全文获取类型
收费全文 | 557篇 |
免费 | 28篇 |
国内免费 | 12篇 |
专业分类
化学 | 383篇 |
晶体学 | 4篇 |
力学 | 21篇 |
数学 | 86篇 |
物理学 | 103篇 |
出版年
2023年 | 5篇 |
2022年 | 12篇 |
2021年 | 24篇 |
2020年 | 27篇 |
2019年 | 32篇 |
2018年 | 40篇 |
2017年 | 30篇 |
2016年 | 50篇 |
2015年 | 16篇 |
2014年 | 38篇 |
2013年 | 69篇 |
2012年 | 48篇 |
2011年 | 31篇 |
2010年 | 25篇 |
2009年 | 26篇 |
2008年 | 25篇 |
2007年 | 27篇 |
2006年 | 17篇 |
2005年 | 12篇 |
2004年 | 8篇 |
2003年 | 5篇 |
2002年 | 3篇 |
2001年 | 6篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1994年 | 1篇 |
1989年 | 2篇 |
1985年 | 2篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1978年 | 4篇 |
1977年 | 2篇 |
1975年 | 1篇 |
1974年 | 2篇 |
排序方式: 共有597条查询结果,搜索用时 15 毫秒
31.
Sadeghi Mohamad Sadegh Anadalibkhah Naghmeh Ghasemiasl Ramin Armaghani Taher Dogonchi Abdul Sattar Chamkha Ali J. Ali Hafiz Asadi Amin 《Journal of Thermal Analysis and Calorimetry》2022,147(1):1-22
Journal of Thermal Analysis and Calorimetry - The ultimate goal of the present review paper is to summarize and discuss the findings of the most recently published literature on natural convection... 相似文献
32.
Hosseinzadeh Kh. Asadi A. Mogharrebi A. R. Ermia Azari M. Ganji D. D. 《Journal of Thermal Analysis and Calorimetry》2021,143(2):1081-1095
Journal of Thermal Analysis and Calorimetry - In this study, flow of a mixture of water and ethylene glycol (50–50%) with hybrid nanoparticles (MWCNT–Ag) over a vertical stretching... 相似文献
33.
34.
Fatemeh Saghatchi Ebrahim Ahmadi Zahra Mohamadnia Hassan Hajifatheali Hashem Tabebordbar Farnoosh Karimi 《Chemical Papers》2014,68(11):1555-1560
This study is aimed at atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) using a novel catalyst. The bis-(2-dodecylsulfanyl-ethyl)-amine (SNS) tridentate ligand with mixed donor atoms was synthesized in high purity using inexpensive reagents and was reacted with copper(I) bromide to produce the CuBr/SNS catalyst. The catalyst mediated living polymerization of MMA yielding polymers with controlled molecular masses and narrow molecular mass distributions (PDI < 1.25). Also, the kinetic plot exhibited a linear increase of ln([M]0/[M]) versus time, indicating constant concentration of propagating radicals during the polymerization. The products were characterized by 1H NMR, 13C NMR, FT-IR, UV-VIS, GC and elemental analyses (CHNS) and by GPC. 相似文献
35.
AbstractThe present article provides a review on the nonlinear mechanical behavior of polymer matrix composites (PMCs). Initially, essential mechanisms driving the nonlinear response of PMCs under different loading conditions are discussed. Rate-dependence, tension-compression asymmetry, viscous behavior, unloading characteristics, interaction between stress components and effects of environmental factors on mechanical properties are briefly reviewed. This is followed by a review of major approaches and constitutive models for predicting stress–strain behavior of PMCs. Following an increasing degree of complexity, models are categorized into four major classes: nonlinear elasticity models, elastic-plastic models, elastic-plastic-viscous models and Damage-Plasticity models. The vast number of existing models is mainly due to the anisotropy and inhomogeneity of PMCs. In brief, this review focuses on informing the reader of major frameworks, rather than addressing all the models in detail. 相似文献
36.
