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81.
Nina K. Gusarova Pavel A. Volkov Nina I. Ivanova Boris G. Sukhov Ludmila I. Larina Olga N. Kazheva Grigorii G. Alexandrov Oleg A. D’yachenko Boris A. Trofimov 《Tetrahedron letters》2013
The oxidative cross-coupling between 4-hydroxy-6-methyl-2-pyrone or 3-hydroxy-2-methyl-4-pyrone and secondary phosphine chalcogenides proceeds in CCl4/Et3N under mild conditions (20–52 °С, 0.75–10 h) through the hydroxyl group to give O-(6-methyl-2-oxo-2H-pyran-4-yl) diorganylphosphinochalcogenoates or O-(2-methyl-4-oxo-4H-pyran-3-yl) diorganylphosphinochalcogenoates, in high yields. 相似文献
82.
Y. M. Kulyako S. A. Perevalov T. I. Trofimov D. A. Malikov S. E. Vinokurov M. D. Samsonov B. F. Myasoedov A. M. Fedoseev A. A. Bessonov A. Y. Shadrin 《Journal of Radioanalytical and Nuclear Chemistry》2014,299(3):1293-1298
It was established that heating to 90 °C of nitrate solutions of U, Np and Pu in the presence of hydrazine hydrate results in the formation of hydrated dioxides of these elements. On ignition under inert or reducing conditions in the temperature range of 280–800 °C hydrated uranium dioxide transmogrify into crystalline UO2. On ignition in air atmosphere UO2·nH2O turns into UO3 at 440 °C and into U3O8 at 570–800 °C. It was shown that thermolysis of the solution containing a mixture of uranium, neptunium and plutonium nitrates at 90 °C in the presence of hydrazine hydrate allows one to prepare hydrated dioxides (U, Np, Pu)O2·nH2O which on heating to ~300 °C transmogrify into crystalline product of UO2, NpO2 and PuO2 solid solution. The technique of preparation of solid solutions of U and Pu dioxides is very promising as simple and effective method of production of MOX-fuel for. 相似文献
83.
Koranit Shlosman Ran Y. Suckeveriene Jasmine Rosen‐Kligvasser Roza Tchoudakov Evgeni Zelikman Raphael Semiat Moshe Narkis 《先进技术聚合物》2014,25(12):1484-1491
This paper summarizes a study of controlled migration of an antifog (AF) additive; sorbitan monooleate (SMO), from linear low density polyethylene (LLDPE) films containing a compatibilizer, LLDPE grafted maleic anhydride (LLDPE‐g‐MA). LLDPE/LLDPE‐g‐MA/SMO blends were prepared by melt compounding. Bulk and surface properties of compression molded LLDPE films containing SMO and LLDPE‐g‐MA were characterized using Fourier transform infrared spectroscopy and contact angle measurements. Thermal properties were investigated using a thermal gravimetric analyzer. Diffusion coefficient (D) was calculated, and AF properties were characterized using a “hot fog” test. Compression molded films were characterized for their morphology using high‐resolution scanning electron microscopy, and rheological properties were measured using a parallel‐plate rotational rheometer. It was found that the LLDPE/LLDPE‐g‐MA/SMO systems are characterized by a slower SMO migration rate, a lower diffusion coefficient, and lower contact angle values compared with LLDPE/SMO blends. These results are well correlated with results of a hot fog test. Morphological studies revealed a very fine dispersion of SMO in the LLDPE films, when 3 phr LLDPE‐g‐MA was combined with 1 phr SMO. Thermal analysis results show that the incorporation of 3 phr LLDPE‐g‐MA and 1 phr SMO significantly increases the decomposition temperature of the blend at T > 400°C. At high shear rates, the LLDPE blends show that the AF and the compatibilizer have a lubrication effect on LLDPE. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
84.
G. P. Aleksandrova A. N. Sapozhnikov A. S. Boymirzaev B. G. Sukhov B. A. Trofimov 《Russian Journal of General Chemistry》2020,90(4):672-679
Water-soluble nanocomposites with narrow distribution of nanoparticles of pharmacophore bismuth and iron oxides have been obtained. The biopolymer matrix of the arabinogalactan polysaccharide has exhibited strong stabilizing properties with respect to transition metal oxides. The size of the spherical metal oxide nanoparticles has been found of 5–7 nm as per transmission electron microscopy. The exclusion liquid chromatography data have revealed that the change in the molecular mass parameters of arabinogalactan is due to the combined processes of self-assembly of nanocomposites and alkaline decomposition. 相似文献
85.
Kulyako Yu. M. Trofimov T. I. Pilyushenko K. S. Vinokurov S. E. Myasoedov B. F. 《Physics of Atomic Nuclei》2020,83(10):1396-1399
Physics of Atomic Nuclei - The use of microwave heating to produce solid solutions of actinide oxides in the processes of thermal denitration of model nitric acid solutions formed in reducing... 相似文献
86.
Nikolay Banichuk Alexander Barsuk S. Y. Ivanova Juha Jeronen Evgeni Makeev 《基于设计的结构力学与机械力学》2018,46(1):1-17
We consider an infinite, homogenous linearly elastic beam resting on a system of linearly elastic supports, as an idealized model for a paper web in the middle of a cylinder-based dryer section. We obtain closed-form analytical expressions for the eigenfrequencies and the eigenmodes. The frequencies increase as the support rigidity is increased. Each frequency is bounded from above by the solution with absolutely rigid supports, and from below by the solution in the limit of vanishing support rigidity. Thus in a real system, the natural frequencies will be lower than predicted by commonly used models with rigid supports. 相似文献
87.
88.
S. F. Malysheva N. A. Belogorlova V. A. Kuimov N. I. Ivanova P. A. Volkov I. A. Ushakov N. K. Gusarova B. A. Trofimov 《Russian Journal of General Chemistry》2010,80(2):232-238
Secondary phosphine oxides and phosphine sulfides react with acetylene, methylacetylene, and phenylacetylene in the presence
of strong bases (KOH-DMSO, KOH-THF) by the mechanism of double nucleophilic α,β-addition to form tertiary diphosphine dioxides
and diphosphine disulfides in high yield (up to 97%). 相似文献
89.
The possibility of formation of a basic (stationary) and an additional (moving) high-absorption domain in an optically bistable system, based on high absorption, is demonstrated. A semiconductor with the absorption coefficient dependent on the concentration of free charge carriers in the conduction band is considered as a nonlinear medium. Under certain conditions, an optical beam passing through the stationary high-absorption domain acquires an annular profile and, after traveling a certain distance, transforms into a Gaussian beam with an intensity on the axis sufficient to switch the medium-beam system to the upper state. This moving domain periodically disappears and reappears due to diffusion processes. 相似文献
90.