排序方式: 共有92条查询结果,搜索用时 15 毫秒
91.
Dorel Cri?an Nicolae Dr?gan M?lina R?ileanu Mihai Anastasescu Diana Mardare Virgil Marinescu 《Journal of Physics and Chemistry of Solids》2008,69(10):2548-2554
Sol-gel nanostructured titania materials have been reported to have applications in areas ranging from optics via solar energy to gas sensors. In order to enhance the photocatalytic activity, there are many studies regarding the doping of titanium dioxide (TiO2) material with either non-metals (S, C, N, P) or metals (Ag, Pt, Nd, Fe). The present work has studied some un-doped and Pd-doped sol-gel TiO2 materials (films and gels), with various surface morphologies and structures, obtained by simultaneous gelation of both precursors Ti(OEt)4 and Pd(acac)2. Their structural evaluation and crystallization behavior with thermal treatment were followed by DTA/TG analysis, infrared (IR) spectroscopy, Fourier transform infrared (FTIR), spectroellipsometry (SE), X-ray diffraction (XRD) and atomic force microscope (AFM). The influence of Pd on TiO2 crystallization for both supported and un-supported materials was studied (lattice parameters, crystallite sizes, internal microstrains). The changes in the optical properties of the TiO2-based vitreous materials were correlated with the changes of the structure. The hydrophilic properties of the films were also connected with their structure, composition and surface morphology. 相似文献
92.
The electrical properties of n-type titanium dioxide thin films deposited by magnetron-sputtering method have been investigated by temperature-dependent conductivity. We observed that the temperature dependence of the electrical conductivity of titanium dioxide films exhibits a crossover from T?1/4 to T?1/2 dependence in the temperature range between 80 and 110 K. Characteristic parameters describing conductivity, such as the characteristic temperature (T0), hopping distance (Rhop), average hopping energy (Δhop), Coulomb gap (ΔC), localization length (ξ) and density of states (N(EF)), were determined, and their values were discussed within the models describing conductivity in TiO2 thin films. 相似文献