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61.
The composite comprised of zinc oxide quantum dots and poly(amic acid) (PAAc) was prepared and studied by X-rays diffraction, X-ray photoelectron spectroscopy, light scattering, UV absorbance and UV fluorescence. The UV absorbance of the ZnO/PAAc composite was found to be much larger than that of its components taken separately. The fluorescence of the ZnO/PAAc composite was found to be shifted to longer wavelengthes in comparison with pure ZnO. The presence of the dopant dodecylbenzenesulfonic acid was found to affect the observed fluorescence. 相似文献
62.
A switching of the S-type in the 20–200 μm thick polycrystalline n-CdTe:In layers with resistance of 103–106 Ω·cm is studied. The electric instability in the layers is found to be due to the electron-thermal breakdown mechanism. The
dependence of the switching threshold parameters on the intensity of exposure can be used for fabrication of infrared-radiation
controlled electric switches on the basis of n-CdTe:In layers.
__________
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 28–30, June, 2005. 相似文献
63.
David S. McGuinness Edward L. Marshall Vernon C. Gibson Jonathan W. Steed 《Journal of polymer science. Part A, Polymer chemistry》2003,41(23):3798-3803
Hetero‐bimetallic Fe(II) alkoxide/aryloxides were evaluated as initiators for the ring‐opening polymerization of rac‐lactide. [(THF)NaFe(OtBu)3]2 ( 1 ) and [(THF)4Na2Fe(2,6‐diisopropylphenolate)4] ( 2 ) (THF = tetrahydrofuran) both polymerized lactide efficiently at room temperature, with complex 1 affording better control over the molecular weight parameters of the resultant polymer. At conversions below 70%, a linear increase in molecular weight with conversion was observed, indicative of a well‐controlled polymerization process. Complex 2 is the first example of a dianionic Fe(II) alkoxide and has been structurally characterized to reveal a distorted square planar FeO4 array in which both Na counterions bridge two aryloxide ligands and are further complexed by two THF ligands. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3798–3803, 2003 相似文献
64.
M. Ya. Amusia N. A. Cherepkov L. V. Chernysheva 《Journal of Experimental and Theoretical Physics》2003,97(1):34-41
The results of calculations of the elastic scattering cross section of positrons on noble gas and alkali atoms are presented. The calculations are performed within the one-electron Hartree-Fock approximation with multielectron correlations in the so-called random phase approximation with exchange taken into account. Virtual positronium formation is taken into account and proved to be very important. Arguments are presented that the positron polarization potential is repulsive for alkali atoms. The results obtained are in a reasonable agreement with experiment and with some previously reported calculations. 相似文献
65.
The surface of hydrogen-sensitive GaAs Schottky diodes is modified by nonpolishing etching and by producing quantum wells and quantum dots in the space-charge region of the semiconductor. The sensitivity to hydrogen is found to increase by a factor of 8–37 after the etching and by two or three orders of magnitude after the introduction of quantum wells and dots. It is shown that the increased sensitivity is associated with the lowering of the barrier at the Pd/GaAs interface, the retardation of hydrogen diffusion into GaAs due to the presence of strained quantum-size layers, and an increase in the recombination current. The presence of the recombination component is supported by luminescence from the quantum wells and quantum dots, as well as from the GaAs substrate. The etch composition is shown to be a decisive factor in raising the sensitivity. 相似文献
66.
H.L. Xu A. Persson S. Svanberg 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,23(2):233-236
New radiative lifetime measurements based on time-resolved laser-induced fluorescence techniques are reported for 18 even-parity
levels belonging to the 4f5d26p and 4f
25d
2 configurations of Ce I and 6 even-parity levels belonging to the 5d26s, 4f5d6p, and 4f6s6p configurations of Ce II. Free neutral and singly ionized cerium atoms were produced by laser ablation. The Ce I and Ce II
levels range in energy from 26 545 to 29 102 cm-1, and 42 573 to 48 152 cm-1, respectively.
Received 25 September 2002 Published online 4 March 2003 相似文献
67.
