Mixed ligand complexes of coumarilic acid/nicotinamide with transition metal complexes

Coumarilate–nicotinamide complexes of Co^II and Zn^II were synthesized and investigated by elemental analysis, magnetic susceptibility, solid state UV–Vis, direct injection probe mass spectra, FTIR spectra, thermoanalytic TG-DTG/DTA, and crystal X-ray diffraction methods. It was obtained that both complex structures contain 2 mol aqua ligands, 2 mol coumarilate (CCA^?) and 2 mol nicotinamide (NA) ligands per formula unit. The CCA^? and NA ligands were bonded to metal cations as monodentate through acidic oxygen and nitrogen of pyridine ring, respectively. Thermal decomposition of each complex starts with dehydration and continue removing of 1 mol NA ligand. The thermal dehydration of the complexes takes place in one or two steps. The decomposition mechanism and thermal stability of the investigated complexes are interpreted in terms of their structures. The final decomposition products are found to be metal oxides.     

Electrochemical deposition and characterization of polyppyrrole coatings doped with nickel cobalt oxide for environmental applications

Electrochemical depositions of hybrid polypyrrole/nickel cobalt oxide (PPy/NiCoO) coatings onto ferritic stainless steel surface were carried out with different electrochemical techniques from 0.1 M pyrrole (Py) in 0.2-M oxalic acid (OA) solution and less than 150-nanometer-sized NiCoO particles. The structural properties of the composite were investigated by using different methods such as transmission electron microscopy (TEM), scanning electron microscopy (SEM) with energy-dispersive X-ray spectrometer (EDS) and Raman spectroscopy. The embedded NiCoO particles, uniformly distributed onto the surface of the PPy film, have similar oxide ratios corresponding to a mixed oxide structure. The electrochemical characterization was done using polarization curves and linear sweep voltammetry (LSV) related to oxygen reduction reaction (ORR) in alkaline solution and hydrogen peroxide as an oxygen source. Concerning the exchange current densities for ORR, the obtained values (between 1.06 and 1.45?×?10^?3 mA cm^?2 for a total amount of NiCoO of 0.1 mg cm^?2) are comparable with other polymer films with Pt.     

Locating Pb2+ and Zn2+ in Zinc Finger-Like Peptides Using Mass Spectrometry

The binding preferences of Pb²⁺and Zn²⁺ in doubly charged complexes with zinc finger-like 12-residue peptides (Pep), [M_n(Pep-2(n-1)H)]²⁺ have been explored using tandem mass spectrometry. The peptides were synthesized strategically by blocking the N-terminus with an acetyl group and with four cysteine and/or histidine residues in positions 2, 5, 8, and 11, arranged in different motifs: CCHH, CHCH, and CCCC. The MS² spectra of the Pb²⁺ and Zn²⁺ complexes show multiple losses of water and a single methane loss and these provide a sensitive method for locating the metal dication and so elucidating its coordination. The elimination of a methane molecule indicated the position of the metal at the Cys2 residue. Whereas lead was observed to preferentially bind to cysteine residues, zinc was found to primarily bind to histidine residues and secondarily to cysteine residues. Preferential binding of lead to cysteine is preserved in the complexes with more than one Pb²⁺. Key to the mechanism of the loss of water and methane is the metal dication withdrawing electrons from the proximal amidic nitrogen. This acidic nitrogen loses its hydrogen to an amidic oxygen situated four atoms away leading to formation of a five-member ring and the elimination of water.      

On Rings Whose Reflexive Ideals are Principal

We call a prime Noetherian maximal order R a pseudo-principal ring if every reflexive ideal of R is principal. This class of rings is a broad class properly containing both prime Noetherian pri-(pli) rings and Noetherian unique factorization rings (UFRs). We show that the class of pseudo-principal rings is closed under formation of n × n full matrix rings. Moreover, we prove that if R is a pseudo-principal ring, then the polynomial ring R[x] is also a pseudo-principal ring. We provide examples to illustrate our results.     

Corrigendum to: Goldie Extending Modules

This corrigendum is written to correct an error in Corollary 2.5(ii) and an error in the proof of the converse of Theorem 2.7 of Akalan, Birkenmeier, and Tercan [1 Akalan , E. , Birkenmeier , G. F. , Tercan , A. ( 2009 ). Goldie extending modules . Comm. Algebra 37 : 663 – 683 .[Taylor &; Francis Online], [Web of Science ®] , [Google Scholar]].     

