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151.
A novel silicone and phosphate modified acrylate (DGTH) was synthesized and characterized by 1H NMR and FTIR. It was found that DGTH could be cured both by UV radiation and moisture mode with FTIR. The flammability and thermal behavior of the cured film were studied by the limited oxygen index (LOI), thermogravimetric analysis (TG) and real time Fourier transform infrared (RT-FTIR). The LOI value of the cured film is 48 and the TG data shows that the cured film has three characteristic degradation temperature regions, attributing to the decomposition of phosphate and polyurethane to alcohols and isocyanates, thermal pyrolysis of alkyl chains, and decomposition of unstable structures in char, respectively. The RT-FTIR data implies that the degraded products of phosphate form poly(phosphoric acid) further catalyse the breakage of carbonyl groups to form an intumescent char, preventing the samples from further burning. 相似文献
152.
153.
主客观相结合眼波面像差分析系统 总被引:1,自引:0,他引:1
利用Hartmann-Shack波面传感器对眼出瞳位置的波面像差进行测量,根据所测像差控制可变形镜对像差进行实时补偿.眼像差以Zernike多项式表示,通过对可变形镜的精确控制,可在光路中生成特定模式和幅值的像差.因此,被测者根据视觉的主观感觉,调节视标像差,直至获得最满意的视觉效果.该系统采用移动三棱镜和柱镜的方法对离焦和散光进行预补偿,弥补了波面传感器测量范围和可变形镜矫正范围受限制的缺点.该系统把快速、客观的测量及补偿和主观调整相结合,更加符合人眼工作的特性,可用于在人眼像差与视觉分辩的基础和临床研究. 相似文献
154.
建立了X射线荧光光谱法测定绿泥石中镁、铝、硅、磷、钾、钙、钛、铁元素含量的快速分析方法。以标准物质及标准物质与基准试剂氧化镁、氧化钙人工混合配制标样的方法建立标准工作曲线,重点讨论了熔剂和脱模剂的选取。最佳熔样条件:采用8.0g四硼酸锂和偏硼酸锂混合熔剂(质量比67: 33)+0.8g样品并添加溴化锂作为脱模剂,熔样温度1100℃,熔样时间10min。该方法相对标准偏差(n=12)均小于5.57%,绿泥石样品测定结果与化学法一致,硅酸盐标准物质测定结果均满足不确定度要求。 相似文献
155.
Miaomiao Chi Kunming Qin Lei Cao Min Zhang Yingying Su Xun Gao 《Molecules (Basel, Switzerland)》2022,27(10)
Coronary heart disease (CHD), which has developed into one of the major diseases, was reported to be treated by the target of peroxisome proliferators-activate receptor γ (PPAR-γ). As a natural medicine long used in the treatment of CHD, there are few studies on how to screen the target active compounds with high specific activity from Choerospondias axillaris. To advance the pace of research on target-specific active compounds in natural medicines, we have combined magnetic ligand fishing and functionalized nano-microspheres to investigate the active ingredients of PPAR-γ targets in Choerospondias axillaris. The PPAR-γ functionalized magnetic nano-microspheres have been successfully synthesized and characterized by vibrating sample magnetometer (VSM), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The specificity, reusability, and reproducibility of the nano-microspheres were investigated with the help of the specific binding of rosiglitazone to PPAR-γ. In addition, the incubation temperature and the pH of the buffer solution in the magnetic ligand fishing were optimized to improve the specific adsorption efficiency of the analytes. Finally, with the aid of ultraperformance liquid chromatography plus Q-Exactive Orbitrap tandem mass spectrometry (UHPLC-Q-Exactive Orbitrap-MS/MS), the 16 active ligands including 9 organic acids, 5 flavonoids, and 2 phenols were found in the ethanolic extracts of Choerospondias axillaris. Therefore, the study can provide a successful precedent for realizing the designated extraction and rapid isolation of target-specific active ingredient groups in the complex mixtures. 相似文献
156.
157.
158.
In this work, the lamellar structural evolution and microvoids variations of β polypropylene(β-PP) during the processing of two different stretching methods, sequential biaxial stretching and simultaneous biaxial stretching, were investigated in detail. It was found that different stretching methods led to significantly different lamellae deformation modes, and the microporous membranes obtained from the simultaneous biaxial stretching exhibited better mechanical properties. For the sequential biaxial stretching, abundant coarse fibers originated from the tight accumulation of the lamellae parallel to the longitudinal stretching direction, whereas the lamellae perpendicular to the stretching direction were easily deformed and separated. Those coarse fibers were difficult to be separated to form micropores during the subsequent transverse stretching process, resulting in a poor micropores distribution. However, for the simultaneous biaxial stretching, the β crystal had the same deformation mode, that is, the lamellae distributed in different directions were all destroyed, forming abundant microvoids and little coarse fibers. 相似文献
159.
纳米-微米复合孔泡沫陶瓷固定化脂肪酶 总被引:2,自引:0,他引:2
考察了泡沫陶瓷的孔径分布和表面性质对脂肪酶固定化的影响.研究表明,泡沫陶瓷的纳米孔孔径分布非常适合脂肪酶的固定化,对固定化酶的催化效率有决定性的影响.经1h的定化,泡沫陶瓷固定化酶的活性达商业化硅藻土固定化酶的1.33倍,体积活力为其2.63倍,蛋白载量为45.36mg/g陶瓷,比活为1215.39U/g,活力回收为41.2%.泡沫陶瓷固定化脂肪酶在有机相乙酸乙酯合成中表现优良,连续使用5次,每次反应3h,乙酸转化率均在93%左右. 相似文献
160.
中空石墨碳材料作为电催化剂载体在直接乙醇燃料电池中的应用 总被引:1,自引:0,他引:1
以间苯二酚、苯酚与甲醛为前体,合成了一种中空石墨碳材料(hollow graphitic carbon,HGC).透射电镜(TEM)、N2吸附-脱附和Raman光谱测试结果表明,所制备的HGC为中孔结构,平均孔径为36nm.与商品Vulcan XC-72R相比,HGC中孔结构丰富,石墨化程度高.分别以HGC和XC-72R为载体制备了总金属载量为45%的PtSn/C电催化剂,X射线衍射和TEM结果表明这两个样品的平均粒径和晶格常数相近.单池性能测试表明,以45%PtSn/HGC为阳极催化剂的直接乙醇燃料电池的最大功率密度达到了62mW/cm2,与PtSn/XC-72R的54mW/cm2相比提高了近15%. 相似文献