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101.
During the course of our investigation of the electron transfer properties of some redox species through highly hydrophobic
long chain alkanethiol molecules on gold in aqueous and non-aqueous solvents, we obtained some intriguing results such as
unusually low interfacial capacitance, very high values of impedance and film resistance, all of which pointed to the possible
existence of a nanometer size interfacial gap between the hydrophobic monolayer and aqueous electrolyte. We explain this phenomenon
by a model for the alkanethiol monolayer—aqueous electrolyte interface, in which the extremely hydrophobic alkanethiol film
repels water molecules adjacent to it and in the process creates a shield between the monolayer film and water. This effectively
increases the overall thickness of the dielectric layer that is manifested as an abnormally low value of interfacial capacitance.
This behaviour is very much akin to the ‘drying transition’ proposed by Lum, Chandler and Weeks in their theory of length
scale dependent hydrophobicity. For small hydrophobic units consisting of apolar solutes, the water molecules can reorganize
around them without sacrificing their hydrogen bonds. Since for an extended hydrophobic unit, the existence of hydrogen bonded
water structure close to it is geometrically unfavourable, there is a net depletion of water molecules in the vicinity leading
to the possible creation of a hydrophobic interfacial gap. 相似文献
102.
应用TGT法生长了直径为75mm的U:CaF2晶体,宏观上透明完整.应用公式K0=Cs/Cl计算了U在CaF2晶体中的分凝系数等于0.53.应用溶质分布一般公式Cs=K0C0(1-g)K0-1,计算U的浓度分布与测量值,数值符合说明晶体生长过程接近平衡状态.分析不同条件下生长的U: CaF2晶体的晶胞参数和吸收光谱,结果表明生长气氛决定U的价态及电荷补偿机理:无PbF2存在的条件下,U为+4价,晶体呈绿色;PbF2的加入起到氟化去氧作用,U倾向于以离子半径最接近于Ca2+的U3+存在,晶体呈红色.从晶体生长开始到结束的部位,U3+:CaF2晶体吸收光谱的峰位不变,峰强呈现与U浓度相同的增加趋势.U3+:CaF2晶体外层厚约5mm处呈黄色,含有U3+和U2+的混合价态离子,其原理是石墨坩埚的还原作用通过单质铅,使部分的U3+进一步还原成了U2+.
关键词:
铀
氟化钙晶体
分凝系数
晶胞参数 相似文献
103.
Dimitar I. Pushkarov 《Central European Journal of Physics》2004,2(3):420-455
Basic ideas and results which characterize quantum diffusion of defects in quantum crystals like solid helium as a new phenomenon
are presented. Quantum effects in such media lead to a delocalization of point defects (vacancies, impurities etc.) and they
turn into quasiparticles of a new type—defectons, which are characterized not by their position in the crystal lattice but
by their quasimomentum and dispersion law. Defecton-defecton and defecton-phonon scattering are considered and an interpolation
formula for the diffusion coefficient valid in all interesting temperature and concentration regions is presented. A comparison
with the experimental data is made. Some alternative points of view are discussed in detail and the inconsistency of the Kisvarsanyi-Sullivan
theory is shown. 相似文献
104.
Noboru Nakatani 《Optical Review》2003,10(4):206-210
This paper describes a compulsorily phase locked differential interferometer using an orthogonally polarized light source of a modulated LD with high extinction ratio to reduce non-linearity of the interferometer caused by polarization cross-talk. The current modulated LD is used as a light source to make the interferometer compact and for the scanning phase of the interferometer. The interferometer is operated compulsorily at the maximum inclination point of the fringe intensity curve by fringe scanning and an electric system. A Wollaston prism of high extinction ratio (50 dB) is used to combine the polarizing beams and to make the polarization cross-talk very small. In one light source the polarized output beams are on the same propagation axis; in the other they have a small crossing angle (2.5 mrad ∼ 10 mrad) to completely exclude non-linearity of the interferometer causded by polarization cross-talk. Using jets of a gas mixture of nitrogen and ethylene, this interferometer was demonstrated to be useful in detecting the photothermal effect of a photothermal velocimeter under phase fluctuation in a turbulent flow. 相似文献
105.
In this paper we obtain a number of Maharam-type slice integral representations, with respect to scalar measures, for positive
projections in Dedekind complete vector lattices and f-algebras.
AMS Classification: 47B65, 46A40, 06F25 相似文献
106.
Valery V. Kiselev 《Central European Journal of Physics》2004,2(3):523-534
We calculate the leptonic constant for the pseudoscalar ground state of the B
c
meson in the framework of a QCD-motivated potential model taking into account the two-loop anomalous dimension for the heavy
quark current in nonrelativistic QCD as matched with full QCD. 相似文献
107.
Gaston Casanova 《Advances in Applied Clifford Algebras》2004,14(2):249-252
We define analytic functions within Clifford Algebras CL, and study their trigonometric properties. We write the addition formulas when their arguments, A and B in CL, commute, this generalizes ordinary trigonometry. We examine in particular the case A2 = 1.
相似文献
108.
M. Lashkarizadeh Bami 《Semigroup Forum》2004,69(2):219-229
In the present paper it is shown that if S1 and S2 are two
Clifford topological semigroups satisfying certain conditions
and T is an isometric isomorphism of LUC(S1*) onto LUC(S2*), then T
maps S1 topologically isomorphically onto S2. Furthermore, T
maps M
l
n(S1) (M(S1), respectively) isometrically
isomorphically onto M
l
n(S2) (M(S2), respectively). Indeed,
we have obtained a generalization of a well-known result of
Ghahramani, Lau and Losert for locally compact groups to a more
general setting of Clifford topological semigroups. 相似文献
109.
Andrew Barton 《The Journal of the Operational Research Society》1987,38(10):965-974
This paper describes some work carried out in the Scientific Research and Development Branch (SRDB) of the Home Office, intended to contribute to an overall aim of building up internal expertise in the field of expert systems. This was done by carrying out a number of pilot and demonstrator projects, two of which are described in some detail. The plan, which proved successful, was to build as far as possible on the relevant skills already possessed by an OR group in the branch. The lessons learned from these are summarized in the hope that they will be of use to other groups who wish to become involved in this important area. 相似文献
110.
本文对一类具有对称轴的图A_n(n≥0),得到了它的特征多项式及匹配多项式的精确表达式;同时还得到A_(?)的完美匹配数。 相似文献