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91.
This paper analyses the interaction between the turbulence and free surface. The phenomenon takes place in many natural flows and industrial processes. In the present experiments, turbulence is generated by a vertically oscillating grid moving beneath the free surface. Fluid velocity has been measured through a hot-film anemometer, and the free surface elevation has been measured by an ultrasonic sensor. Integral length scales and several turbulence estimators have been computed. In order to detect the generation of turbulence near the free surface, the correlation between free surface elevation and the underneath flow velocity has been studied, as well as the time lag between turbulence and free surface. The free surface dynamics has been characterized by a velocity scale and a length scale. The kinetic energy associated with the free surface fluctuations increases with the Reynolds number at a rate depending on the frequency of the grid movement. For Reynolds number larger than ≈1000, however, the relationships collapse to a single curve characterized by a lower rate. The present experiments do not achieve the inertial sub-range in the vertical velocity fluctuations, and the estimated spectrum decays with an exponent smaller than ?3, which is the typical value for the two-dimensional turbulence in the inertial sub-range. The macro length scale, estimated by using the Taylor’s frozen turbulence hypothesis, experiences a decay away from the grid, which follows reasonably well the profile of Thompson and Turner (J Fluid Mechanics 67: 349–368, 1975). The micro length scale reduces immediately beneath the free surface, which can be interpreted by the increase of dissipation rate in the subsurface layer. The classification diagram by Brocchini and Peregrine (J Fluid Mech 449: 225–254, 2001) indicates that most tests fall in the weak turbulence domain, but some tests fall in the wavy domain. The vertical velocity fluctuations and the free surface level show a significant correlation with a negative phase lag, that is, the free surface fluctuations are ahead of the vertical velocity fluctuations. 相似文献
92.
Olzon-Dionysio M. Souza S. D. Ayala A. P. Carbonari A. Longo E. 《Hyperfine Interactions》2001,136(3-8):523-528
The concentration dependence of the electric field gradient (EFG) in PZT ceramics was studied by Time Differential Perturbed
Angular Correlations (PAC) using the 181Ta radioactive probe in samples with x=0.3, 0.5 and 0.8 at room temperature. This phase presents two sites, probably related to defects close to probes, caused
by oxygen and lead vacancies. We can also state that both the paraelectric and ferroelectric phases of these systems have
two sites with different characteristics and that the high-frequency quadrupolar frequency site presents the highest fraction.
The concentration dependence revealed by our results is discussed by comparing the latter with previous PAC studies.
This revised version was published online in September 2006 with corrections to the Cover Date. 相似文献
93.
The preparation procedure for nanoparticles of the water-soluble salts Na2S and ZnSO4, two commonly used reagents to synthesise ZnS nanoparticles, by evaporation of volatile components of salt-containing water-in-oil
microemulsions is described. In suitable conditions, the evaporation leads to the formation of dry salt–surfactant composites
and to the formation of Na2S or ZnSO4 nanoparticles. It was found that the salt–surfactant composites can be totally redissolved in a dry apolar organic solvent
allowing the formation of virtually water-free solutions containing a considerable amount of the water-soluble salts. The
presence of nanoparticles in these solutions and in the composites has been proved by small-angle X-ray scattering and transmission
electron microscopy, respectively. By mixing these solutions, the solid–solid reaction between Na2S and ZnSO4 nanoparticles leading to the formation of very small-sized ZnS nanoparticles has been ascertained by UV spectrophotometry.
Received: 09 February 2001 Accepted: 19 March 2001 相似文献
94.
F. Gonella E. Cattaruzza G. Battaglin F. D''Acapito C. Sada P. Mazzoldi C. Maurizio G. Mattei A. Martorana A. Longo F. Zontone 《Journal of Non》2001,280(1-3):241-248
Silica glass containing metal clusters is studied for both basic and applied aspects, related to the physics of cluster formation and to the optical properties of these materials. To obtain such composite structure, Cu + Ni, Au + Cu, Au + Ag, Cu + Co, and Cu + Ag sequential implantations in fused silica were realized. The resulting systems, after possible annealing in various atmospheres, were studied by synchrotron radiation-based techniques, namely, extended X-ray absorption fine structure (EXAFS) spectroscopy, grazing incidence X-ray diffraction (GIXRD), and grazing incidence small angle X-ray scattering (GISAXS). The unique potential of these techniques is the capability to investigate dilute (volume fraction of clusters0.01) and very thin (50 nm) systems. In the presented experiment, both pure and alloy clusters in the nanometer range of size were observed to form, pointing out the complexity of the cluster formation process in terms of physical and chemical driving forces. 相似文献
95.
S. Munavalli D. K. Rohrbaugh G. W. Wagner F. R. Longo H. D. Durst 《Phosphorus, sulfur, and silicon and the related elements》2013,188(4):781-789
Microwave catalyzed reaction of a neat mixture of styrene oxide and H-dimethylphosphonate furnished dimethyl methylphosphonate, trimethylphosphate, phenylacetaldehyde, 1-methoxy-2-phenylethanol, 1-phenylethleneglycol, cis- and trans-1,3-diphenylcyclobutanes, hydrogen 1-(2-phenylethyl)methylphosphinate, (1-phenylethyl)dimethylphosphonate, and (1-phenylethyl)dimethylphosphonate via free radical processes. 相似文献
96.