Classes of Almost Clean Rings

A ring is clean (almost clean) if each of its elements is the sum of a unit (regular element) and an idempotent. A module is clean (almost clean) if its endomorphism ring is clean (almost clean). We show that every quasi-continuous and nonsingular module is almost clean and that every right CS (i.e. right extending) and right nonsingular ring is almost clean. As a corollary, all right strongly semihereditary rings, including finite AW ^*-algebras and noetherian Leavitt path algebras in particular, are almost clean. We say that a ring R is special clean (special almost clean) if each element a can be decomposed as the sum of a unit (regular element) u and an idempotent e with aR?∩?eR?=?0. The Camillo-Khurana Theorem characterizes unit-regular rings as special clean rings. We prove an analogous theorem for abelian Rickart rings: an abelian ring is Rickart if and only if it is special almost clean. As a corollary, we show that a right quasi-continuous and right nonsingular ring is left and right Rickart. If a special (almost) clean decomposition is unique, we say that the ring is uniquely special (almost) clean. We show that (1) an abelian ring is unit-regular (equiv. special clean) if and only if it is uniquely special clean, and that (2) an abelian and right quasi-continuous ring is Rickart (equiv. special almost clean) if and only if it is uniquely special almost clean. Finally, we adapt some of our results to rings with involution: a *-ring is *-clean (almost *-clean) if each of its elements is the sum of a unit (regular element) and a projection (self-adjoint idempotent). A special (almost) *-clean ring is similarly defined by replacing “idempotent” with “projection” in the appropriate definition. We show that an abelian *-ring is a Rickart *-ring if and only if it is special almost *-clean, and that an abelian *-ring is *-regular if and only if it is special *-clean.     

Synthesis,characterization, spectroscopic,and thermal studies of imidazole complexes of metal benzenesulfonates. Crystal structure of [M(imH)<Subscript>3</Subscript>(H<Subscript>2</Subscript>O)<Subscript>3</Subscript>]·(BS)<Subscript>2</Subscript> [M=Ni(II) and Co(II)]

Four novel transition metal benzenesulfonate (BS) complexes of imidazole (im) with a general formula [M(imH)₃(H₂O)₃]·(BS)₂ [M=Mn(II) (1), Ni(II) (2), Co(II) (3)] and [Cu(BS)(imH)₃]·(BS) (4) have been synthesized and characterized by physicochemical and spectroscopic methods. The complexes 2 and 3 have also been characterized by single X-ray diffraction technique. The BS anion in complexes 1–3 acts as a counter anion, while in complex 4, it acts as both ligand and counter anion. The Ni and Co complexes are isomorphous, crystallizing in the monoclinic crystal system with C2/c space group. Each metal(II) atom in 2 and 3 is octahedrally coordinated by three imidazole and three aqua ligands, adopting a mer-coordination mode with Ni(II) or Co(II) centers. In both 2 and 3, the H2C atom has bifurcated donor (O3 and O5) atoms, forming a bifurcated hydrogen bond. This hydrogen bond links the complex cation and BS anion, forming one-dimensional hydrogen-bonded supramolecular chains. The complexes exhibit different decomposition characteristics. Magnetic susceptibility measurement shows that complex 3 has orbital interactions.     

A DFT‐based mechanistic study on the formation of oximes

Oxime chemistry has been proven to be a reliable bioconjugation method for biomedical applications. Because of its stable and bio‐orthogonal nature, a number of materials have been devised for in vitro and in vivo applications such as drug delivery, imaging, and biochemical assays. Polymers, synthetic molecules, nanoparticles, and biomolecules carrying alkoxyamine and aldehyde/ketone functional groups could be linked to each other through oxime bond, and a variety of modular platforms could be produced. Formation of oximes is catalyzed in acidic medium, and the proposed reaction mechanism follows classical imine formation pathways. Aniline has been found to accelerate the rate of oxime formation several orders of magnitude. In this computational study, we analyzed the proposed mechanism on model systems using DFT calculations including a solvation model. The energetics of the reaction steps in neutral and acidic conditions as well as in the presence of aniline was performed. Explicit water molecules were included in the calculations to study the energetics of solvent assisted proton transfer steps.     

Modeling of L-lactide Polymerization by Reactive Extrusion

The kinetics of L-lactide ring-opening polymerization initiated by stannous octoate and triphenylphosphine was investigated in a batch apparatus (Haake Rheocord Mixer). Based on the experimental data, a kinetic model is developed, considering a coordination-insertion mechanism. Reactive extrusion experiments were further conducted for the same polymerization process, on a co-rotating twin screw extruder. The melted material flow and mixing was described by using the Ludovic® commercial simulator. Based on the developed kinetic model and simulated flow of L-lactide polymerization mixture, a mathematical model of reactive extrusion process is formulated, describing the evolutions of monomer conversion and average molecular weight along the extruder. The model is predicting with a reasonable good accuracy the experimental data.     

Geodesic Motions in Euclidean Taub-NUT Spinning Spaces

We investigate the geodesic motions of pseudo-classical spin- \frac12\frac{1}{2} point particles in the Euclidean Taub-NUT space. We derive the constants of motion from the solutions of the generalized Killing equations for spinning spaces and exploiting those the motion of pseudo-classical Dirac fermions are analyzed on a cone and plane.