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111.
Daria E. Lonsdale Geoffrey Johnston‐Hall Amanda Fawcett Craig A. Bell Carl N. Urbani Michael R. Whittaker Michael J. Monteiro 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3620-3625
In this work, we propose that retardation in vinyl acetate polymerization rate in the presence of toluene is due to degradative chain transfer. The transfer constant to toluene (Ctrs) determined using the Mayo method is equal to 3.8 × 10?3, which is remarkably similar to the value calculated from the rate data, assuming degradative chain transfer (2.7 × 10?3). Simulations, including chain‐length‐dependent termination, were carried out to compare our degradative chain transfer model with experimental results. The conversion–time profiles showed excellent agreement between experiment and simulation. Good agreement was found for the Mn data as a function of conversion. The experimental and simulation data strongly support the postulate that degradative chain transfer is the dominant kinetic mechanism. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3620–3625, 2007 相似文献
112.
113.
V. I. Bliznikas A. P. Norden B. N. Shapukov A. P. Shirokov 《Journal of Mathematical Sciences》1991,55(6):2091-2100
Biographical information on the eminent Soviet geometer Boris Lukich Laptev (4/23/05–1/15-89) is given as well as a survey of his research in the areas of differential geometry and history of mathematics.Translated from Itogi Nauki i Tekhniki, Seriya Problemy Geometrii, Vol. 21, pp.27–42, 1989. 相似文献
114.
Pál Sohár Gábor Bernáth Géza Stájer Angela E. Szabo 《Magnetic resonance in chemistry : MRC》1989,27(9):872-876
Pentacyclic isoxazolines were obtained by the cycloaddition of benzonitrile oxide to norbornene-azetidinone-fused 3,1-oxazines. The constitutions of two of the isomers obtained, and the configurations and conformations of all products, were determined by means of 1H and 13C NMR spectroscopy and DNOE experiments. 相似文献
115.
Lerner E.J. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》1989,17(2):259-263
A cosmological model is presented that produces He, C, O, D, Li, Be, and B in their observed abundances without a Big Bang. The elements are produced during the 1.5-Gy formation period of a galaxy, with C, O, and other heavy elements produced by stars of M >12 M3 , He by stars of 6 Ms<M <12 Ms, and D, Li, Be, and B by cosmic-ray reactions in a nearly pure H plasma halo. Thus, the model shows that the major elements used in astrophysical studies can be produced during galactic formation by exactly the same processes known to function today at much lower rates 相似文献
116.
V. B. Levenshtam 《Siberian Mathematical Journal》1989,30(4):554-559
Rostov-on-Don. Translated from Sibirskii Matematicheskii Zhurnal, Vol. 30, No. 4, pp. 69–75, July–August, 1989. 相似文献
117.
A. V. Lebedev 《Acoustical Physics》2002,48(3):339-346
The possibility of using the resonant acoustic spectroscopy method for testing the internal state of rock is considered. This method can be used for the determination of the concentration of defects and their spatial distribution. A rock specimen with defects is characterized by a high loss of vibrational energy, which leads to the overlapping of the resonant responses. In this case, the complex resonant frequencies are determined as the parameters of a model that describes the measured transfer function of the response of the mechanical system. The linearity of the vibratory system is used as the a priori information for presetting the functional dependences of the model. An algorithm is developed for the determination of the parameters of the resonances in conditions of their partial overlapping. Examples are presented to demonstrate the possibility of analyzing the complex elastic constant tensor of rock by the acoustic spectroscopy method. The proposed method of experimental data processing provides the possibility for the determination of the weak anisotropy that occurs in the velocity of sound because of a partial fracture of rock. 相似文献
118.
The statistical characteristics of conditional time before ruin of an insurance company, including the distribution function of conditional time and its moments are examined. 相似文献
119.
Exact solutions of the Lagrange equations in the Logunov metric are found in the context of classical gravitation theory. 相似文献
120.
A relaxation kinetic equation that describes the behavior of a Bose gas is derived. The Kramers half-space problem on isothermal slip is treated. An analytical solution and the number-of-particle distribution function for particles flying toward a wall, in explicit form, are obtained. The dependence of the slip velocity on the parameter that is the ratio of the chemical potential to the product of Boltzmann's constant by the absolute temperature is analyzed. The influence of the quantum effects on the isothermal slip coefficient is evaluated for He4. 相似文献