Thermal and Structural Investigation of The Reaction Between 1,2-propanediol and Ni(NO3)2⋅6H2O

The authors present the results of an investigation concerning the reaction between 1,2-propanediol and Ni(NO₃)₂6H₂O, leading to a complex containing as ligand the lactate anion (L), suggesting that the oxidation of 1,2-propanediol occurs at the primary hydroxyl group. The obtained solid homopolynuclear combination, [Ni₂(OH)₂L₂(H₂O)₂0.5H₂O]_n, has been investigated by thermal analysis, electron and IR spectroscopy,and magnetic methods. Nickel oxide obtained by thermolysis of this complex compound was characterized by IR, X-ray spectroscopy and elemental analysis. All the investigations lead to the conclusion that the complex compound is characterized by pseudooctahedral configuration of the nickel(II) ion. Thermal analysis of the homopolynuclear complex compound enabled to prove the thermal decomposition mechanism.This revised version was published online in November 2005 with corrections to the Cover Date.     

Development of membrane extraction with a sorbent interface-micro gas chromatography system for field analysis

The commercially available portable gas chromatographs have a rather limited scope of applications, typically allowing analysis of gaseous samples only, and having relatively poor sensitivity. Combination of those instruments with modern sampling/sample preparation techniques can remedy these problems. A Chrompack micro-GC system equipped with a thermal conductivity detector has been coupled to membrane extraction with a sorbent interface (MESI). The sorbent trap has replaced the GC injector. The design of the trap was also modified in order to enhance the preconcentration of analytes. The use of a thin flat sheet membrane reduces the response time, and decreases the memory effect of the system. Rapid separation times were achieved, and the sensitivity was significantly improved. MESI enables semi-continuous monitoring of both gaseous and aqueous samples, owing to the selectivity of the membrane material. The system does not use moving parts, therefore being reliable. The sensitivity of the micro-GC system was increased by a factor of more than 100 by the addition of the MESI system, even with a preconcentration time as short as 1 min. Chloroform, having a concentration lower than 1 ppb, was detected in tap water. A cup system was used to allow headspace sampling of volatile organic compounds from aqueous matrices, keeping the membrane away from interfering species that could be present in water, and improving the mass transfer. A linear calibration line was obtained, and the estimated limit of detection was 60 ppt. This represents a great improvement for the sensitivity of the micro-GC system.     

Porous silicon surfaces: a candidate substrate for reverse protein arrays in cancer biomarker detection

This paper introduces a new substrate for reverse-phase protein microarray applications based on macroporous silicon. A key feature of the microarray substrate is the vastly surface enlarging properties of the porous silicon, which simultaneously offers highly confined microarray spots. The proof of principle of the reverse array concept was demonstrated in the detection of different levels of cyclin E, a possible cancer biomarker candidate which regulates G1-S transition and correlates with poor prognosis in different types of human cancers. The substrate properties were studied performing analysis of total cyclin E expression in human colon cancer cell lines Hct116 and SW480. The absence of unspecific binding and good microarray quality was demonstrated. In order to verify the performance of the 3-D textured macroporous surface for complex biological samples, lysates of the human tissue spiked to different levels with cell extract overproducing cyclin E (Hct116) were arrayed on the chip surface. The samples were spotted in a noncontact mode in 100 pL droplets with spots sizes ranged between 50 and 70 mum and spot-to-spot center distances 100 mum, allowing microarray spot densities up to 14 000 spots per cm(2). The different sample types of increasing complexities did not have any impact on the spot intensities recorded and the protein spots showed good homogeneity and reproducibility over the recorded microarrays. The data demonstrate the potential use of macroporous silicon as a substrate for quantitative determination of a cancer biomarker cyclin E in tissue lysates.     

Scheduling problems in transportation networks of line topology

In this paper we consider online scheduling problems for linear topology under various objective functions: minimizing the maximum completion time, minimizing the largest delay, and minimizing the sum of completion times. We give optimal solutions for uni-directional version of the problem for each of the objectives and show that for the two-directional versions of each problem, no online algorithm can deterministically achieve the optimal solution for any of the considered objective functions. We also propose 2-approximation on-line algorithms for the MinMakespan and the MinSum minimization objectives. We also prove that no online algorithm can deterministically achieve the optimal solution for any of the considered objective functions for the weighted case of uni-directional scenarios.     

