Ionic liquid-based headspace single-drop microextraction coupled to gas chromatography for the determination of chlorobenzene derivatives

A novel method, based on the coupling of ionic liquid-based headspace single-drop microextraction (SDME) with gas chromatography (GC), is developed for the determination of chlorobenzene derivatives. For the SDME of five chlorobenzene derivatives, a 1.0 μL 1-octyl-3-methylimidazolium hexafluorophosphate microdrop is exposed for 20 min to the headspace of a 15 ml aqueous sample containing 20% (w/v) NaCl placed in 25 ml vial at 40 °C. Then, the extractant is directly injected into the injector block of the GC instrument. To avoid ionic liquid leaking into the chromatographic column, a small glass tube is placed in the injection block. Under optimized operation conditions, linear relation between peak areas and analyte concentrations up to 1.5 mg L^?1 has been obtained The detection limits range from 0.1 to 0.5 μg L^?1 for the various analytes. The relative standard deviations at 1.0 μg L^?1 range from 7.7 to 12.4%, and the enrichment factors from 41 to 127. The method is simple and sensitive, and does not suffer from the influence of a solvent peak. Its applicability is demonstrated by the determination of chlorobenzenes in wastewater samples.     

关于控制算子的若干注记

Let B(H) be the set of all bounded linear operators on a Hilbert space H. An operator T∈B(H) is called dominant if (T-λ)(T-λ)^*≤M_λ²(T-λ)^*(T-λ),?λ∈C.The numerical range of T is difined by W (T) = {(Tx, x): ‖x‖ = 1, x∈H}. In Section 1 some new characteristic of dominant operators are given. If C = AB - BA, we prove that O∈W(C)^- then A is a dominart or φ-quasihy ponor-mal. In Section 2 we prove that O∈σ_e(△_A^σ) if A is a dominant, where(?), we also prove that if A∈B(H) is a norm attaining Ф-quasihyponormal, then A has a non-trivial invariant subspace. In Section 3 we discuss the closeness of the range of bounded linear operator F_AB:X→AX-XB, and prove that R(δ_A)∩{A}′∩{Aⁿ}′=0, where δ_A:X→AX-XA.     

Morphology of critical nuclei in solid-state phase transformations

Predicting the shape of a critical nucleus in solids has been a long-standing problem in solid-state phase transformations. We show that a diffuse-interface approach together with a minimax algorithm is able to predict the critical nucleus morphology in elastically anisotropic solids without a priori assumptions. We demonstrate the possibility of nonconvex surfaces for critical nuclei. It is found that strong elastic energy contributions may lead to critical nuclei whose point group symmetry is below the crystalline symmetries of both the new and the parent phases.     

Diode-pumped efficient slab laser with two Nd:YLF crystals and second-harmonic generation by slab LBO

We demonstrate a diode-pumped electro-optical Q-switched slab laser with a high optical efficiency, high pulse energy, and short pulse width with two Nd:YLF crystals inside one resonator. The single compact slab resonator can generate a 1D top-hat beam at both the far field and the near field. With a slab-geometry-design lithium triborate (LBO) crystal, efficient critical phase-matching second-harmonic generation for a 1D top-hat beam with multiple transverse modes is achieved.     

Dynamics of a Diffusion Malaria Model With Vector-Bias北大核心CSCD

为了探讨季节性、蚊子叮咬的偏好性和人类的扩散对疟疾传播的影响,该文提出了一个部分退化的周期反应扩散模型.利用动力系统的持续性理论,研究了模型关于基本再生数R₀的阈值动力学.即当R₀<1时,疾病灭绝;而当R₀>1时,疾病一致持续,且会发生季节性的流行.数值上发现了忽略空间异质性和蚊子叮咬的偏好性会低估疾病传染的风险.     

Instability Entanglement in the Electron Cyclotron Maser

Investigation of absolute instability (AI) and convective instability (CI) of the electron cyclotron maser has independently led to the birth of gyrotron oscillators and amplifiers. Here, it is demonstrated that these instabilities can form a cooperative relationship owing to the nonlinear behavior of the stimulated electron beam. The CI can be induced in a zero-drive system with the assistance of AI, and the ohmic losses of all the excited waves inside the system are greatly reduced, which is called “instability entanglement” here. According to the theoretical and experimental study of a 167/330 GHz gyrotron, when instability entanglement occurs, the ohmic dissipation decreases to one-ninth of the AI-only condition, and the output power is enhanced by 20%. This discovery is promising for surpassing the ceiling of output power and frequency of gyrodevices placed by ohmic losses.     

八节点等参元滑动接触算法的改进

分析认为采用八节点等参元计算滑动接触问题时,往往存在较大的接触应力计算误差的主要原因在于这种单元具有两种不同的节点。为此,本文提出了双模拟接触边界法,即分别采用两种不同的节点,形成两个模拟接触边界,并限制“从接触边界”上的节点只能和“主接触边界”上其同类节点形成的模拟接触边界形成接触关系,从而有效的减小了采用八节点等参元计算滑动接触问题时的误差。     

NUMERICAL METHOD AND APPLICATION FOR THREEDIMENSIONAL NONLINEAR SYSTEM OF DYNAMICS OF FLUIDS IN POROUS MEDIA

For the system of multilayer dynamics of fluids in porous media, the second order upwind finite difference fractional steps schemes applicable to parallel arithmetic are put forward. Some techniques, such as calculus of variations, energy method, multiplicative commutation rule of difference operators, decomposition of high order difference operators and prior estimates are adopted. Optimal order estimates are derived to determine the error in the second order approximate solution. These methods have already been applied to the numerical simulation of migration-accumulation of oil resources.     

一种非对称大型有限元方程组的有效分块波前解法

提出分块波前法求解非对称大型有限元方程组，该方法综合分块解法和波前法的优点，根据计算机容量和方程的阶数优化计算过程，以在经济效率和存储效率之间达到平衡。本文利用该方法求解了轮胎稳态滚动有限元方程组，表明该方法是有效、可靠的。     

中国区域稳定工程地质学产生与发展

区域稳定工程地质学是在中国产生、发展和壮大起来的。自50年代产生以来，历经几代工程地质工作者的不懈努力，现已形成了具有系统理论和系统研究方法、在国民经济建设中正发挥着显着作用的新兴学科。回顾该学科的产生与发展过程，对促进该学科的思维方法、学科理论和进一步发挥学科作用具有重要的意义。