Quantum cascade laser modulation for correction of matrix-induced background changes in aqueous samples

A robust method for the determination of carbon dioxide in sugar containing solutions using a single distributed feedback quantum cascade laser (QCL) has been developed. By switching the driving current between two selected values, 1.6 and 1 A, emission wavelengths at 2341.4 and 2341.6 cm^-1 could be achieved. The method is based on absorbance measurements in transmission and the calculation of the absorbance differences between both wavenumbers. This allows the elimination of indirect matrix interference produced on carbon dioxide measurements with increasing sugar concentrations. A flow injection setup was employed to produce carbon dioxide standards from a series of bicarbonate solutions (0–3 g/l) by adjusting the pH with a sodium hydroxide/citric acid buffer solution to pH 3.13. Different concentrations (0–90 g/l) of sugar were also mixed on line with the analyte to study their influence on carbon dioxide measurement. As the difference in the two evaluated wavelengths is small compared to the absorption peak of CO₂, the analytical readout of the QCL modulation can be seen as a proportional parameter to the first derivative of FTIR spectra in this spectral region. PACS 42.55.Px; 42.62.Fi     

X‐ray collimation by crystals with precise parabolic holes based on diffractive–refractive optics

Two crystals with precise parabolic holes were used to demonstrate sagittal beam collimation by means of a diffractive–refractive double‐crystal monochromator. A new approach is introduced and beam collimation is demonstrated. Two Si(333) crystals with an asymmetry angle of α = 15° were prepared and arranged in a dispersive position (+,?,?,+). Based on theoretical calculations, this double‐crystal set‐up should provide tunable beam collimation within an energy range of 6.3–18.8 keV (Θ_B = 71–18.4°). An experiment study was performed on BM05 at ESRF. Using 8.97 keV energy, the beam profile at various distances was measured. The experimental results are in good agreement with theoretical predictions. Owing to insufficient harmonic suppression, the collimated (333) beam was overlapped by horizontally diverging (444) and (555) beams.     

Invariant Measures and Lower Ricci Curvature Bounds

Potential Analysis - Given a metric measure space $(X,d,mathfrak {m})$ that satisfies the Riemannian Curvature Dimension condition, RCD?(K,N), and a compact subgroup of isometries G ≤...     

On the Geometric Diversity of Wavefronts for the Scalar Kolmogorov Ecological Equation

We answer three fundamental questions concerning monostable traveling fronts for the scalar Kolmogorov ecological equation with diffusion and spatiotemporal interaction: These are the questions about their existence, uniqueness and geometric shape. In the particular case of the food-limited model, we give a rigorous proof of the existence of a peculiar, yet substantive and nonlinearly determined class of non-monotone and non-oscillating wavefronts.

     

Noise robustness of the nonlocality of entangled quantum states

We study the nonlocal properties of states resulting from the mixture of an arbitrary entangled state rho of two d-dimensional systems and completely depolarized noise, with respective weights p and 1-p. We first construct a local model for the case in which rho is maximally entangled and p at or below a certain bound. We then extend the model to arbitrary rho. Our results provide bounds on the resistance to noise of the nonlocal correlations of entangled states. For projective measurements, the critical value of the noise parameter p for which the state becomes local is at least asymptotically log(d) larger than the critical value for separability.     

A high-throughput search for direct methanol fuel cell anode electrocatalysts of type PtxBiyPbz

We used a high-throughput method to screen for direct methanol fuel cell anode electrocatalysts in the Pt-Bi-Pb system. Previous studies showed that PtBi and PtPb (both NiAs structure type) were active electrocatalysts for the oxidation of formic acid, but only PtPb was active in oxidizing methanol. We synthesized thin films with continuous composition spreads of the three elements by magnetron sputtering at deposition temperatures from ambient to 510 °C. A fluorescence method was then used to identify compositions that were active toward methanol oxidation. Only films deposited between temperatures of 160 and 400 °C showed electrocatalytic activity. The areas that were active for methanol oxidation showed predominantly the NiAs structure type according to XRD, with optimal activity for compositions near PtBi_0.01Pb_0.53.     

Mössbauer effect phase determination in iron oxide–polyaniline nanocomposites

Mössbauer effect spectroscopy and thermal analysis techniques were applied to characterize polyaniline composites successfully synthesized by embedding Fe oxide nanoparticles (about 10–13 nm) in a polymeric matrix in the presence of dodecyl benzene sulfonic acid and HCl (dopant). Thermal techniques provided quantitative information on iron oxide content and on polyaniline stability and transformations. Mössbauer results indicated that for the whole studied composition range, 3.4 to 100 iron oxide wt.%, composites hold maghemite particles. A preliminary study of the conductivity of the nanocomposites was performed. The largest conductivity was observed for a 8 wt.% maghemite composite where all particles are magnetically unblocked at room temperature within the Mössbauer time window.     

Enhancing energy harvesting by coupling monostable oscillators

The performance of a ring of linearly coupled, monostable nonlinear oscillators is optimized towards its goal of acting as energy harvester – through piezoelectric transduction – of mesoscopic fluctuations, which are modeled as Ornstein-Uhlenbeck noises. For a single oscillator, the maximum output voltage and overall efficiency are attained for a soft piecewise-linear potential (providing a weak attractive constant force) but they are still fairly large for a harmonic potential. When several harmonic springs are linearly and bidirectionally coupled to form a ring, it is found that counter-phase coupling can largely improve the performance while in-phase coupling worsens it. Moreover, it turns out that few (two or three) coupled units perform better than more.     

Operations planning test bed under rolling horizons,multiproduct, multiechelon,multiprocess for capacitated production planning modelling with strokes

One of the problems when conducting research in mathematical programming models for operations planning is having an adequate database of experiments that can be used to verify advances and developments with enough factors to understand different consequences. This paper presents a test bed generator and instances database for a rolling horizons analysis for multiechelon planning, multiproduct with alternatives processes, multistroke, multicapacity with different stochastic demand patterns to be used with a stroke-like bill of materials considering production costs, setup, storage and delays for operations management. From the analysis of the operations planning obtained from this test bed, it is concluded that a product structure with an alternative process obtains the lowest total cost and the highest service level. In addition, decreasing seasonal demand could present a lower total cost than constant demand, but would generate a worse service level. This test bed will allow researchers further investigation so as to verify improvements in forecast methods, rolling horizons parameters, employed software, etc.

     

Using an ANP performance management framework to manage the development of transversal competences in University degrees

Organisations are concerned about measuring the performance of the product/service they deliver to their customers. In all types of organisations, if a proper performance assessment is to be developed, it should be measured in different dimensions. At University, the new study programs include the development and assessment of transversal competences due to their importance in enhancing the abilities and improving the employability of students. The achievement of transversal competences can be assessed in different levels/stages; for example, the 1st and 2nd years of a Bachelor’s degree; the 3rd and 4th years of a Bachelor’s degree and at Master’s level. The purpose of this paper is to integrate the research into performance management in organisations to develop an approach consisting of four components (a methodology, a solid and integrated performance management framework, graphical diagrams and quantitative techniques) to assess and manage the achievement of transversal competences through the different levels of study using a consolidated approach. The proposal uses the Analytic Network Process (ANP) to model dependences and feedback among the elements of the competences.