The Euclidean Bottleneck Steiner Path Problem and Other Applications of (α,β)-Pair Decomposition

We consider a geometric optimization problem that arises in network design. Given a set P of n points in the plane, source and destination points s, t∈P, and an integer k>0, one has to locate k Steiner points, such that the length of the longest edge of a bottleneck path between s and t is minimized. In this paper, we present an O(nlog² n)-time algorithm that computes an optimal solution, for any constant k. This problem was previously studied by Hou et al. (in Wireless Networks 16, 1033–1043, 2010), who gave an O(n ²logn)-time algorithm. We also study the dual version of the problem, where a value λ>0 is given (instead of k), and the goal is to locate as few Steiner points as possible, so that the length of the longest edge of a bottleneck path between s and t is at most λ. Our algorithms are based on two new geometric structures that we develop—an (α,β)-pair decomposition of P and a floor (1+ε)-spanner of P. For real numbers β>α>0, an (α,β)-pair decomposition of P is a collection $\mathcal{W}=\{(A_{1},B_{1}),\ldots,(A_{m},B_{m})\}$ of pairs of subsets of P, satisfying the following: (i) For each pair $(A_{i},B_{i}) \in\mathcal {W}$ , both minimum enclosing circles of A _i and B _i have a radius at most α, and (ii) for any p, q∈P, such that |pq|≤β, there exists a single pair $(A_{i},B_{i}) \in\mathcal{W}$ , such that p∈A _i and q∈B _i , or vice versa. We construct (a compact representation of) an (α,β)-pair decomposition of P in time O((β/α)³ nlogn). In some applications, a simpler (though weaker) grid-based version of an (α,β)-pair decomposition of P is sufficient. We call this version a weak (α,β)-pair decomposition of P. For ε>0, a floor (1+ε)-spanner of P is a (1+ε)-spanner of the complete graph over P with weight function w(p,q)=?|pq|?. We construct such a spanner with O(n/ε ²) edges in time O((1/ε ²)nlog² n), even though w is not a metric. Finally, we present two additional applications of an (α,β)-pair decomposition of P. In the first, we construct a strong spanner of the unit disk graph of P, with the additional property that the spanning paths also approximate the number of substantial hops, i.e., hops of length greater than a given threshold. In the second application, we present an O((1/ε ²)nlogn)-time algorithm for computing a one-sided approximation for distance selection (i.e., given k, $1 \le k \le{n \choose2}$ , find the k’th smallest Euclidean distance induced by P), significantly improving the running time of the algorithm of Bespamyatnikh and Segal.     

Dynamic evanescent phonon coupling across the La(1-x)Sr(x)MnO3/SrTiO3 interface

The transport and magnetic properties of correlated La0.53Sr0.47MnO3 ultrathin films, grown epitaxially on SrTiO3, show a sharp cusp at the structural transition temperature of the substrate. Using a combination of experiment and first principles theory we show that the cusp is a result of evanescent cross-interface coupling between the charge carriers in the film and a soft phonon mode in the SrTiO3, mediated through linked oxygen octahedral motions. The amplitude of the mode diverges at the transition temperature, and phonons are launched into the first few atomic layers of the film, affecting its electronic state.     

Nonisothermal decomposition kinetics of [CoC<Subscript>2</Subscript>O<Subscript>4</Subscript>·2.5H<Subscript>2</Subscript>O]<Subscript><Emphasis Type="Italic">n</Emphasis></Subscript>

The authors present their results concerning the decomposition in air of the homopolynuclear coordination compound [CoC₂O₄·2.5H₂O] _n . In the temperature range 20–300 °C, the heating curves TG, DTG and DTA allowed to evidence three decomposition steps. The kinetic analysis was performed on the second step which proved to be the only workable one. The application of nonlinear regression procedure shows that this is a complex process consisting in three successive steps. The checking of the mechanism and corresponding kinetic parameters for quasi-isothermal data (T = 150 °C) shows that the obtained results could be used for prediction of the thermal behaviour of the investigated compound in both isothermal and non-isothermal conditions.     

Single mode heat rectifier: controlling energy flow between electronic conductors

We study heat transfer between conductors, mediated by the excitation of a monomodal harmonic oscillator. Using a simple model, we show that the onset of rectification in the system is directly related to the nonlinearity of the electron gas dispersion relation. When the metals have a strictly linear dispersion relation, a Landauer-type expression for the thermal current holds, symmetric with respect to the temperature difference. Rectification becomes prominent when deviations from linear dispersion exist, and the fermionic model cannot be mapped into a harmonic bosonized representation. The effects described here are relevant for understanding radiative heat transfer and vibrational energy flow in electrically insulating molecular junctions.