全文获取类型
收费全文 | 1841篇 |
免费 | 61篇 |
国内免费 | 160篇 |
专业分类
化学 | 1083篇 |
力学 | 202篇 |
综合类 | 3篇 |
数学 | 59篇 |
物理学 | 715篇 |
出版年
2016年 | 4篇 |
2015年 | 15篇 |
2014年 | 1篇 |
2013年 | 9篇 |
2012年 | 22篇 |
2011年 | 397篇 |
2010年 | 199篇 |
2009年 | 225篇 |
2008年 | 38篇 |
2007年 | 15篇 |
2006年 | 47篇 |
2005年 | 107篇 |
2004年 | 351篇 |
2003年 | 174篇 |
2002年 | 136篇 |
2001年 | 93篇 |
2000年 | 30篇 |
1999年 | 23篇 |
1998年 | 25篇 |
1997年 | 13篇 |
1996年 | 12篇 |
1995年 | 9篇 |
1994年 | 2篇 |
1993年 | 23篇 |
1992年 | 33篇 |
1991年 | 14篇 |
1990年 | 19篇 |
1989年 | 15篇 |
1988年 | 4篇 |
1987年 | 2篇 |
1982年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1925年 | 2篇 |
排序方式: 共有2062条查询结果,搜索用时 31 毫秒
111.
Wen Jing Zhao Yong Heng Shi Gui Long Zhao Yu Li Wang Hua Shao Li Da Tang Jian Wu Wang 《中国化学快报》2011,22(10):1215-1218
A series of gem-dimethyl-bearing C-glucosides were designed and synthesized as SGLT2 inhibitors,with anhydrous aluminum chloride-mediated Friedel-Crafts alkylation to construct the gem-dimethyl functionality being the key step.The in vivo anti-hyperglycemic activity was evaluated with mice oral glucose tolerance test(OGTT),and all the synthesized compounds showed significant but less potent anti-hyperglycemic activity than the positive control dapagliflozin. 相似文献
112.
SUI XinCe SHI Yan & FU ZhiFeng State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology Beijing China 《中国科学B辑(英文版)》2011,(3)
A novel copolymer network with acetal structure was prepared using bis[4-(vinyloxy)butyl](4-methyl-1,3-phenylene)biscarbamate(BECT)as the crosslinking agent.Firstly,a tri-copolymer of maleic anhydride(MAn),n-butyl vinyl ether(BVE)and 4-hydroxybutyl vinyl ether(HBVE)was synthesized via free-radical polymerization with 2,2′-azobisisobutyronitrile as the initiator.The tri-copolymer consisted of two sorts of alternating units,MAn-alt-BVE and MAn-alt-HBVE.The linear copolymer Poly((MAn-alt-BVE)-co-(MAn-alt-HBVE)... 相似文献
113.
Jinxia Gua b Zhipeng Baib Weifang Lib Liping Wua Aixia Liuc Haiyan Dongd Yiyang Xiec a Tianjin Institute of Urban Construction Tianjin China b State Environmental Protection Key Laboratory of Urban Ambient Air Particulate Matter Pollution Prevention Control College of Environmental Science Engineering Nankai University Tianjin China c Tianjin Institute of Meteorological Instruments Tianjin China d Tianjin Environmental Monitoring Central Station Tianjin China 《中国颗粒学报》2011,(3)
PM2.5 samples for 24 h were collected during winter in Tianjin,China. The ambient mass concentration and chemical composition of the PM2.5 were determined. Ionic species were analyzed by ion chromatog-raphy,while carbonaceous species were determined with the IMPROVE thermal optical reectance(TOR) method,and inorganic elements were measured by inductively coupled plasma-atomic emission spec-trometer. The daily PM2.5 mass concentrations ranged from 48.2 to 319.2 g/m3 with an arithmetic average of 144.6 g/m3. ... 相似文献
114.
ZHAO YuXin YI ShiHe TIAN LiFeng HE Lin & CHENG ZhongYu College of Aerospace Material Engineering National University of Defense Technology Changsha China 《中国科学G辑(英文版)》2008,51(8):1134-1143
Flow visualization of supersonic mixing layer has been studied based on the high spatiotemporal resolution Nano-based Planar Laser Scattering(NPLS) method in SML-1 wind tunnel. The corresponding images distinctly reproduced the flow structure of laminar,transitional and turbulent region,with which the fractal measurement can be implemented. Two methods of measuring fractal dimension were introduced and compared. The fractal dimension of the transitional region and the fully developing turbulence region of supersonic mixing layer were measured based on the box-counting method. In the transitional region,the fractal dimension will increase with turbulent intensity. In the fully developing turbulent region,the fractal dimension will not vary apparently for different flow structures,which em-bodies the self-similarity of supersonic turbulence. 相似文献
115.
高速扫描相机时间测量不确定度分析 总被引:21,自引:6,他引:15
以国内普遍使用的SJZ-30型高速扫描相机为例,用精测转速方法的结果处理数据,转速测量相对合成不确定度小于0.1%,时间间隔测量的相对扩展不确定度为0.2%.扫描速度在像面上的位置误差,采用"中值扫描速度",可予以校正.同时讨论了进一步降低转速测量不确定度和位置误差的方法. 相似文献
116.
构造了由多模复共轭相干态|{Zj*}〉q、多模复共轭虚相干态|{iZj*}〉q和多模真空态|{Qj} 〉q这三态的线性叠加所组成的第Ⅲ类三态叠加多模叠加态光场|ψ3(3)〉q.利用多模压缩态理论研究了态|ψ3(3)〉q中广义磁场分量的任意偶数次广义非线性等幂次N次方Y压缩特性.结果发现:在压缩次数N取偶数,只要各模的初始相位φj(j=1,2,3,…,…,q),态间的初始相位差(θi-θ2)(i=1,3)和各单模相干态光场平均光子数Rj2之和 分别满足各自的取值条件,态|ψ3(3)〉q的广义磁场分量(即第一正交相位分量)就可呈现出周期性变化的、任意偶数次的广义非线性等幂次N次方Y压缩效应. 相似文献
117.
INTRODUCTIONThe atom transfer radical polymerization (ATRP) has become an important method for preparing well-definedmacromolecules. This technique offers control over the molecular weights, the chain end functionalities, and thechain architectures[1-12]. It has been used extensively for the preparation of homopolymers, block, and randomcopolymers[13-39], for the preparation of organic/inorganic hybrid materials[40-54], as well as for combining variousother living polymerization methods … 相似文献
118.
119.
120.
CUI Tao TANG ShunLin ZHANG Lei & YU DaRen School of Energy Science Engineering Harbin Institute of Technology Harbin China Pharmaceutical College Heilongjiang University of Chinese Medicine Institution Harbin China 《中国科学B辑(英文版)》2011,(7)
Catalytic CO oxidation on platinum group metals exhibits nonlinear phenomena such as hysteresis and bifurcation.Elucidation of the nonlinear mechanisms is important for catalyst design and control of reaction routes.Previous studies have offered initial insights into the local bifurcation behavior of CO oxidation.However,since the bifurcation behavior of CO oxidation is determined by multiple parameters such as temperature,total flux,and CO fraction,it is difficult to predict the global bifurcation behavior... 相似文献