全文获取类型
收费全文 | 786篇 |
免费 | 36篇 |
国内免费 | 7篇 |
专业分类
化学 | 484篇 |
晶体学 | 2篇 |
力学 | 66篇 |
数学 | 78篇 |
物理学 | 199篇 |
出版年
2024年 | 1篇 |
2023年 | 6篇 |
2022年 | 23篇 |
2021年 | 24篇 |
2020年 | 29篇 |
2019年 | 44篇 |
2018年 | 51篇 |
2017年 | 40篇 |
2016年 | 50篇 |
2015年 | 31篇 |
2014年 | 60篇 |
2013年 | 79篇 |
2012年 | 81篇 |
2011年 | 90篇 |
2010年 | 42篇 |
2009年 | 42篇 |
2008年 | 38篇 |
2007年 | 31篇 |
2006年 | 18篇 |
2005年 | 10篇 |
2004年 | 11篇 |
2003年 | 4篇 |
2002年 | 4篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1996年 | 3篇 |
1990年 | 4篇 |
1989年 | 1篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1970年 | 1篇 |
1968年 | 1篇 |
排序方式: 共有829条查询结果,搜索用时 15 毫秒
21.
22.
Maryam S. Sadeghi Mohammad Reza Moghbeli William A. Goddard III 《Journal of polymer science. Part A, Polymer chemistry》2021,59(7):614-626
We followed the self-assembly of high-molecular weight MePEG- b -PCL (poly(methyl ethylene glycol)-block-poly(ε-caprolactone)) diblock and MePEG- b -PBO- b -PCL (poly(methyl ethylene glycol)-block-poly(1,2-butylene oxide)-block-poly(ε-caprolactone)) into micelles using molecular dynamics simulation with a coarse grain (CG) force field based on quantum mechanics (CGq FF). The triblock polymer included a short poly(1,2-butylene oxide) (PBO) at the hydrophilic-hydrophobic interface of these systems. Keeping the hydrophilic length fixed (MePEG45), we considered 250 chains in which the hydrophobic length changed from PCL44 or PBO6- b -PCL43 to PCL62 or PBO9- b -PCL61. The polymers were solvated in explicit water for 2 μs of simulations at 310.15 K. We found that the longer diblock system undergoes a morphological transition from an intermediate rod-like micelle to a prolate-sphere, while the micelle formed from the longer triblock system is a stable rod-like micelle. The two shorter diblock and triblock systems show similar self-assembly processes, both resulting in slightly prolate-spheres. The dynamics of the self-assembly is quantified in terms of chain radius of gyration, shape anisotropy, and hydration of the micelle cores. The final micelle structures are analyzed in terms of the local density components. We conclude that the CG model accurately describes the molecular mechanisms of self-assembly and the equilibrium micellar structures of hydrophilic and hydrophobic chains, including the quantity of solvent trapped inside the micellar core. 相似文献
23.
Santa Islam Syed Shaheen Shah Prof. Shamsun Naher Dr. Muhammad Ali Ehsan Dr. Md. Abdul Aziz Dr. A. J. Saleh Ahammad 《化学:亚洲杂志》2021,16(22):3516-3543
Dopamine (DA) is an important neurotransmitter, which is created and released from the central nervous system. It plays a crucial role in human activities, like cognition, emotions, and response to anything. Maladjustment of DA in human blood serum results in different neural diseases, like Parkinson's and Schizophrenia. Consequently, researchers have started working on DA detection in blood serum, which is undoubtedly a hot research area. Electrochemical sensing techniques are more promising to detect DA in real samples. However, utilizing conventional electrodes for selective determination of DA encounters numerous problems due to the coexistence of other materials, such as uric acid and ascorbic acid, which have an oxidation potential close to DA. To overcome such problems, researchers have put their focus on the modification of bare electrodes. The aim of this review is to present recent advances in modifications of most used bare electrodes with carbonaceous materials, especially graphene, its derivatives, and carbon nanotubes, for electrochemical detection of DA. A brief discussion about the mechanistic phenomena at the electrode interface has also been included in this review. 相似文献
24.
The electronic (energy gap and work function) as well as electrical properties (dipole moment, polarizability, and first hyperpolarizabilities) of the first-row transition metals decorated C24N24 cavernous nitride fullerene were explored using DFT calculations. The transition metals are decorated at N4 cavity of C24N24 fullerene. According to our spin polarized computations, the most stable spin state monotonically increases to sextet for Mn@C24N24 and thereafter dropped off gradually to singlet state for Zn@C24N24 system. The findings demonstrate that transition metals can remarkably decrease the HOMO-LUMO energy gap and work function values up to 63% and 21% of bare C24N24, respectively. As can be seen, when the Sc and Ti metals are located above the N4 cavity of fullerene, systems of enhanced static hyperpolarizabilities (β0) are delivered. These findings might provide an effective strategy to design high performance eletcro-optical materials based on carbon- nitride fullerene. 相似文献
25.
Taghavizadeh Yazdi Mohammad Ehsan Modarres Masoomeh Amiri Mohammad Sadegh Darroudi Majid 《Research on Chemical Intermediates》2019,45(3):1105-1116
Research on Chemical Intermediates - We have synthesized silver nanoparticles (Ag-NPs) via a simple and eco-friendly method through the utilization of aqueous aerial parts of Salvia leriifolia... 相似文献
26.
Benjamin Arras Ehsan Azmoodeh Guillaume Poly Yvik Swan 《Stochastic Processes and their Applications》2019,129(7):2341-2375
We provide a bound on a distance between finitely supported elements and general elements of the unit sphere of . We use this bound to estimate the Wasserstein-2 distance between random variables represented by linear combinations of independent random variables. Our results are expressed in terms of a discrepancy measure related to Nourdin–Peccati’s Malliavin–Stein method. The main application is towards the computation of quantitative rates of convergence to elements of the second Wiener chaos. In particular, we explicit these rates for non-central asymptotic of sequences of quadratic forms and the behavior of the generalized Rosenblatt process at extreme critical exponent. 相似文献
27.
In this paper, we consider locally dually flat (??, ??)-metrics with isotropic S-curvature and find some necessary and sufficient conditions under which these metrics reduce to locally Minkowskian metrics. 相似文献
28.
We present a biographical sketch of Alenush Terian, the first Iranian woman physicist, who was known as the Iranian Solar Mother, since she founded the first solar telescopic observatory in Iran. She taught and carried out astronomical research for three decades with inadequate resources but with unflinching devotion, motivated by a strong desire to propagate scientific education and research in her country. 相似文献
29.
30.