a-C:F薄膜的热稳定性与光学带隙的关联

以CF4和C6H6的混合气体作为气源,在微波电子回旋共振化学气相沉积(ECRCVD)装置中制备了氟化非晶碳薄膜(aC:F),并在N2气氛中作了退火处理以考察其热稳定性.通过傅里叶变换红外吸收谱和紫外可见光谱获得了薄膜中CC双键的相对含量和光学带隙,发现膜中CC键含量与光学带隙之间存在着密切的关联,在高微波功率下沉积的氟化非晶碳膜具有低的光学带隙和较好的热稳定性. 关键词： 氟化非晶碳膜 光学带隙 退火温度 热稳定性     

组合证券投资的概率准则模型探讨

在基于概率准则的组合证券模型下，把实现一定收益率水平目标的概率优化模型的求解转化成易于求解的非线性规划问题，从而方便地得出模型的解及其意义；提出了概率准则下的β值组合证券投资决策模型，研究了它们解的存在性和求解的公式，并给出了上海股市股票的数值算例。     

时变线性系统特征根判稳的推广

本文研究了二维时变线性系统零解的稳定性，给出了一些允许系数矩阵主对角元变号，系数矩阵特征根变号的判定稳定性的充分条件。     

Electron–hole complexes in self-assembled quantum dots in strong magnetic fields

We present results of calculations and experiments on electron–hole complexes in InGaAs/GaAs self-assembled quantum dots in high magnetic field (B). Due to hidden symmetries, the chemical potential of an N-exciton system at special B fields becomes insensitive to the exciton number as well as the magnetic field. This results in plateau regions of high intensity in measured magneto-PL spectrum. Theoretical calculations using exact diagonalization techniques successfully explain the measured magneto-photoluminescence spectrum with B fields up to 28 T.     

一种不等带宽光学梳状滤波器

提出了一种新型—Michelson—三面镜FabryPerot型50GHz不等带宽光学梳状滤波器设计方案,分析和模拟表明:该器件将一路信道间隔为50GHz的输入信号分离成信道间隔为100GHz的奇偶两路输出信号,其中在3dB处,奇数信道带宽大于30GHz用于10Gb/s传输,偶数信道带宽大于60GHz用于40Gb/s传输对于将来的40Gb/s系统,该器件具有优势.     

Vacuum System for HL-2A Tokamak

The vacuum system of today＇s tokamak devices is designed to meet the operational requirements of the experiments. The operation can be divided into five modes, （1） pumping down and leak detecting of the vacuum vessel, （2） baking, （3） plasma-facing component （PFC） conditioning, （4）evacuating and controlling of the particles at plasma edge, （5） plasma discharge experiments.     

A lithium ethyl­ene­diphos­phon­ate containing lithium chains and symmetric hydrogen bonds

In the title compound, catena‐poly[lithium‐μ₃‐ethyl­ene­diphos­phon­ato], [Li(C₂H₇O₆P₂)]_n, the supra­molecular monoclinic (C2/c) structure consists of one‐dimensional lithium chains [Li⋯Li = 2.7036 (8) Å] that are embedded within ethyl­ene­diphosphon­ate anions linked by strong symmetric hydrogen bonds [O⋯O = 2.473 (3) Å]. The Li atoms and the H atom in the symmetric hydrogen bond reside on twofold rotation axes and there is an inversion center at the mid‐point of the C—C bond of the ethylenediphosphonate ligand.     

SPME-GC-MS快速分析炼油厂废水中痕量VOCs

采用固相微萃取-气相色谱-质谱联用(SPME-GC-MS)对炼油厂废水中痕量挥发性有机化合物(VOCs)进行了定性分析,简化了预处理过程,总分析时间为1h左右.对比处理前后的废水样品的MS定性结果,为废水处理工艺的评价以及有机物降解机理提供了依据.     

Synthesis,structure, spectroscopic and magnetic properties of a novel two-dimensional copper(II) complex Na2[Cu(pba)] · 6H2O [pba = 1,3-propylenebis(oxamato)]

The copper(II) complex Na₂[Cu(pba)] · 6H₂O has been synthesized and its structure determined. It consists of a novel two-dimensional network of [Cu(pba)]^2– anions connected to each other through the sodium ion as a bridge. Spectroscopic and magnetic properties have been measured and a spin distribution calculation has been carried out with the GAUSSIAN-94. Theoretical calculations indicate the rather larger spin density on nitrogen atoms should be responsible for the satellite lines appearing beside the main hyperfine coupling signs of copper(II). The antiferromagnetic interaction may be due to the intermolecular interaction and/or different copper(II) ions through the Na⁺ bridge in the same layer.     

A New Cycloartane from Sphaerophysa salsula

A novel cycloartane,named sphaerophysone A,9,19-cycloart-7β,24β,25-triol-1-en-3-one,was isolated from the ethanol extract of Sphaerophysa salsula DC.The structure was elucidated on the basis of spectral evidences and confirmed by X-ray analysis,the stereochemistry of the compound was also defined by X-ray analysis.