全文获取类型
收费全文 | 25563篇 |
免费 | 806篇 |
国内免费 | 141篇 |
专业分类
化学 | 16966篇 |
晶体学 | 260篇 |
力学 | 777篇 |
数学 | 2421篇 |
物理学 | 6086篇 |
出版年
2023年 | 165篇 |
2022年 | 462篇 |
2021年 | 612篇 |
2020年 | 464篇 |
2019年 | 475篇 |
2018年 | 427篇 |
2017年 | 392篇 |
2016年 | 744篇 |
2015年 | 641篇 |
2014年 | 900篇 |
2013年 | 1549篇 |
2012年 | 1862篇 |
2011年 | 2066篇 |
2010年 | 1307篇 |
2009年 | 1139篇 |
2008年 | 1726篇 |
2007年 | 1471篇 |
2006年 | 1516篇 |
2005年 | 1296篇 |
2004年 | 1140篇 |
2003年 | 957篇 |
2002年 | 914篇 |
2001年 | 558篇 |
2000年 | 508篇 |
1999年 | 350篇 |
1998年 | 219篇 |
1997年 | 220篇 |
1996年 | 286篇 |
1995年 | 199篇 |
1994年 | 208篇 |
1993年 | 213篇 |
1992年 | 159篇 |
1991年 | 136篇 |
1990年 | 135篇 |
1989年 | 107篇 |
1988年 | 71篇 |
1987年 | 80篇 |
1986年 | 60篇 |
1985年 | 79篇 |
1984年 | 55篇 |
1983年 | 49篇 |
1982年 | 69篇 |
1981年 | 71篇 |
1980年 | 39篇 |
1979年 | 49篇 |
1978年 | 52篇 |
1977年 | 37篇 |
1976年 | 46篇 |
1975年 | 44篇 |
1974年 | 43篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
991.
We study the growth of Fe films on GaAs(1 0 0) at a low temperature, 140 K, by in situ X-ray reflectivity (XRR) using synchrotron radiation. The XRR curves are well modeled by a single Fe layer on GaAs both at the growth temperature and after annealed at the room temperature. We found that the surface became progressively rougher during the growth with the growth exponent, βS = 0.43 ± 0.14. The observed βS is attributed to the restricted interlayer diffusion at the low growth temperature. The change of the interface width during growth was minimal. When the Fe film was annealed to room temperature, the surface smoothed, keeping the interface width almost unchanged. The confinement of the interface derives from that the diffusion of Ga and As proceeds via the inefficient bulk diffusion, and the overlying Fe film is kinetically stabilized. 相似文献
992.
Surface status and size influences of nickel nanoparticles on sulfur compound adsorption 总被引:1,自引:0,他引:1
Metallic nickel nanoparticles were incorporated on mesoporous silica to remove sulfur compounds in diesel selectively. In the first method, nickel nanoparticles were formed on mesoporous silica SBA-15 by impregnation and subsequent reduction of nickel nitrate. The sulfur adsorption capacity was strongly dependent on the nickel loading and the average nickel particle size. In the second method, nickel nanoparticles were synthesized in solution in the presence of a capping agent and then incorporated in mesoporous silica MCF by sonication. Although these particles maintain their sizes on the MCF surface after heat treatment, capping agent remaining on the Ni particle surface might interfere the adsorption of sulfur compounds. 相似文献
993.
We have synthesized cone-like GeO2 structures via thermal heating of Ge powders. We have investigated the effects of substrate temperature on the sample morphology, revealing that cone-shaped structures are preferentially obtained at higher temperature. The cone-shaped structures, which gradually become thinner to form a sharp tip, appear to be a single-crystalline, hexagonal structure of GeO2. Room-temperature photoluminescence measurement revealed two emission peaks, at about 2.78 and 3.04 eV. 相似文献
994.
Seung U. Lee Mun Heum Park Jin Won Kim Hyeun Kyung Jo Won-Jeong Kim 《Applied Surface Science》2007,254(5):1493-1497
Ferroelectric BiFeO3 thin films with Nd-Cr (or Sm-Cr) co-substitution (denoted by BNdFCr and BSmFCr, respectively) were deposited on the Pt(2 0 0)/TiO2/SiO2/Si(1 0 0) substrates by a chemical solution deposition method. X-ray diffraction patterns revealed the formation of BNdFCr and BSmFCr thin films without any secondary phases. The co-substituted BNdFCr (or BSmFCr) thin films, which were annealed at 550 °C for 30 min in N2 atmosphere, exhibited enhanced electrical properties compared to BFO thin films with the remanent polarization (2Pr) and coercive electric field (2Ec) of 196, 188 μC/cm2 and 600, 570 kV/cm with the electric field of 800 kV/cm, respectively. The leakage current densities of BNdFCr and BSmFCr thin films measured at room temperature were approximately three orders of magnitude lower than that of BFO thin film, and the leakage current at room temperature of the thin films exhibited three distinctive conduction behaviors. Furthermore, the values of pulse polarizations [i.e., +(P*-P^) or −(P*-P^)] of BNdFCr and BSmFCr thin films were reasonably unchanged up to 1.4 × 1010 switching cycles. 相似文献
995.
