FTIR-ATR技术考察TiO2膜对油酸的光催化氧化性能

采用Sol-Gel和PVD法在玻璃、陶瓷、铝片表面制备出TiO2膜,直接将食用油中的主成分油酸用溶剂稀释后均匀涂在膜表面,采用FTIR-ATR技术实现了对膜样品光催化自清洁性能的快速准确评价,并通过测量水的接触角评价了膜的亲水性。结果表明,Sol-Gel法和PVD法制备的TiO2/玻璃膜都具有较好的光致亲水性和光催化降解油酸性能,两者的亲水性没有明显差别,但前者的光催化活性稍优于后者。比较Sol-Gel法制备的TiO2/玻璃、TiO2/陶瓷和TiO2/铝片膜对油酸的光催化降解性能发现,光照3·5h后3个样品的降解率分别为92%,85%和46%,表明基底材料性质对TiO2膜的光催化活性有明显影响,镀在非导电性玻璃和陶瓷表面的TiO2膜比镀在导电性金属铝表面的TiO2膜对油酸有更高的光催化降解能力。     

常压MOCVD生长Ga2O3薄膜及其分析

以去离子水(H₂O)和三甲基镓(TMGa)为源材料,用常压MOCVD方法在蓝宝石(0001)面上生长出β-Ga₂O₃薄膜.用原子力显微镜(AFM)、X射线衍射(XRD)以及二次离子质谱(SIMS)实验表征Ga₂O₃外延膜的质量.在X射线衍射谱中有一个强的Ga₂O₃(102)面衍射峰,其半峰全宽(FWHM)为0.25°,表明该Ga₂O₃外延膜是(102)择优取向.在二次离子质谱中除了C、H、O和Ga原子外,没有观测到其他原子.     

等离子体断路开关和电感负载间的功率流特性

利用PIC (particle-in-cell) 方法,结合实验装置的几何结构和实验结果,采用动态开关模型,对微秒等离子体断路开关和电感负载间的功率流特性进行了研究。模拟得到了与实验结果符合较好的开关电压和负载电流波形,并给出了开关下游出现的稀薄等离子体的密度(约1012 cm-3)和速度(约1 cm/ns), 同时也得到了开关下游的空间电流分布。模拟结果表明,开关下游的结构应避免阻抗突变以减少电流损失,同时提高开关阻抗可有利于提高负载上的最大功率。     

ICP-AES测定氟化稀土中铝

采用高氯酸、盐酸分解样品,草酸将稀土沉淀分离,用ICP-AES快速测定氟化稀土中的铝,加标回收率达98%—102%,相对标准偏差＆lt;2.0%,此方法分析简单快速、结果准确可靠。     

A Diode-Pumped 1617 nm Single Longitudinal Mode Er：YAG Laser with Intra-Cavity Etalons

We demonstrate the continuous wave p-polarized single longitudinal mode （SLM） operation of an Er：YAG laser at 1617.6nm pumped by a diode-laser with three inserted Fabry-Perot （FP） etalons at room temperature. The Brewster angle inserted FP is applied to obtain the p-polarized laser. For free running, the maximum output power is 570 m W with a pump power of 12.5 W. An incident pump power of 12.5 W is used to generate the maximum p-polarized single longitudinal mode output power of 78.5 m W, corresponding to a slope efficiency of 1.6% and an optical-to-optical efficiency of 0.61%. The beam quality M2 is measured to be 1.15 at the highest SLM output power. This stable polarized SLM oscillation is encouraging due to its application for an injection-locked system used as a master laser.     

Simulation of Dual Frequency Capacitive Sheath over a Concave Electrode in Low Pressure

A self-consistent two-dimensional （2D） collisionless fluid model is developed to simulate the characteristics of a dual frequency capacitive sheath over an electrode with a cylindrical hole. The model consists of 2D time-dependent fluid equations coupled with Poisson＇s equation, in which the low-frequency （LF） and high-frequency current sources are applied to an electrode. Thus, the so-called equivalent circuit model coupling with the fluid equations will be able to self-consistently determine the relationship between the instantaneous voltage on the powered electrode and the sheath thickness. The time-averaged potential, electric field, ion density in the sheath and ion energy distributions at the bottom of the hole are calculated and compared for different LF frequencies. The results show that the LF frequency is crucial for determining the sheath structure. The existence of the cylindrical hole on the electrode obviously affects the sheath profile in the parallel to the electrode and makes the sheath profile tend to adapt the contours of the electrode, which is the plasma molding effect.     

Study of Ternary Fission Produced in 12C Bombarding 209Bi Target with Medium Energy

Alternative layers of target material,which were prepared by evaporating ²⁰⁹Bi on the surface of mica foils,were irradiated with ¹²C ions.Ternary fission events in which three fragments of comparable mass were produced in 2525－47.5MeV/A ¹²C+²⁰⁹Bi reaction,were recorded by the mica detectors with 2π geometry.The observed probability ratio of ternary fission relative to binary fission in 2π geometry was modified to 4π geometry spatial in terms of the Monte Carlo method.The values of ratioes increase with the bombarding energy,and are compared with the calculation result of the cascade fission model.     

HPLC测定辛芩喷雾剂中的黄芩苷

建立HPLC测定辛芩喷雾剂中黄芩苷含量的方法.采用Hypersil C18 (4.6mm×150mm,5μm)为色谱柱,流动相为甲醇∶水∶磷酸(47∶53∶0.2,V/V/V),流速为1.0mL/min,紫外检测波长为280nm.在6.0-300μg·mL-1范围内线性关系良好(r=0.9993).加标回收率为97.02％,重复性实验的RSD为1.08％(n=3).本法操作简便、快速准确,重现性好,可作为该制剂的含量测定方法.     

混流叶轮S2流面的展向掺混模型与应用

本文在S2流面流动方程中加入了"展向掺混"模型,模拟叶栅端部二次流动、湍流扩散等对局部低动量流体的展向输运效应。方法用于混流叶轮内流动分析,结果表明:由于混流叶轮子午流道的大曲率,叶轮端部的低动量流体在展向的扩散远大于轴流叶栅,叶轮出口的展向均匀化趋势更加明显。合理的选择掺混扩散系数,可以获得与三维N-S计算的周向平均值类似的子午面分布,从而提高了S2流面分析和设计的可靠性。     

Electromagnetic Transition Rates and Deformation Feature in 130Ce

Lifetimes of the excited states in light rare-earth nucleus ¹³⁰Ce have been measured using heavy ion reaction ¹¹⁶Sn(¹⁶O,2n)¹³⁰Ce at beam energy of 73MeV through analyzing the Doppler-broadened line shapes. The reduced transition probabilities B(E2) are extracted from these measurements. The experimental results show that the previously reported anomalously high B(E2) value has not been observed in the present work. The transition quadrupole moment for the yrast band varies with spin and corresponds to a triaxial deformation with γ≈7°.