Synthesis and Characterization of Iron Nanowires

The iron nanowires can be fabricated via the process in which sodium borohydride reduces iron salts in external magnetic field. The iron nanowires are found to be covered by passivated layers of iron oxide which prevent the oxidation of iron nanowires. In this process, the boron will include in iron nanowires. The average length and diameter of iron nanowires is around 1.2 micrometers and 60 nanometers, respectively. According to ICP results, the contents of B and Fe are about 1.98 wt% and 87.04 wt%, respectively, in iron nanowires. A wide variety of equipment is used to investigate the morphological, microchemical, and structural characteristics of the newly synthesized iron nanowires ––– e.g., XRD, FE‐SEM, HR‐TEM, VSM and XANES. XANES analysis indicates the boron in iron nanowires exists in the form of B₂O₃. The saturation magnetization and the coercive force of iron nanowires are 157.93 emu/g and 9.74 Oe, respectively. In‐situ images of synthesized iron nanowires during reduction process in magnetic field are observed by NSRRC transmission X‐ray microscope. Thus, this study develop a novel process to produce iron nanowires with large quantitates and can control its length and diameter by various the concentration of precursors for various applications.     

Period-doubling route to chaos for a swirling flow in an open cylindrical container with a rotating disk

Conclusion The period-doubling route to chaos for a swirling vortex flow in an open cylindrical container, at an aspect ratio of 2, driven by a rotating bottom disk was recognized by using laser-Doppler velocimetry. The onset of periodic motion for the flow was found when Re was in the range between 1850 and 1900. The flow was subharmonically bifurcated into a double-period motion when Re was about 2150. When the Reynolds number was in the range from 2300 to 2400, the flow bifurcated again through the period-doubling mode. When the Reynolds number was further increased, the flow eventually showed chaotic motion. The existence of a free surface promotes the onset of periodicity, and the difference of the critical Reynolds number with and without a free surface was estimated to be about 600.This work was supported by the National Science Council of the Republic of China under grant No. NSC-82-0410-E-002-191     

Aryne‐Induced Novel Tandem 1,2‐Addition/(3+2) Cycloaddition to Generate Imidazolidines and Pyrrolidines

A new “single‐flask” method was developed for the synthesis of imidazolidines and pyrrolidines with high stereoselectivity. First, a Schiff base was arylated with an aryne. Second, an intramolecular proton transfer took place from the methylene position to the anionic aryne ring. Third, the resultant ylide reacted with a second equivalent of the same Schiff base in situ or an electron‐deficient alkene through a (3+2) cycloaddition. These sequential tandem 1,2‐addition/(3+2) cycloaddition reactions led to the desired heterocycles in 63–88 % yields.