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61.
Hashem Azizi Alireza Khorshidi Khalil Tabatabaeian 《Journal of the Iranian Chemical Society》2018,15(5):1023-1032
A family of 3,4-dihydropyrano[3,2-c]chromenes were synthesized from 4-hydroxycoumarin and malononitrile via a one-pot reaction under solvent-free conditions at 100 °C catalyzed by Ni@Imine-Li+-MMT. This methodology tolerates most of the substrates and has the merits of lower loading of the catalyst, absence of solvents, excellent yields and reusability of the catalyst. A reasonable mechanism is also proposed. This catalytic system can be reused for at least five times with a negligible loss of activity. The prepared catalyst was characterized by using FTIR, TGA, SEM, TEM, uv-DRS, EDX and XRD. 相似文献
62.
63.
Umar Farid Maria Luisa Aiello Prof. Stephen J. Connon 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(43):10074-10079
A new catalytic methodology was developed to promote an efficient one-pot kinetic resolution of racemic aldehydes with selectivity (s*) of up to 91 (99:1 d.r., >99 % ee) in a cycloaddition reaction with enolizable anhydrides to afford dihydroisocoumarin products (a core prevalent in natural products and molecules of medicinal interest) containing three contiguous stereocentres. 相似文献
64.
Abd-Rabbou M. Y. Khalil E. M. Ahmed M. M. A. Obada A.-S. F. 《International Journal of Theoretical Physics》2019,58(12):4012-4024
International Journal of Theoretical Physics - The interaction between a moving two-level atom and squeezed coherent states in the presence of Kerr like medium and an external classical field is... 相似文献
65.
Will R. Henderson Ajeet Kumar Dr. Khalil A. Abboud Prof. Ronald K. Castellano 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(72):17588-17597
Reported here is the synthesis and self-assembly characterization of [n.n]paracyclophanes ( [n.n]pCps , n=2, 3) equipped with anilide hydrogen bonding units. These molecules differ from previous self-assembling [n.n]paracyclophanes ( [n.n]pCps ) in the connectivity of their amide hydrogen bonding units (C-centered/carboxamide vs. N-centered/anilide). This subtle change results in a ≈30-fold increase in the elongation constant for the [2.2]pCp -4,7,12,15-tetraanilide ( [2.2]pCpNTA ) compared to previously reported [2.2]pCp -4,7,12,15-tetracarboxamide ( [2.2]pCpTA ), and a ≈300-fold increase in the elongation constant for the [3.3]pCp -5,8,14,17-tetraanilide ( [3.3]pCpNTA ) compared to previously reported [3.3]pCp -5,8,14,17-tetracarboxamide ( [3.3]pCpTA ). The [n.n]pCpNTA monomers also represent the reversal of a previously reported trend in solution-phase assembly strength when comparing [2.2]pCpTA and [3.3]pCpTA monomers. The origins of the assembly differences are geometric changes in the association between [n.n]pCpNTA monomers—revealed by computations and X-ray crystallography—resulting in a more favorable slipped stacking of the intermolecular π-surfaces ( [n.n]pCpNTA vs. [n.n]pCpTA ), and a more complementary H-bonding geometry ( [3.3]pCpNTA vs. [2.2]pCpNTA ). 相似文献
66.
Zerrouki Abdelkhalek Abrigach Farid Taleb Mustapha El Kadiri Sghir 《Research on Chemical Intermediates》2020,46(2):1453-1467
Research on Chemical Intermediates - A class of novel multi-tripodal ligands has been prepared via condensation reaction between pyrazole or triazole moieties and... 相似文献
67.
Nehal F. Farid Ibrahim A. Naguib Nessreen S. Abdelhamid Basma H. Anwar Maimana A. Magdy 《Journal of separation science》2020,43(12):2330-2337
A novel ecofriendly, cost and time saving high‐performance thin‐layer chromatographic method was developed and validated for simultaneous determination of metoclopramide, ergotamine, caffeine, and paracetamol in bulk and pharmaceutical formulation. The separation was carried out on silica gel plates, using ethyl acetate:ethanol:ammonia (9:1:0.1, v/v/v) as a developing system. Ultraviolet detection was carried out at 272 nm. The resulting retention times were 0.15, 0.36, 0.49, and 0.74 min for metoclopramide, ergotamine, caffeine, and paracetamol, respectively. The greenness profile assessment was achieved to the proposed method to evaluate its greenness characters to the environment with acceptable results. Validation parameters were checked according to International Conference of Harmonization guidelines to achieve the international requirements for quality control analysis of the proposed drugs. 相似文献
68.
69.
Ying Li Anne Sylvie Fabiano-Tixier Valérie Tomao Giancarlo Cravotto Farid Chemat 《Ultrasonics sonochemistry》2013,20(1):12-18
A green, inexpensive and easy-to-use method for carotenoids extraction from fresh carrots assisted by ultrasound was designed in this work. Sunflower oil was applied as a substitute to organic solvents in this green ultrasound-assisted extraction (UAE): a process which is in line with green extraction and bio-refinery concepts. The processing procedure of this original UAE was first compared with conventional solvent extraction (CSE) using hexane as solvent. Moreover, the UAE optimal conditions for the subsequent comparison were optimized using response surface methodology (RSM) and ultra performance liquid chromatography – diode array detector – mass spectroscopy (UPLC–DAD–MS). The results showed that the UAE using sunflower as solvent has obtained its highest β-carotene yield (334.75 mg/l) in 20 min only, while CSE using hexane as solvent obtained a similar yield (321.35 mg/l) in 60 min. The green UAE performed under optimal extraction conditions (carrot to oil ratio of 2:10, ultrasonic intensity of 22.5 W cm?2, temperature of 40 °C and sonication time of 20 min) gave the best yield of β-carotene. 相似文献
70.
Let R be a commutative ring with 1 ≠ 0, G be a nontrivial finite group, and let Z(R) be the set of zero divisors of R. The zero-divisor graph of R is defined as the graph Γ(R) whose vertex set is Z(R)* = Z(R)?{0} and two distinct vertices a and b are adjacent if and only if ab = 0. In this paper, we investigate the interplay between the ring-theoretic properties of group rings RG and the graph-theoretic properties of Γ(RG). We characterize finite commutative group rings RG for which either diam(Γ(RG)) ≤2 or gr(Γ(RG)) ≥4. Also, we investigate the isomorphism problem for zero-divisor graphs of group rings. First, we show that the rank and the cardinality of a finite abelian p-group are determined by the zero-divisor graph of its modular group ring. With the notion of zero-divisor graphs extended to noncommutative rings, it is also shown that two finite semisimple group rings are isomorphic if and only if their zero-divisor graphs are isomorphic. Finally, we show that finite noncommutative reversible group rings are determined by their zero-divisor graphs. 相似文献