A New Reagent for the Reduction of N-Arylsulfonylimines

Potassiumselenatedborohydride(KBHZSe3),sodiumselenatedborohydride(NaBHZSe3)werepreparedfirstbyLalancetteetall.However,sincethen,therehavebeenlittlereportabouttheirapplication.Wehaveusedpotassiumselenatedborohydrideinformamidetoreducearomaticnitrocompounds,andsuccessfullyobtainedthecorrespondinganilines2.Inaddition,wehavealsoreportedthereductionofarylsulfonylchloridestothecorrespondingdisulfidesbysodiumselenatedborohydriderefluxinginCH,CN'.Fromourresearchwork,KBHZSe3andNaBHZSe3werefou…     

环戊叉基环戊酮的烷基化反应研究

研究了环戊叉基环戊酮与不同类型烷化剂的反应规律；讨论了不同催化剂对烷基化反应的催化性能，发现ＮａＮＨ２和ＮａＨ具有较好的催化作用；讨论了烷基化产物的结构，证实了烷基化反应发生在羰基的α双键碳原子上。     

电感耦合等离子体原子发射光谱法及离子选择电极法测定荧光级氧化钇中痕量铈的研究

文章描述了荧光级氧化钇中痕量稀土铈的测定方法,在溴酸钾存在下,5摩尔/升HNO_3介质中,以P507萃取微量铈,然后有机相用硝酸、过氧化氢反萃取、再将水相浓缩定容,然后以电感耦合等离子体原子发射光谱法分析。同时用铈的离子选择电极以二次标准加入法作第二种手段分析。样品溶液以乙醇预去溶方式引入等离子体,测定下限为2微克/克,方法简单、快速、准确。离子选择电极法测定铈离子下限1×10～(-5)摩尔/升,回收率为94-101%,方法简单,结果满意、价格便宜。     

包络半群与拓扑动力学中的接近关系

运用包络半群的理论，对接近关系中一个重要定理给出了一个简单证明．作为这一定理的应用，我们得到接近关系可乘性的一个结果．并且对另一种接近关系，也得到一个结果．这两个定理减弱了Ｃｌａｙ在这一领域中两个定理的条件．     

The characteristic junction parameter of a semiconductor laser and its relation with reliability

We discuss the factors which affect the characteristic junction parameter m, which is obtained from the intercept of the / (dV/dl) vs / characteristic. The relation between m and the reliability of InGaAsP/InP BH laser devices is also discussed.     

Synthesis and mesomorphic properties of 4-n-alkoxy 4'-[4-((4-n-alkoxy-2,3,5,6-tetrafluoro-phenyl)ethynyl)benzyloxy]benzoates

Two series of tolane-based liquid crystals have been prepared that incorporate a tetrafluorophenyl moiety and a flexible methyl ether bond into the core structure. The mesomorphic properties have been studied by polarizing microscopic textural observation and DSC measurements. By comparison with their non-fluorinated analogues, the effect of tetrafluorophenylene on mesomorphic behaviour has been discussed in this paper.     

流动注射-电感耦合等离子体发射光谱法测定天然水中的钙和镁

本文采用流动注射－电感耦合等离子体发现光谱联用技术测定了天然水中的钙、镁元素。考察了试液的雾化和曝光时间及载气压力等因素对分析信号的影响。通过与气动连续进样的对比，测出了钙、镁在流动注射进样下的分散系数。本法在测定钙、镁含量高的水性时，不需对试样进行稀释处理。对五个水样中钙、镁的分析结果与EDTA络合滴定法相吻合。     

挠性陀螺捷联系统场地快速标定

本文给出了捷联式惯性导航系统一种简单实用的场地标定方法。在系统中，对挠性陀螺仪采用特殊安装，把组合件旋转１８０°，用两位置数据测出陀螺的标度系数、常值漂移、加速度计零位和系统真方位。在标定过程中不需要对惯性组合件做水平调整。