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One of the best approaches for modeling large deformation of shells is the Cosserat surface. However, the finite-element implementation of this model suffers from membrane and shear locking, especially for very thin shells. The basic assumption of this theory is that the mid-surface of the shell is regarded as a Cosserat surface with one inextensible director. In this paper, it is shown that by constraining the director vector normal to the mid-surface, besides very good and accurate results, shear locking is also eliminated. This constraint is in fact a limiting analysis of the Cosserat theory in which Kirichhoff’s hypothesis is enforced. Numerical solution is performed using nine-node isoparametric element. The principal of virtual work is used to obtain the weak form of the governing differential equations and the material and geometric stiffness matrices are derived through a linearization process. The validity and the accuracy of the method are illustrated by numerical examples. 相似文献
63.
Morteza Bahram Khalil Farhadi Farzin Arjmand 《Central European Journal of Chemistry》2009,7(3):524-531
A new differential pulse voltammetric method for dopamine determination at a bare glassy carbon electrode has been developed.
Dopamine, ascorbic acid (AA) and uric acid (UA) usually coexist in physiological samples. Because AA and UA can be oxidized
at potentials close to that of DA it is difficult to determine dopamine electrochemically, although resolution can be achieved
using modified electrodes. Additionally, oxidized dopamine mediates AA oxidation and the electrode surface can be easily fouled
by the AA oxidation product. In this work a chemometrics strategy, partial least squares (PLS) regression, has been applied
to determine dopamine in the presence of AA and UA without electrode modification. The method is based on the electrooxidation
of dopamine at a glassy carbon electrode in pH 7 phosphate buffer. The dopamine calibration curve was linear over the range
of 1–313 μM and the limit of detection was 0.25 μM. The relative standard error (RSE %) was 5.28%. The method has been successfully
applied to the measurement of dopamine in human plasma and urine.
相似文献
64.
A. Nilchi M. Ghanadi Maragheh A. Khanchi 《Journal of Radioanalytical and Nuclear Chemistry》2000,244(3):589-594
The disodium, dilithium, dipotassium and distrontium forms of cerium phosphate were prepared from their corresponding mono-forms. The chemical content of these inorganic ion exchangers have been characterized by inductively coupled plasma (ICP) spectroscopy. The ion exchange properties of these cation exchangers, their chemical stability and selectivity for certain ions were investigated. It was found that, by introducing different salts into the reaction mixture used to prepare cerium phosphate, robust cation exchange materials of reproducible composition with a good cation capacity, and suitable for column use, are produced. All the ion exchangers with the exception of CeP (dipotassium) show excellent selectivity towards certain cations, thereby increasing the potential practical applications of these inorganic exchangers. 相似文献
65.
Farzin Marandi Babak Mirtamizdoust Ali A. Soudi Veysel T. Yilmaz Canan Kazak 《无机化学与普通化学杂志》2006,632(15):2380-2382
A novel 1D polymeric lead(II) complex containing the first Pb2‐(μ‐N3)2 motif, [Pb(phen)(μ‐N3)(μ‐NO3)]n (phen = 1,10‐phenanthroline), has been synthesized and characterized. The single‐crystal X‐ray data showed the coordination number of Pb2+ ions to be eight (PbN4O4) with the Pb2+ ions having “stereo‐chemically active” electron lone pairs; the coordination sphere is hemidirected. The chains interact with each other via π‐π interactions to create a 3D framework. 相似文献
66.
The proposed research, presents the synthesis, characterization, and photocatalytic accomplishment of ZnO nanoplate (ZnOs) modified with activated carbon derived from Konar bark. The obtained nanocomposite (photocatalyst) was characterized by scanning electron microscopy (SEM), X‐ray diffraction (XRD), Raman spectroscopy, X‐ray photoelectron spectroscopy (XPS), and Brunauer–Emmett–Teller (BET). First, the ZnO photocatalyst and activated carbon (AC) were prepared separately; then, the ZnO photocatalyst was modified with activated carbon. Various parameters namely pH, degradation time, and photocatalyst dose were optimized and studied in multivariate method by design expert7 software. The synergic efficiency of ZnO‐AC (adsorbent/photocatalyst) exhibited a good rate of ciprofloxacin (CIP) removal under visible irradiation. In addition, first pseudo order kinetic and isotherms equations were calculated. Moreover, the identification of degradation products was performed by ultra performance liquid chromatography‐tandem mass spectrometer (UPLC‐MS/MS). It is for the first time that a ZnO photocatalyst modified with activated carbon (ZnO‐AC) applied for CIP degradation. 相似文献
67.
