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971.
After carefull analysis in a turbulent zero-pressure gradient flow, various simple algebraic turbulence models were applied to the almost separated flow on the upperside of an airfoil at incidence. The Johnson-King and Horton non-equilibrium (or rate equation) models give clearly improved results. 相似文献
972.
This Review discusses the synthesis and characterization by our Group of new antibiotics belonging to the class of penicillins, cephalosporins and rifamycins with ferrocenyl and 1, 1′-ferrocenilene residues in the molecule. As reactants for 6-aminopenicillanic acid (6-APA) and 7-aminocephalosporanic acid (7-ACA) the following were used: 1, 1-bis(chlorocarbonyl)ferrocene, ferrocenyl sulfochloride, 1, 1′-ferrocenylenedisulfochloride and thioglycolic acids S-modified with ferrocene. In the synthesis of rifamycins, the hydrazides of the thioglycolic acids, S-modified with ferrocene, were employed as nucleophilic agents. The synthesized intermediates were characterized by elemental analysis, TLC, IR, UV and 1H NMR spectra. The characterization of new antibiotics was made by TLC, IR and UV spectral analysis. Biological activity was tested on Gram-negative and Gram-positive bacteria. Good activity is reported towards Gram-positive bacteria in the case of derivatives containing residues of thioglycolic acid S-modified with ferrocene, the antibacterial activity being similar to that of amoxicillin, carbenicillin and cephalothin. All compounds are inactive towards Gram-negative bacteria. 相似文献
973.
We study the stochastic dynamics of deposition-evaporation cooperative processes of dimers, trimers, etc., in two- and higher-dimensional lattices. The dimer system in bipartite lattices allows for an exact solution of dynamic correlations and scaling functions by means of a quantum spin equivalence. Autocorrelations exhibit a diffusive asymptotic kinetics and crossovers of different dynamic regimes in highly anisotropic lattices. Monte Carlo simulations combined with finite-size scaling arguments support the validity of the diffusive picture in more general situations. Steady-state coverages and diffusion constants are obtained using mean-field approaches, spin wave calculations, and random walk analyses in nearly jammed configurations. 相似文献
974.
A number of biphenyl, terphenyl analogues and ethynes which contain a pyrazine ring have been made and their liquid crystal transition temperatures, together with examples of birefringence measurements, are reported. All the 2,5-disubstituted pyrazine systems are liquid crystalline showing high birefringence values for the biphenyl and terphenyl analogues, whereas the 1,5-disubstituted systems are not liquid crystalline. The pyrazine ethyne systems exhibit very high birefringence values. X-ray diffraction has been used to identify the liquid crystal phases of 2-n-nonyloxy-5-(4'-propylbiphenyl-4-yl)pyrazine. 相似文献
975.
V. D. Fedotov N. P. Obuchov R. A. Zadikhanov J. Spěváček J. Straka 《Applied magnetic resonance》1993,4(4):491-511
The combined analysis of1H and13C NMR relaxation data in solid lysozyme and some typical homopolypeptides was carried out by using “model-free” approach. Three types of relaxation transitions (γ’, γ and β) were revealed in the temperature range investigated. The microdynamical parameters of these motions were determined. From the comparison of these parameters with those of selected synthetic polymers it follows that the molecular motions in proteins and synthetic polymers are of the same nature. All these motions show pronounced anisotropic character. In the investigated temperature range no molecular motions corresponding to α-relaxation (liquid-like) transition were revealed. The hydration effects on parameters of the motions in proteins were considered. The most pronounced effect takes place for β-transition. The effect of Brownian rotation of protein molecule in solution on measured correlation function of local motions was also discussed. 相似文献
976.
D. A. Rakhimov M. Kh. Malikova A. A. Vakhabov I. O. Ruziev T. R. Abdurakhmanov 《Chemistry of Natural Compounds》1995,31(2):260-261
Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, fax (3712) 89 14 75. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 313–314, March–April, 1995. Original article submitted November 7, 1994. 相似文献
977.
Ulrich D. Holzbaur 《Annals of Operations Research》1991,32(1):35-50
Starting from fuzzy real numbers with an arbitrary lattice of belief and following the extension principle, we develop concepts of fuzzy probabilities, transition probabilities and random variables and of their combinations, and show that these concepts are consistent. We derive some results on fuzzy real numbers, on the expectation of fuzzy random variables and on fuzzy stochastic processes. To sketch the range of applications of fuzzy stochastics, we give two examples that show how real-world problems may be modeled by means of fuzzy probabilities and that give small numerical examples. Moreover, we give a brief outlook for a possible expansion of our theory to fuzzy Markovian decision processes by means of a partial order on the set of all fuzzy real numbers. 相似文献
978.
The many facets of linear programming 总被引:1,自引:0,他引:1
Michael J. Todd 《Mathematical Programming》2002,91(3):417-436
We examine the history of linear programming from computational, geometric, and complexity points of view, looking at simplex,
ellipsoid, interior-point, and other methods.
Received: June 22, 2000 / Accepted: April 4, 2001?Published online October 2, 2001 相似文献
979.
D. Kast A. Jungclaus K.P. Lieb M. Górska G. de Angelis P.G. Bizzeti A. Dewald C. Fahlander H. Grawe R. Peusquens M. De Poli H. Tiesler 《The European Physical Journal A - Hadrons and Nuclei》1998,3(2):115-128
In the neutron deficient isotopes 104,105In lifetimes of high spin states in the range from 0.5 ps to 600 ps have been measured in a coincidence recoil distance Doppler
shift (RDDS) experiment. By combining the Doppler shift attenuation (DSA) and RDDS methods at few μm flight distances, the
problem of delayed feeding has been avoided and very short lifetimes in the range 0.5–0.8 ps have been determined. Shell model
calculations with strong restrictions for the neutron orbitals reveal good agreement with experimental level energies and
still fair agreement for most measured B(M1) and B(E2) values.
Received: 30 June 1998 相似文献
980.