全文获取类型
收费全文 | 351篇 |
免费 | 19篇 |
国内免费 | 2篇 |
专业分类
化学 | 203篇 |
晶体学 | 8篇 |
力学 | 9篇 |
数学 | 73篇 |
物理学 | 79篇 |
出版年
2023年 | 4篇 |
2022年 | 9篇 |
2021年 | 9篇 |
2020年 | 11篇 |
2019年 | 19篇 |
2018年 | 10篇 |
2017年 | 16篇 |
2016年 | 24篇 |
2015年 | 18篇 |
2014年 | 17篇 |
2013年 | 36篇 |
2012年 | 32篇 |
2011年 | 37篇 |
2010年 | 20篇 |
2009年 | 19篇 |
2008年 | 24篇 |
2007年 | 16篇 |
2006年 | 18篇 |
2005年 | 7篇 |
2004年 | 9篇 |
2003年 | 3篇 |
2002年 | 4篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1998年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1982年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有372条查询结果,搜索用时 31 毫秒
81.
82.
83.
The essential oils (EOs) obtained by solvent-free microwave extraction (SFME) and hydrodistillation (HD) from endemic Origanum husnucanbaseri H. Duman, Aytac & A. Duran were investigated using the gas chromatography-mass spectrometry system. The main constituents of both oils obtained from SFME and HD from O. husnucanbaseri are borneol (15.2-12.8%), α-terpineol (12.3-10.8%) and trans-sabinene hydrate (11.8-9.92%). The EO obtained from SFME contained substantially higher amounts of oxygenated compounds and lower amounts of monoterpenes than that from HD. The antibacterial activities of the EOs from SFME and HD were evaluated by the disc diffusion method against six bacterial strains. The EO extracted by SFME was more effective than the EO extracted by HD against the tested bacteria, except for Klebsiella pneumoniae American type culture collection (ATCC) 13883. Streptococcus pyogenes ATCC 19615 and Staphylococcus aureus ATCC 25923 in particular were more sensitive against the EO extracted by SFME. 相似文献
84.
We report a detailed analysis of the potential energy surface of N-acetyl-l-tryptophan-N-methylamide, (NATMA) both in the gas phase and in solution. The minima are identified using the density-functional-theory (DFT) with the 6-31g(d) basis set. The full potential energy surface in terms of torsional angles is spanned starting from various initial configurations. We were able to locate 77 distinct L-minima. The calculated energy maps correspond to the intrinsic conformational propensities of the individual NATMA molecule. We show that these conformations are essentially similar to the conformations of tryptophan in native proteins. For this reason, we compare the results of DFT calculations in the gas and solution phases with native state conformations of tryptophan obtained from a protein library. In native proteins, tryptophan conformations have strong preferences for the beta sheet, right-handed helix, tight turn, and bridge structures. The conformations calculated by DFT, the solution-phase results in particular, for the single tryptophan residue are in agreement with native state values obtained from the Protein Data Bank. 相似文献
85.
Fraley AW Pons B Dalkara D Nullans G Behr JP Zuber G 《Journal of the American Chemical Society》2006,128(33):10763-10771
Oligonucleotide delivery is a crucial issue for therapeutical purposes and is often addressed by conjugation to short cationic peptides although with controversial results. To further examine this mechanism, a 15-mer anionic oligonucleotide was conjugated to a cationic peptide in order to obtain a diblock compound with an overall positive charge with aggregation properties. These microaggregates were efficiently internalized in cells via the expeditious pathway used by commercial gene delivery systems. Moreover, stability of the duplex formed with the complementary sequence increased without inhibiting oligonucleotide enzyme recognition as shown by the properties of the conjugate to prime chain elongation by Taq DNA polymerase in a linear amplification/sequencing process. 相似文献
86.
87.
A general model with multiple input flows (classes) and several flexible multi-server pools is considered. We propose a robust, generic scheme for routing new arrivals, which optimally balances server pools’ loads, without the knowledge of the flow input rates and without solving any optimization problem. The scheme is based on Shadow routing in a virtual queueing system. We study the behavior of our scheme in the Halfin–Whitt (or, QED) asymptotic regime, when server pool sizes and the input rates are scaled up simultaneously by a factor r growing to infinity, while keeping the system load within \(O(\sqrt{r}\,)\) of its capacity.The main results are as follows. (i) We show that, in general, a system in a stationary regime has at least \(O(\sqrt{r}\,)\) average queue lengths, even if the so called null-controllability (Atar et al., Ann. Appl. Probab. 16, 1764–1804, 2006) on a finite time interval is possible; strategies achieving this \(O(\sqrt{r}\,)\) growth rate we call order-optimal. (ii) We show that some natural algorithms, such as MaxWeight, that guarantee stability, are not order-optimal. (iii) Under the complete resource pooling condition, we prove the diffusion limit of the arrival processes into server pools, under the Shadow routing. (We conjecture that result (iii) leads to order-optimality of the Shadow routing algorithm; a formal proof of this fact is an important subject of future work.) Simulation results demonstrate good performance and robustness of our scheme. 相似文献
88.
Yusuf Gurefe Yusuf Pandir Tolga Akturk Hasan Bulut 《Journal of Applied Analysis & Computation》2017,7(1):372-391
In this work, we have constructed various types of soliton solutions of the generalized regularized long wave and generalized nonlinear Klein-Gordon equations by the using of the extended trial equation method. Some of the obtained exact traveling wave solutions to these nonlinear problems are the rational function, 1-soliton, singular, the elliptic integral functions $F, E, \Pi$ and the Jacobi elliptic function sn solutions. Also, all of the solutions are compared with the exact solutions in literature, and it is seen that some of the solutions computed in this paper are new wave solutions. 相似文献
89.
90.