Effluents of a large variety of industries usually contain important quantities of synthetic organic compounds. The discharge of these compounds in the environment causes considerable non-aesthetic pollution and serious health risk factors. Since conventional wastewater treatment plants cannot degrade the majority of these pollutants, powerful methods for the decontamination of dye wastewaters have received increasing attention over the past decade. In this work, fundamentals and main applications of photoelectrocatalysis as one of the most powerful and recent progresses of emerging photoassisted electrochemical treatments with UV irradiation are studied. The effect of various effective factors such as photoanode type, light source and its intensity, pH solution value, type and concentration of supporting electrolyte, type of cathode electrode, to be moving of photoanode or solution, thicknesses of semiconductor film on the electrode surface, and applied potential on the destruction of pollutants is described. Furthermore, various methods used for TiO2 modification are mentioned. Also, application of photocatalysts except semiconductors is presented for photoelectrocatalytic aims. Finally, application of photoelectrocatalysis in determination of materials as a new method is discussed. 相似文献
37.
Mohammad Hossein Tavakoli Hossein KarbaschiFeridoun Samavat Ebrahim Mohammadi-Manesh 《Journal of Crystal Growth》2010,312(21):3198-3203
A set of 2D finite element numerical simulation of induction heating process for an oxide Czochralski crystal growth system has been made for a range of f=1–100 kHz applied frequency of driving current. It was shown that the frequency selection has a marked effect in all basic induction phenomena, including electromagnetic field distribution, skin depth, coil efficiency, and intensity and structure of heating in the growth setup. 相似文献
38.
Tofighi-Niaki Ebrahim Asgharifard-Sharabiani Pouya Ahmadian Hamid 《Nonlinear dynamics》2018,94(4):2937-2956
Nonlinear Dynamics - Rub–impact phenomenon occurring in hydrodynamic journal bearings is one of the main malfunctions in rotating machines and causes undesirable dynamic behavior. In order to... 相似文献
39.
Faezeh Toutounian Davod Khojasteh Salkuyeh Bahram Asadi 《Journal of Applied Mathematics and Computing》2005,17(1-2):457-473
In each step of the quasi-minimal residual (QMR) method which uses a look-ahead variant of the nonsymmetric Lanczos process to generate basis vectors for the Krylov subspaces induced byA, it is necessary to decide whether to construct the Lanczos vectorsv n +1 andw n +1 as regular or inner vectors. For a regular step it is necessary thatD k =W k T V k is nonsingular. Therefore, in the floating-point arithmetic, the smallest singular value of matrix Dk,σ min (D k ), is computed and an inner step is performed ifσ min (D k )<∈, where ∈ is a suitably chosen tolerance. In practice it is absolutely impossible to choose correctly the value of the tolerance ∈. The subject of this paper is to show how discrete stochastic arithmetic remedies the problem of this tolerance, as well as the problem of the other tolerances which are needed in the other checks of the QMR method with the estimation of the accuracy of some intermediate results. Numerical examples are used to show the good numerical properties. 相似文献
40.
Silver nanoparticles supported on ionic‐tagged magnetic hydroxyapatite as a highly efficient and reusable nanocatalyst for hydrogenation of nitroarenes in water
下载免费PDF全文
![点击此处可从《应用有机金属化学》网站下载免费的PDF全文](/ch/ext_images/free.gif)
A novel chemically modified magnetic hydroxyapatite (MHAp) was prepared and used as support and stabilizer for the synthesis of silver nanoparticles. First, 1,4‐diazabicyclo[2.2.2]octane (DABCO) was successfully grafted onto the surface of MHAp, and then silver nanoparticles were homogeneously loaded on mesoporous MHAp‐DABCO (ionic‐tagged MHAp) nanocomposite by in situ chemical reduction of silver nitrate using sodium borohydride. The structure and properties of the resulting MHAp‐DABCO‐Ag nanocomposite were confirmed using various techniques. The catalytic activity of ionic‐tagged MHAp‐Ag nanocatalyst was investigated for the hydrogenation reaction of nitroarenes in aqueous media. The results reveal that the Ag‐containing inorganic–organic nanocomposite is highly efficient for the reduction of a wide range of aromatic nitro compounds under green conditions. The superparamagnetic nature of the nanocatalyst leads to its being readily removed from solution via application of a magnetic field, and it can be easily stored and reused. 相似文献