R. Pizzoferrato L. Lagonigro T. Ziller A. Di Carlo R. Paolesse F. Mandoj A. Ricci C. Lo Sterzo 《Chemical physics》2004,300(1-3):217-225
We study the infrared emission at 1.54 μm of an organolanthanide complex, Er(III)-tetraphenylporphyrin [Er(TPP)acac], both as a result of direct optical excitation and via energy transfer from host π-conjugate polymers of type poly(arylene–ethynylene) [PAE]. In the first case, the emission of the neat complex is characterized in inert transparent materials and a value of the quantum yield at 1.54 μm φIR=4×10−4 is measured. Then, fluorescence resonance transfer is investigated in blends of Er(TPP)acac with PAEs by monitoring the quenching of the polymer fluorescence along with the enhancement of both the visible emission of the ligand and the near-infrared band of Er3+. These different procedures allow a detailed analysis of the transfer efficiency within a specific implementation of the Förster model for polymeric donors. The experimental values of the critical radius R0, ranging from 1.3 to 2.5 nm for the different blends, are in good agreement with theory for a wide interval of the physical and spectroscopic parameters. This suggests that other mechanisms for excitation transfer do not play a significant role in these materials. 相似文献
68.
Michael S. Donovan Andrew B. Lowe Taylor A. Sanford Charles L. McCormick 《Journal of polymer science. Part A, Polymer chemistry》2003,41(9):1262-1281
A novel bifunctional acrylamido‐based reversible addition–fragmentation chain transfer (RAFT) chain‐transfer agent (CTA), N,N′‐ethylenebis[2‐(thiobenzoylthio)propionamide] (CTA2), has been synthesized and used for the controlled free‐radical polymerization of N,N‐dimethylacrylamide (DMA). A comparative study of CTA2 and the monofunctional CTA N,N‐dimethyl‐s‐thiobenzoylthiopropionamide (CTA1) has been conducted. Polymerizations mediated by CTA1 result in poly(N,N‐dimethylacrylamide) (PDMA) homopolymers with unimodal molecular weight distributions, whereas CTA2 yields unimodal, bimodal, and trimodal distributions according to the extent of conversion. The multimodal nature of the PDMAs has been attributed to termination events and/or chains initiated by primary radicals. The RAFT polymerization of DMA with CTA2 also results in a prolonged induction period that may be attributed to the higher local concentration of dithioester functionalities early in the polymerization. A series of ω‐ and α,ω‐dithioester‐capped PDMAs have been prepared in organic media and subsequently employed as macro‐CTAs for the synthesis of diblock and triblock copolymers in aqueous media with the zwitterionic monomer 3‐[2‐(N‐methylacrylamido)‐ethyldimethylammonio] propane sulfonate (MAEDAPS). Additionally, an ω‐dithioester‐capped MAEDAPS homopolymer has been used as a macro‐CTA for the block polymerization of DMA. To our knowledge, this is the first example of a near‐monodisperse, sulfobetaine‐containing block copolymer prepared entirely in aqueous media. The diblock and triblock copolymers form aggregates in pure water that can be dissociated by the addition of salt, as determined by 1H NMR spectroscopy and dynamic light scattering. In pure water, highly uniform, micellelike aggregates with hydrodynamic diameters of 71–93 nm are formed. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1262–1281, 2003 相似文献
69.
Alison L. Parry 《Journal of polymer science. Part A, Polymer chemistry》2007,45(15):3178-3190
The ring‐opening metathesis polymerizations (ROMP), using RuCl2 (PCy3)2CHPh, of a series of peptide‐functionalized norbornene derivatives have been investigated. Incorporation of a PEG‐monomer was found to prevent premature precipitation of polymer strands during the course of polymerization reactions and yield water compatible polymers in high conversions. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3178–3190, 2007 相似文献
70.
Anna L. Mazzucato 《Transactions of the American Mathematical Society》2003,355(4):1297-1364
This paper is devoted to the analysis of function spaces modeled on Besov spaces and their applications to non-linear partial differential equations, with emphasis on the incompressible, isotropic Navier-Stokes system and semi-linear heat equations. Specifically, we consider the class, introduced by Hideo Kozono and Masao Yamazaki, of Besov spaces based on Morrey spaces, which we call Besov-Morrey or BM spaces. We obtain equivalent representations in terms of the Weierstrass semigroup and wavelets, and various embeddings in classical spaces. We then establish pseudo-differential and para-differential estimates. Our results cover non-regular and exotic symbols. Although the heat semigroup is not strongly continuous on Morrey spaces, we show that its action defines an equivalent norm. In particular, homogeneous BM spaces belong to a larger class constructed by Grzegorz Karch to analyze scaling in parabolic equations. We compare Karch's results with those of Kozono and Yamazaki and generalize them by obtaining short-time existence and uniqueness of solutions for arbitrary data with subcritical regularity. We exploit pseudo-differential calculus to extend the analysis to compact, smooth, boundaryless, Riemannian manifolds. BM spaces are defined by means of partitions of unity and coordinate patches, and intrinsically in terms of functions of the Laplace operator.