Jing Jin Mark Prochaska Dominic Rochefort David K. Kim Lin Zhuang Francis J. DiSalvo R.B. van Dover Héctor D. Abruña 《Applied Surface Science》2007,254(3):653-661
We used a high-throughput method to screen for direct methanol fuel cell anode electrocatalysts in the Pt-Bi-Pb system. Previous studies showed that PtBi and PtPb (both NiAs structure type) were active electrocatalysts for the oxidation of formic acid, but only PtPb was active in oxidizing methanol. We synthesized thin films with continuous composition spreads of the three elements by magnetron sputtering at deposition temperatures from ambient to 510 °C. A fluorescence method was then used to identify compositions that were active toward methanol oxidation. Only films deposited between temperatures of 160 and 400 °C showed electrocatalytic activity. The areas that were active for methanol oxidation showed predominantly the NiAs structure type according to XRD, with optimal activity for compositions near PtBi0.01Pb0.53. 相似文献
996.
Hwa-Min Kim 《Physics letters. A》2007,371(4):314-317
The dynamic plasma screening and non-Maxwellian effects on elastic electron-ion collisions are investigated in generalized Lorentzian distribution plasmas. The eikonal is employed to obtain the eikonal phase as a function of the spectral index, impact parameter, collision energy, thermal energy, and Debye length. The result shows that the non-Maxwellian effect suppresses the eikonal phase. It is found that the dynamic screening effect significantly enhances the elastic collision cross section for the low thermal energy case. In addition, the eikonal collision cross section is increased by the non-Maxwellian effect. 相似文献
997.
We employ angle-resolved photoemission to characterize the electronic band structure of the Pb "nanowire" array self-assembled on a stepped Si(111) surface. Despite the highly oriented nanowires observed in scanning tunneling microscopy images, we find essentially two-dimensional Fermi contours modulated one dimensionally perpendicular to the wires. This strong two-dimensional and quasi-one-dimensional nature of the band structure explains the stability and anisotropy of the metallic phase down to 4 K as reported recently. A simple tight-binding model with each Si nanoterrace covered by a densely packed Pb overlayer successfully reproduces this modulated band structure and quantifies the electron coupling within the "nanostripes" and the step-edge potential. 相似文献
998.
Lee KI Joo SJ Lee JH Rhie K Kim TS Lee WY Shin KH Lee BC LeClair P Lee JS Park JH 《Physical review letters》2007,98(10):107202
Tunneling magnetoresistance was found to be suppressed with decreasing temperature for magnetic tunnel junctions (MTJs) oxidized under high plasma power. A strong temperature dependence of the junction resistance was observed, along with zero-bias anomalies of dynamic resistance at low temperatures. Resistance shows a logarithmic dependence on temperature, and resistance versus temperature exhibits a scaling behavior. Our experimental data can be explained in a consistent way by the Kondo effect in the MTJs with the Kondo temperature TK=20-30 K. 相似文献
999.
Seong Yong Yoon Hoo San LeeSok Hyun Kong Hoon Sang Oh 《Journal of magnetism and magnetic materials》2007
We studied the magnetic and noise properties with various soft underlayer (SUL) types. For an as-deposited SUL, the results of spectrum, oscilloscope waveform and MFM indicated that the SUL types with IrMn pinning layer have more noise level than that of SUL types without IrMn pinning layer. And, after magnetic filed annealing along radial direction of disk, the exchange bias field increased and the noise level of type B (exchange bias type) decreased. These results reveal that incomplete or partial coupling may be generated at the interface between IrMn and ferromagnetic layer in as-deposited SUL. This incomplete coupling may result in complex or multidomain patterns in ferromagnetic layer. 相似文献
1000.
We show that the phase transition from the decelerating universe to the accelerating universe, which is of relevance to the cosmological coincidence problem, is possible in the semiclassically quantized two-dimensional dilaton gravity by taking into account the noncommutative field variables during the finite time. Initially, the quantum-mechanically induced energy from the noncommutativity among the fields makes the early universe decelerate and subsequently the universe is accelerating because the dilaton driven cosmology becomes dominant later. 相似文献