor und Blut gefundenen Veronalmengen Schlüsse auf die Höhe der verabreichten Dosis zu ziehen.Im Anschluß daran wird eine Trennung von Veronal und Bernsteinsäure mit Hilfe von Adsorptionsmitteln beschrieben.
Summary A procedure is described which renders possible the determination of minimal amounts of veronal in blood and liquor cerebrospinalis (spinal fluid). The material under examination is treated with an acid buffer solution to prevent separation of albumen from the blood, and the veronal extracted with ether. The extract, after drying, is purified by treatment with charcoal and magnesia, filtered, the filtrate evaporated, and the residue sublimed quantitatively in a sublimation apparatus, the sublimates obtained being weighed on a micro-balance. It is necessary that only very carefully purified ether be used for the extraction. The limits of error range between 2,5 to 6,7% in the case of blood (blood from cattle, cats, and human beings was investigated) and between 2,5 to 4,8% in the case of liquor cerebrospinalis (spinal fluid); in all cases quantities of veronal ranging from 70 to 300 were involved. The above procedure enables conclusions to be drawn (quite apart from vivisection experiments), from the quantities of veronal found in the liquor and blood as to the magnitude of the original dose of the drug.A separation of veronal from succinic acid with the help of adsorption agents is also given in the paper.
Résumé On décrit un procédé à l'aide duquel on peut déterminer les plus petites quantités du véronal dans le sang et dans le liquor. On ajoute une solution tampon (Pufferlösung) acide à la matière à essayer, pour éviter la précipitation des protéines du sang et on extrait le véronal au perforateur. L'extrait d'éther est purifié après séchage avec du charbon et d'oxyde de magnésium, filtré, évaporé en petite capsule et sublimé quantitativement dans l'appareil de sublimation. Les micro-sublimés sont pesés sur la microbalance. L'éther, employé pour l'extraction, doit être purifié très exactement. La limite d'erreurs est de 2,5 à 6,7% analysant le sang (on a essayé du sang d'homme, de vache et de chat) et de 2,5 à 4,8% analysant le liquor, quand on avait appliqué de 70 à 300 de véronal. Il est possible de calculer ainsi de la quantité de véronal, trouvée dans le sang ou dans le liquor, la dose administrée chez des intoxications.A cet occasion on décrit encore la séparation du véronal de l'acide succinique à l'aide des moyens d'adsorption.相似文献
78.
Berthold Fischer Helmut W. Schmalle Markus R. Baumgartner Max Viscontini 《Helvetica chimica acta》1997,80(1):103-110
The first crystal structure of a molybdenum complex 9 with a hydrogenated pterin and a sulfur ligand contributes to the discussion about the active center of molybdenum and tungsten enzymes containing a molybdopterin cofactor. Complex 9 was synthesized through a redox reaction of [MoVIO2 (LN-S2)] ( 8 ; LN-S2 = pyridine-2, 6-bis(methanethiolato)) with 5, 6, 7, 8-tetrahydropterin ( 7 ). 2 HCl (H4Ptr.2 HCl). The complex crystallizes, with a non-coordinating Cl-atom acting as a counterion, in the monoclinic space group C2/c (No. 15) with cell dimensions a = 22.900(5), b = 10.716(2), c = 17.551(4) Å, β = 120.36(3)°, and Z = 8. We interpret 9 as [MoIVO(LN-S2)(H+-q-H2Ptr)]Cl (q = quinonoid; H2Ptr = dihydropterin), i.e., a MoIV monooxo center coordinated by a pyridine-2, 6-bis(methanethiolato) ligand and a protonated dihydropterin. The spectroscopic properties of this new complex are comparable to those of other crystalline molybdenum complexes of hydrogenated pterins without additional S-coordination. The slightly H2O-soluble complex 9 reacts with the natural enzyme substrate DMSO very slowly, possibly due to the lack of easily dissociable ligands at the metal center. 相似文献
79.
Breakstone A Crawley HB Dallavalle GM Doroba K Drijard D Fabbri F Firestone A Fischer HG Frehse F Geist W Giacomelli G Gokieli R Gorbics M Hanke P Heiden M Herr W Kluge EE Lamsa JW Lohse T Meyer WT Mornacchi G Nakada T Panter M Putzer A Rauschnabel K Rimondi F Siroli GP Sosnowski R Szczekowski M Ullaland O Wegener D 《Physical review letters》1985,55(20):2180-2183
80.