全文获取类型
收费全文 | 444篇 |
免费 | 30篇 |
国内免费 | 9篇 |
专业分类
化学 | 300篇 |
晶体学 | 4篇 |
力学 | 20篇 |
数学 | 64篇 |
物理学 | 95篇 |
出版年
2023年 | 1篇 |
2022年 | 11篇 |
2021年 | 18篇 |
2020年 | 16篇 |
2019年 | 28篇 |
2018年 | 36篇 |
2017年 | 27篇 |
2016年 | 33篇 |
2015年 | 12篇 |
2014年 | 28篇 |
2013年 | 59篇 |
2012年 | 44篇 |
2011年 | 27篇 |
2010年 | 14篇 |
2009年 | 27篇 |
2008年 | 22篇 |
2007年 | 22篇 |
2006年 | 14篇 |
2005年 | 8篇 |
2004年 | 5篇 |
2003年 | 3篇 |
2002年 | 1篇 |
2001年 | 5篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1994年 | 1篇 |
1992年 | 1篇 |
1989年 | 2篇 |
1985年 | 2篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1978年 | 4篇 |
1977年 | 2篇 |
1975年 | 1篇 |
1974年 | 2篇 |
1965年 | 1篇 |
排序方式: 共有483条查询结果,搜索用时 15 毫秒
41.
This study aimed at polymerization of methyl methacrylate with novel catalysts in the atom transfer radical polymerization (ATRP) condition at 90 °C. This was accomplished using CuBr/N-(2-aminoethyl)-3-aminopropyltrimethoxysilane (CuBr–AEAPTMS) as a homogeneous catalyst and one time with CuBr@AEAPTMS/SBA-15 as a heterogeneous catalyst. Catalysts were characterized using TGA, FT-IR, and UV–Vis spectroscopy. The structural analysis of the polymer was carried out by 13C NMR spectroscopy and GPC. Three characteristic parts of polymer produced by ATRP method including the initiator, monomer units, and end group was shown in 13C NMR spectra. In addition, the presence of C–Br unit showed that the polymerization process is alive. The 1H NMR analysis was used for kinetic investigation of methyl methacrylate polymerization with homogeneous and heterogeneous catalysts that showed high monomer conversion (98 and 90% after 35 min, respectively) and good control of molecular weight with a dispersity (Ð = 1.5–1.7). In addition, the plot of ln ([monomer]0/[monomer] t ) versus time gave linear relationships indicating a constant concentration of the propagating species throughout the polymerization. Finally, the results of the polymerization using heterogeneous catalyst compared with homogeneous catalyst revealed that it was according to ATRP method. 相似文献
42.
43.
Ebrahim Hashemi 《Mediterranean Journal of Mathematics》2011,8(2):207-214
Let R be a ring with unity and M be a right R-module. The system M[x] forms a left near R[x]-module under addition and substitution operations. In this paper we extend the study of annihilator conditions on nearring
of polynomials to left near R[x]-module M[x], when M is a reduced Baer module. Also, we give a characterization of reduced modules. As a corollary we obtain some results of Birkenmeier
and Huang [3]. 相似文献
44.
Ahmed A. Ebrahim 《Brazilian Journal of Physics》2011,41(2-3):146-153
Angular distributions of differential cross sections for the 12C(π ±, π ±)12C and 12C(π ±, π ±)12C* reactions at pion kinetic energy ranging from 50 to 260 MeV have been analyzed with the 3α-particle model of 12C. The model provides good fits to a wide range of data. Differential cross sections for inelastic transitions to the (2?+?; 4.44 MeV) and (3???; 9.64 MeV) states in 12C are computed and the deformation lengths δ 2 and δ 3 are extracted. It is found that the extracted deformation lengths are sensitive to the nuclear model used and similar to the corresponding values found with other probes and nuclear models. 相似文献
45.
Mahmood Alaghmandan Yemon Choi Ebrahim Samei 《Journal of Mathematical Analysis and Applications》2014
Let G be a restricted direct product of finite groups {Gi}i∈I, and let Z?1(G) denote the centre of its group algebra. We show that Z?1(G) is amenable if and only if Gi is abelian for all but finitely many i , and characterize the maximal ideals of Z?1(G) which have bounded approximate identities. We also study when an algebra character of Z?1(G) belongs to c0 or ?p and provide a variety of examples. 相似文献
46.
A mild and efficient method for the synthesis of 1H-chromeno[2,3-d]pyrimidine-5-carboxamide derivatives via a one-pot, three-component reaction of an isocyanide, barbituric acid, and a salicylaldehyde in the presence of acetic acid in ethanol/water mixture at 75 °C is reported. This high atom economy reaction led to the construction of one benzopyran ring, and one amide group in a single synthetic step. 相似文献
47.
Background
Hemodialysis patient are at high risk for hepatitis B virus (HBV) infection. 相似文献48.
Masoumeh Zakeri Mohamed Mahmoud Nasef Tina Kargaran Arshad Ahmad Ebrahim Abouzari-Lotf Jahanbakhsh Asadi 《Research on Chemical Intermediates》2017,43(2):717-728
Optimization of a green approach to the synthesis of pyrano[2,3-c]pyrazoles based on the one-pot, four-component condensation via a domino Knoevenagel/Michael/cyclization sequence was investigated. This method involved the evaluation of the activity of several ionic liquids (ILs) in various solvents. This one-pot, four-component reaction revealed simplicity, higher yield and lower toxicity advantages over a corresponding three-component method. The effect of reaction parameters including the type and amount of catalyst, type of solvent, reaction temperature and time were studied with respect to yield of pyrano[2,3-c]pyrazoles. Catalyst recyclability and time-saving aspects of the reaction suggest that this method presents real alternatives over conventional reaction protocols. 相似文献
49.
Esmail Vessally Akram Hosseinian Ladan Edjlali Ebrahim Ghorbani-Kalhor Rahim Hosseinzadeh-Khanmiri 《Journal of the Iranian Chemical Society》2017,14(11):2339-2353
Indole derivatives are an important class of heterocycle found in a large number of natural products and synthetic pharmaceuticals. Given the low cost and easy availability of N-propargyl anilines, synthesis of indole cores from these versatile structural motifs has attracted a lot of attention in the past decade. In this review, we summarize the most representative and interesting reports on this rapidly advancing area, with special emphasis on mechanistic aspects of the reactions. 相似文献
50.
Ebrahim Abouzari-Lotf Abbas Shockravi Ali Javadi 《Polymer Degradation and Stability》2011,96(5):1022-1028
A series of novel fluorinated heat-resistant poly(amide imide)s (PAIS) based on non-coplanar diimide-diacid monomer (DIDA) were synthesized and characterized. The poly(amide imide)s were obtained in high yields and possessed inherent viscosities in the range of 0.47-0.91 dL g−1. All of the polymers were amorphous in nature, showed outstanding solubility and could be readily soluble in common organic solvents such as N,N-dimethylacetamide, N-methyl-2-pyrrolidinoned, dimethyl sulfoxide, N,N-dimethylformamide, pyridine and tetrahydrofuran. Glass transition temperatures were in the range of 221-263 °C, as determined by differential scanning calorimetry. Degradation temperatures for 10% weight loss occurred all above 520 °C and char yields was more than 50% at 700 °C in nitrogen atmosphere. Moreover, these PAIs possessed low refractive indexes (n = 1.58-1.59), birefringence (Δn = 0.008-0.013), and dielectric constants (? ≈ 2.5) due to the trifluoromethyl pendent groups and ortho-catenated aromatic rings that interrupt chain packing and increase free volume. 相似文献