首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   21071篇
  免费   3656篇
  国内免费   3501篇
化学   15374篇
晶体学   446篇
力学   1539篇
综合类   324篇
数学   2575篇
物理学   7970篇
  2024年   66篇
  2023年   380篇
  2022年   656篇
  2021年   693篇
  2020年   747篇
  2019年   761篇
  2018年   633篇
  2017年   689篇
  2016年   868篇
  2015年   959篇
  2014年   1173篇
  2013年   1498篇
  2012年   1810篇
  2011年   1907篇
  2010年   1435篇
  2009年   1286篇
  2008年   1475篇
  2007年   1385篇
  2006年   1306篇
  2005年   1101篇
  2004年   858篇
  2003年   740篇
  2002年   750篇
  2001年   645篇
  2000年   590篇
  1999年   495篇
  1998年   359篇
  1997年   330篇
  1996年   349篇
  1995年   266篇
  1994年   249篇
  1993年   214篇
  1992年   209篇
  1991年   200篇
  1990年   152篇
  1989年   144篇
  1988年   100篇
  1987年   91篇
  1986年   93篇
  1985年   72篇
  1984年   71篇
  1983年   55篇
  1982年   40篇
  1981年   41篇
  1980年   33篇
  1978年   26篇
  1977年   25篇
  1976年   23篇
  1974年   22篇
  1973年   26篇
排序方式: 共有10000条查询结果,搜索用时 997 毫秒
21.
This paper through discussing subdifferentiability and convexity of convex functions shows that a Banach space admits an equivalent uniformly [locally uniformly, strictly] convex norm if and only if there exists a continuous uniformly [locally uniformly, strictly] convex function on some nonempty open convex subset of the space and presents some characterizations of super-reflexive Banach spaces. Supported by NSFC  相似文献   
22.
A series of (di)picolinic acids and their derivates are investigated as novel complexing tridentate or bidentate ligands in the iron‐mediated reverse atom transfer radical polymerization of methyl methacrylate in N,N‐dimethylformamide at 100 °C with 2,2′‐azobisisobutyrontrile as an initiator. The polymerization rates and polydispersity indices (1.32–1.8) of the resulting polymers are dependent on the structures of the ligands employed. Different iron complexes may be involved in iron‐mediated reverse atom transfer radical polymerization, depending on the type of acid used. 1H NMR spectroscopy has been used to study the structure of the resulting polymers. Chain‐extension reactions have been performed to further confirm the living nature of this catalytic system. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2912–2921, 2006  相似文献   
23.
Natural populations, whose generations are non-overlapping, can be modelled by difference equations that describe how the populations evolve in discrete time-steps. In the 1970s ecological research detected chaos and other forms of complex dynamics in simple population dynamics models, initiating a new research tradition in ecology. However, in former studies most of the investigations of complex population dynamics were mainly concentrated on single populations instead of higher dimensional ecological systems. This paper reports a recent study on the complicated dynamics occurring in a class of discrete-time models of predator–prey interaction based on age-structure of predator. The complexities include (a) non-unique dynamics, meaning that several attractors coexist; (b) antimonotonicity; (c) basins of attraction (defined as the set of the initial conditions leading to a certain type of an attractor) with fractal properties, consisting of pattern of self-similarity and fractal basin boundaries; (d) intermittency; (e) supertransients; and (f) chaotic attractors.  相似文献   
24.
红外热像仪参数的双黑体测量装置   总被引:6,自引:4,他引:2       下载免费PDF全文
对红外热像仪参数双黑体测量装置的工作原理进行了介绍。装置采用双黑体及反射型靶标为温差辐射源,可实现黑体温度温差准直辐射的定期校准和红外热像仪参数测量量值的溯源,也可实现红外热像仪参数的可控性,以及对它进行稳定的、可复现的精确测量。推导出利用红外热像仪参数双黑体测量装置测量信号传递函数SiTF数学模型,分析了红外热像仪参数测量装置的客观因素——仪器常数,针对仪器常数对SiTF测量的影响进行了试验。试验结果表明,仪器常数对红外热像仪SiTF参数测量精度影响较大,并同时影响时域与空域NETD及3D噪声的准确测量。  相似文献   
25.