A nanocomposite composed of graphene oxide and magnetite (Fe3O4) was coated with the ionic liquid (IL) 1,3-didecyl-2-methylimidazolium chloride and used to capture and separate hemin from serum samples. The critical parameters affecting the extraction of analyte, such as pH, surfactant and adsorbent amounts, and desorption conditions were studied and optimized. Following magnetic separation and desorption with a 5:1 mixture of acetic acid and acetone, hemin (an iron porphyrin complex) was quantified by FAAS of iron. Under optimum conditions, the enrichment factor was 96. The calibration curve was linear in the 4.8 to 730 μg L?1 concentration range, the limit of detection was 3.0 μg L?1, and the relative standard deviations (RSDs) for single-sorbent repeatability and sorbent-to-sorbent reproducibility were less than 3.9 % and 10.2 % (n = 5), respectively. The adsorbent displayed adsorption capacity as high as 200 mg g?1, indicating IL-coated Fe3O4/GO to be a good sorbent for the adsorption of hemin. The method was validated by determining serum hemin in the presence of a large excess (480-fold) of Fe3+ without considerable interference. The results compare well to those obtained with a commercial hemin assay kit. The results show that this method can be successfully applied to the enrichment and determination of hemin in acid digested serum samples of breast cancer patients. 相似文献
68.
Farzin Rahmani Mina Mahdavi Sasan Nouranian Ahmed Al‐Ostaz 《Journal of Polymer Science.Polymer Physics》2017,55(13):1026-1035
Nonisothermal and isothermal decomposition of poly(ethylene oxide) (PEO) loaded with different concentrations of pristine graphene (PG) and graphene oxide (GO) nanoplatelets were investigated using reactive molecular dynamics simulation. The onset of nonisothermal decomposition of the PG‐loaded PEO system was the highest among all systems, suggesting that introducing PG to the polymer improves its thermal stability (an effect that increases with an increase in the PG concentration). At low concentration, introducing GO to the polymer brings about a deterioration of the thermal stability of the polymer consistent with experimental findings. On average, the activation energy for the isothermal decomposition of PG‐loaded PEO system increases by 60% over that of the neat PEO system, while it decreases by 40% for the GO‐loaded PEO system. A time‐dependent analysis of the through‐thickness decomposition profile of the above systems reveals that the polymer confined between the PG sheets exhibit a higher thermal stability compared to the bulk polymer. However, an opposite effect is observed with the polymer confined between the GO sheets. The latter observation is attributed to accelerated polymer chain scission in confined regions due to the ejection of reactive hydroxyl radicals from the GO surface during the early stages of thermal decomposition. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55, 1026–1035 相似文献
69.
Farzin Ghanadi Maziar Arjomandi Benjamin S. Cazzolato Anthony C. Zander 《Journal of Turbulence》2013,14(8):705-728
This study investigates the changes in the structure of a turbulent boundary layer downstream of a flow-excited Helmholtz resonator. To this end, a fully developed turbulent boundary layer over a resonator mounted flush with a flat plate was simulated by implementing a large eddy simulation (LES). To assist in understanding the effect of the resonator on the flow structure, a sensitivity study was undertaken by changing the main geometrical parameters of the resonator. The results demonstrated that when the boundary layer thickness equals the orifice length, the cross-stream component of velocity fluctuations penetrates the boundary layer, resulting in a reduction of the turbulence intensity by up to 12%. Therefore, it is concluded that a Helmholtz resonator has the potential to reduce the instabilities within the boundary layer. These investigations also assist in identifying the optimal parameters to delay turbulence events within the grazing flow using Helmholtz resonators. 相似文献
70.
Farhad Haji Aboutalebi Mahmoud Farzin Mohammad Mashayekhi 《Acta Mechanica Solida Sinica》2012,25(6):638-650
Prediction of forming limit in sheet metal forming is among the most important challenges confronting researchers. In this paper, a fully coupled elastic-plastic-damage model has been developed and implemented into an explicit code. Due to the adoption of the plane stress and finite strain theories, model can predict deformation and damage of parts quickly and accurately. Also, damage initiation, propagation, and fracture in some operations are predicted and validated with experiments. It is concluded that finite strain combined with continuum damage mechanics can be used as a quick tool to predict ductile damage, fracture, and forming limits in sheet metal forming processes. 相似文献