Notiz über die Verteilung von Tetramethylammoniumpikrat zwischen Wasser und Nitrobenzol

Zusammenfassung Die Verteilung von Tetramethylammoniumpikrat zwischen Wasser und Nitrobenzol wurde gemessen. Die Konzentration der wäßrigen Lösung wurde mit Hilfe eines photoelektrischen Kolorimeters bestimmt. Die Versuche ergeben unter Annahme vollständiger Dissoziation in beiden Lösungsmitteln Werte für den Aktivitätskoeffizienten in Nitrobenzol, die mit derDebye-Hückelschen Theorie verträglich sind, obwohl eine etwa 7% höhere Neigung die Versuche etwas besser wiedergibt.Mit 1 Abbildung.Herrn Prof. Dr.A. Klemenc zum 70. Geburtstag gewidmet.     

An exponential lower bound for Cunningham’s rule

In this paper we give an exponential lower bound for Cunningham’s least recently considered (round-robin) rule as applied to parity games, Markov decision processes and linear programs. This improves a recent subexponential bound of Friedmann for this rule on these problems. The round-robin rule fixes a cyclical order of the variables and chooses the next pivot variable starting from the previously chosen variable and proceeding in the given circular order. It is perhaps the simplest example from the class of history-based pivot rules. Our results are based on a new lower bound construction for parity games. Due to the nature of the construction we are also able to obtain an exponential lower bound for the round-robin rule applied to acyclic unique sink orientations of hypercubes (AUSOs). Furthermore these AUSOs are realizable as polytopes. We believe these are the first such results for history based rules for AUSOs, realizable or not. The paper is self-contained and requires no previous knowledge of parity games.     

Computational aerodynamics of low Reynolds number plunging,pitching and flexible wings for MAV applications

Micro air vehicles （MAV＇s） have the potential to revolutionize our sensing and information gathering capabilities in environmental monitoring and homeland security areas. Due to the MAV＇s＇ small size, flight regime, and modes of operation, significant scientific advancement will be needed to create this revolutionary capability. Aerodynamics, structural dynamics, and flight dynamics of natural flyers intersects with some of the richest problems in MAV＇s, inclu- ding massively unsteady three-dimensional separation, transition in boundary layers and shear layers, vortical flows and bluff body flows, unsteady flight environment, aeroelasticity, and nonlinear and adaptive control are just a few examples. A challenge is that the scaling of both fluid dynamics and structural dynamics between smaller natural flyer and practical flying hardware/lab experiment （larger dimension） is fundamentally difficult. In this paper, we offer an overview of the challenges and issues, along with sample results illustrating some of the efforts made from a computational modeling angle.     

Novel Concepts for the Immunological Detection of Bound Residues

Abstract

Immunoassays could be applied successfully to the determination of bound residues in soil and other complex matrices. Nevertheless, there was some doubt whether these assays could be regarded as quantitative and selective. We present some results, which imply that several approaches are quite promising. One approach is based on a non-competitive saturation immunoassay, which evens out the different cross-reactivities of the bound species. This may lead to a true molar sum value, which is not an equivalent concentration. For competitive assays, a method for the determination of the affinity constant(s) of the bound species is discussed. This would enable a correction for the cross-reactivity. The selectivity problem could be diminished very much, too. The application of special blocking reagents and the use of inhibition tests essentially solved the problem of non-specific binding (NSB). In addition, it could be proven experimentally that adsorbed analytes do not disturb the non-competitive assays, which have been suspected to be highly selective for covalently bound residues.     

Wirkungsquerschnittsbestimmung von14N(n,p)14C für 14,7 MeV-Neutronen über eine Aktivitätsmessung von14C

The¹⁴N(n, p)¹⁴C cross-section for 14.7 MeV neutrons has been evaluated by the measurement of the activity of the formed¹⁴C. The value is 38±3 mb. This result was compared with calculations based on the statistical model for nuclear reactions.     

Effect of two-photon saturation on ordinary Raman scattering

The excitation profile of ordinary Raman scattering under steady-state excitation conditions and the time-resolved emission spectrum of ordinary Raman scattering under transient excitation conditions undergo considerable changes when the excitation frequency ω approaches $\text{1}\text{2}$ ω_mn, where ω_mn is the resonance frequency of a two-photon transition from the ground state |n to an excited state |m of a molecule. The appearance of ghost peaks, dips or dispersion-like features centred at ω ? $\text{1}\text{2}$ ω_mn in the excitation profile and of coherence effects such as Rabi nutations with unusual time-dependence in the time-resolved spectrum are predicted.     

Saturation effects in time-resolved and frequency-resolved resonance Raman and resonance fluorescence induced by realistic coherent pulses

Saturation effects in time — and frequency — resolved resonance Raman and resonance fluorescence are calculated using realistic steep quasi-rectangular pulses. In particular, our results reproduce the increased curvature of the leading edge of the time-resolved spectrum due to saturation observed by Rousseau and Williams.     

ON THE SIGNAL-TRANSDUCTION CHAINS OF TWO Pfr- MEDIATED SHORT-TERM PROCESSES: INCREASE OF ANCHORAGE and MOVEMENT OF Mougeotia CHLOROPLASTS

Abstract— We examined two published hypotheses on the signal-transduction chain of the light-oriented chloroplast movements in the fresh-water alga Mougeotia. One hypothesis postulates a Ca²+-influx controlled by a tetrapolar gradient of phytochrome in its far-red light absorbing form (Pfr). The other hypothesis postulates anchorage sites for actin-filaments even at those areas of the plasmalemma where phytochrome is in its inactive form (Pr). Calmodulin and Ca²+-sequestering vesicles are assumed to be essential links of this transduction chain.
To test these hypotheses we have studied the effects of Ca²+-entry blockers, Ca²+ deficiency and calmodulin antagonists on chloroplast movements and on chloroplast anchorage. None of our results support the Ca²+/calmodulin hypotheses mentioned above. The results and their implications (with regard to the role of Ca²', calmodulin and anchorage sites) are discussed.