Grant DM Elson DS Schimpf D Dunsby C Requejo-Isidro J Auksorius E Munro I Neil MA French PM Nye E Stamp G Courtney P 《Optics letters》2005,30(24):3353-3355
We demonstrate an optically sectioned fluorescence lifetime imaging microscope with a wide-field detector, using a convenient, continuously tunable (435-1150 nm) ultrafast source for fluorescence imaging applications that is derived from a visible supercontinuum generated in a microstructured fiber. 相似文献
97.
T. Badapanda V. Senthil S.K. Rout L.S. Cavalcante A.Z. Simões T.P. Sinha S. Panigrahi M.M. de Jesus E. Longo J.A. Varela 《Current Applied Physics》2011,11(6):1282-1293
In this work, we report the Rietveld refinement, microstructure, conductivity and impedance properties of Ba[Zr0.25Ti0.75]O3 ceramic synthesized by solid state reaction. This ceramic was characterized by X-ray diffraction, Rietveld refinement, scanning electron microscopy and energy dispersive X-ray spectrometry. Impedance spectroscopy analyses reveals a non-Debye relaxation phenomenon being its relaxation frequency moving toward to positive side with increase of temperature. A significant shift in impedance loss peaks toward higher frequency side indicates conduction in material and favoring the long range motion of mobile charge carriers. The frequency dependent ac conductivity at different temperatures indicates that the conduction process is thermally activated. The variation of dc conductivity exhibited a negative temperature coefficient of resistance behavior. The ac conductivity data are used to evaluate the density of states at Fermi level and activation energy of this ceramic. The dc electrical and thermal conductivities of grain and grain boundary have been discussed. 相似文献
98.
J. Dorenbosch F. Udo J. V. Allaby U. Amaldi G. Barbiellini M. Baubillier F. Bergsma A. Capone W. Flegel F. Grancagnolo M. Jonker L. Lanceri M. Metcalf C. Nieuwenhuis J. Panman R. Plunkett C. Santoni K. Winter I. Abt F. W. Büsser H. Daumann P. D. Gall T. Hebbeker F. Niebergall P. Stähelin P. Gorbunov E. Grigoriev V. Kaftanov V. Khovansky A. Rosanov A. Baroncelli L. Barone B. Borgia C. Bosio M. Diemoz U. Dore F. Ferroni E. Longo L. Luminari P. Monacelli S. Morganti F. de Notaristefani L. Tortora V. Valente CHARM Collaboration 《Zeitschrift fur Physik C Particles and Fields》1989,41(4):567-589
A determination of sin2 θ w based on measurements of elastic scattering of muon-neutrinos and muon-anti-neutrinos on atomic electrons is described. These purely leptonic processes were studied using the CHARM calorimeter exposed to neutrino and antineutrino wide-band beams at the CERN super proton synchrotron. A total of 83±16 neutrino-electron and 112±21 antineutrino-electron events have been detected. From the measurement of the ratio of muon-neutrino and muon-antineutrino cross-sections a value of sin2 θ w =0.211±0.037 was obtained. 相似文献
99.
Tatiane M. Arantes Giovanni P. Mambrini Daniel G. Stroppa Edson R. Leite Elson Longo Antonio J. Ramirez Emerson R. Camargo 《Journal of nanoparticle research》2010,12(8):3105-3110
Nanocrystalline zirconium oxide was synthesized by hydrothermal treatment of ZrO(NO3)2 and ZrOCl2 aqueous solutions at different temperatures and time in presence of hydrogen peroxide. Hydrothermal treatment of zirconium salts (0.25 and 0.50 mol L?1) produced nanocrystalline monoclinic ZrO2 powders with narrow size distribution, which were formed by the attachment of the smaller particles with crystallites size of 3.5 nm, estimated by means of the Scherrer’s equation and confirmed by transmission electronic microscopy. Typical monoclinic zirconium oxide X-ray powder diffraction patterns and Raman spectra were obtained for all the crystalline powders. It was observed that the crystallization depends strongly on the temperature, resulting in amorphous material when the synthesis was realized at 100 °C, and crystalline with monoclinic phase when synthesized at 110 °C, independently of the salt used. Zirconium oxide colloidal nanoparticles were formed only at hydrothermal treatments longer than 24 h. The stability of the colloids was successfully characterized of zeta potential, showing an initial value of + 59.2 mV in acid media and isoelectric point at pH = 5.2, in good agreement with previous studies. 相似文献
100.
Requejo-Isidro J McGinty J Munro I Elson DS Galletly NP Lever MJ Neil MA Stamp GW French PM Kellett PA Hares JD Dymoke-Bradshaw AK 《Optics letters》2004,29(19):2249-2251
We report the development of a high-speed wide-field fluorescence-lifetime imaging (FLIM) system that provides fluorescence-lifetime images at rates of as many as 29 frames/s. A FLIM multiwell plate reader and a potentially portable FLIM endoscopic system operating at 355-nm excitation have been demonstrated. 相似文献