The oxidation of SiGe film epitaxial grown on top of SOI wafers has been studied. These SiGe/SOI samples were oxidized at 700, 900, 1100 °C. Germanium atoms were rejected from SiGe film to SOI layer. A new Si1−xGex (x is minimal) layer formed at SiGe/Si interface. As the germanium atoms diffused, the new Si1−xGex (x is minimal) layer moved to Si/SiO2 interface. Propagation of threading dislocation in SiGe film to SOI substrate was hindered by the new SiGe/Si interface. Strain in SOI substrate transferred from SiGe film was released through dislocation nucleation and propagation inner. The relaxation of SiGe film could be described as: strain relaxed through strain equalization and transfer process between SiGe film and SOI substrates. Raman spectroscopy was used to characterize the strain of SiGe film. Microstructure of SiGe/SOI was observed by transmission electron microscope (TEM).  相似文献   
26.
The structural evolution in amorphous silicon and germanium thin films has been investigated by high-resolution transmission electron microscopy (HRTEM) in conjunction with autocorrelation function (ACF) analysis. The results established that the structure of as-deposited semiconductor films is of a high density of nanocrystallites embedded in the amorphous matrix. In addition, from ACF analysis, the structure of a-Ge is more ordered than that of a-Si. The density of embedded nanocrystallites in amorphous films was found to diminish with annealing temperature first, then to increase. The conclusions also corroborate well with the results of diminished medium-range order in annealed amorphous films determined previously by a variable coherence microscopy method.  相似文献   
27.
超细CaO粉炉内喷射脱硫的实验研究   总被引:2,自引:0,他引:2  
本文对超细CaO粉炉内喷射脱硫进行了实验研究,分析了可能影响超细CaO粉炉内脱硫效率的多种因素,实验结果表明:使用预先锻烧生成的超细CaO粉在并不苛刻的反应条件下脱硫效果很好,颗粒大小、反应区温度、反应时间和Ca/S比对炉内喷钙脱硫的效率有重要的影响.  相似文献   
28.
Er3+掺杂的Bi2O3-B2O3-SiO2玻璃的光谱性质   总被引:2,自引:1,他引:1       下载免费PDF全文
测试了Bi2O3-B2O3-SiO2玻璃中的Er3+离子的吸收光谱、发射光谱、4I13/2的荧光寿命、拉曼光谱,及OH-的傅里叶红外吸收光谱。应用Judd-Ofelt理论计算了该玻璃中的Er3+离子的J-O参数、振子强度、4I13/2能级的寿命,从而利用测得的4I13/2的荧光寿命得出了4I13/2能级的量子效率(15%)。由于较低量子效率可能与OH-有关,所以计算了玻璃中的OH-浓度,发现其浓度较高(1.66×1019cm-1,相当于Er3+浓度的3倍)。应用McCumber理论和四能级模型计算了Er3+离子的受激发射截面和荧光发射光谱的半峰全宽,结果与通过吸收光谱计算所得基本吻合。根据透射率和折射率的关系计算了折射率,发现和测量值相差很大,说明有较大的散射,通过拉曼光谱和显微镜测试,认为是玻璃中的微小气泡造成的。  相似文献   
29.
A convenient route was developed to synthesize S-oxo-[(methylthio)-methyl]cysteinols on a large scale from cheap l-serine as the starting material. The structures of diastereoisomers were determined by NMR, CD spectra, and X-ray diffraction analysis. All four diastereoisomers were examined for their ability to inhibit certain bacteria from growing.  相似文献   
30.
基于液晶光阀的全息照相控光仪   总被引:2,自引:2,他引:0  
何源  邢增海  陈焕杰  余艺  梁海辉  钟铖  张红  谭炎 《物理实验》2006,26(5):22-24,28
设计了通过液晶光阀自动调整全息照相物光和参考光辐照比至最佳状态,同时能实现曝光时间自动控制的控光仪.该仪器巧妙运用液晶光阀和硅光电池器件,使测量、调整、自控一体化,从而提高拍摄优质全息图的工作效率.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号