The Gender Productivity Gap in Croatian Science: Women Are Catching up with Males and Becoming Even Better

How much different genders contribute to citations and whether we see different gender patterns between STEM and non-STEM researchers are questions that have long been studied in academia. Here we analyze the research output in terms of citations collected from the Web of Science of males and females from the largest Croatian university, University of Zagreb. Applying the Mann–Whitney statistical test, for most faculties, we demonstrate no gender difference in research output except for seven faculties, where males are significantly better than females on six faculties. We find that female STEM full professors are significantly more cited than male colleagues, while male non-STEM assistant professors are significantly more cited than their female colleagues. There are ten faculties where females have the larger average citations than their male colleagues and eleven faculties where the most cited researcher is woman. For the most cited researchers, our Zipf plot analyses demonstrate that both genders follow power laws, where the exponent calculated for male researchers is moderately larger than the exponent for females. The exponent for STEM citations is slightly larger than the exponent obtained for non-STEM citations, implying that compared to non-STEM, STEM research output leads to fatter tails and so larger citations inequality than non-STEM.     

Chiral Anthranyl Trifluoromethyl Alcohols: Structures,Oxidative Dearomatization and Chiroptical Properties

Chiral trifluoromethyl alcohol groups were introduced at the hindered ortho positions of 9,10-diphenylanthracenes to investigate their effects on the physical properties and reactivity towards oxidative dearomatization. In such compact structures, the position in different quadrants and the preferred orientation of the −CH(OH)CF₃ groups were determined by the relative and absolute configurations of each stereoisomer, respectively. As a consequence, the stereochemistry governs the organization of the H-bonded molecules in single crystals (homochiral dimers vs ribbon), whereas in chlorinated solvents, they all behave as discrete compounds. Concerning their reactivity, the stereospecific dearomative oxidation of these molecules leads to 9,10-bis-spiro-isobenzofuran-anthracenes, when using organic single-electron transfer oxidants. The chiroptical properties of the alcohols and the corresponding dearomatized products were compared and showed an important modulation of the intensity.     

On the Hyers-Ulam stability of the linear differential equation

We obtain some results on generalized Hyers-Ulam stability of the linear differential equation in a Banach space. As a consequence we improve some known estimates of the difference between the perturbed and the exact solutions.     

Remarks on stability of linear recurrence of higher order

We prove some stability results for linear recurrences with constant coefficients in normed spaces. As a consequence we obtain a complete solution of the problem of the Hyers–Ulam stability for such recurrences.     

Thiete Dioxides as Templates Towards Twisted Scaffolds and Macrocyclic Structures

Thiete dioxide units have been employed as a template for further functionalization through C−H activation strategies. Using simple thiete dioxide building blocks, a new library of axially chiral molecules has been synthesized that owe their stability to electrostatic interactions in the solid state. Similar starting materials were further engaged in the formation of cyclic trimeric structures, opening the pathway to unprecedented macrocyclic ring systems.     

Selective Formation of Indene through the Reaction of Benzyl Radicals with Acetylene

The combustion of fossil fuels forms polycyclic aromatic hydrocarbons (PAHs) composed of five‐ and six‐ membered aromatic rings, such as indene (C₉H₈), which are carcinogenic, mutagenic, and deleterious to the environment. Indene, the simplest PAH with single five‐ and six‐membered rings, has been predicted theoretically to be formed through the reaction of benzyl radicals with acetylene. Benzyl radicals are found in significant concentrations in combustion flames, owing to their highly stable aromatic and resonantly stabilized free‐radical character. We provide compelling experimental evidence that indene is synthesized through the reaction of the benzyl radical (C₇H₇) with acetylene (C₂H₂) under combustion‐like conditions at 600 K. The mechanism involves an initial addition step followed by cyclization and aromatization through atomic hydrogen loss. This reaction was found to form the indene isomer exclusively, which, in conjunction with the high concentrations of benzyl and acetylene in combustion environments, indicates that this pathway is the predominant route to synthesize the prototypical five‐ and six‐membered PAH.     

π-Stacking interactions at the service of [Cu]-bis(oxazoline) recycling

Anthracene- and pyrene-tagged bis(oxazoline) ligands have been prepared and immobilized on charcoal, fullerene, and single-walled carbon nanotubes through π–π interactions. The corresponding copper complexes have been evaluated for their propensity to promote heterogeneous asymmetric Henry and ene reactions. The best results, in terms of activity, selectivity, and stability toward the recycling procedure have been obtained with the pyrene/SWCNT system, as the first example demonstrating the usefulness of such reversible interactions for the asymmetric formation of new C–C bonds.