Kinetics-driven growth of orthogonally branched single-crystalline magnesium oxide nanostructures

Orthogonally branched single-crystalline magnesium oxide nanostructures were synthesized through a simple chemical vapor transport and condensation process in a flowing Ar/O(2) atmosphere. Other morphologies, such as cubes and nanowires, can also be obtained under different controlled conditions. The formation of different types of nanostructures can be tuned by modifying oxygen partial pressure during the synthesis. All the nanostructures are cubic single-crystalline enclosed by low-index {100} facets. Growth mechanisms for the nanostructures are discussed in detail: different supersaturation ratios, relatively high substrate temperatures, and surface defects in certain crystallographic planes cooperatively take important effects on determining the product morphologies. Structural defect-related blue light emission of the three types of MgO nanostructures was investigated. The MgO nanostructures with abundant morphologies may find applications in various nanodevices, and the kinetics-driven methodology might be exploited to synthesize similar nanostructures of other functional oxide materials.     

Stereoselective Synthesis of Phenyl-1,2,3-triazoles Containing (E)-Vinyl Halide Group via a One-Pot,Three-Component Reaction

Phenyl-1,2,3-triazoles containing (E)-vinyl halide were readily synthesized via a one-pot, three-component reaction of 3-(4- or 2-azidophenyl)acrylic acid, NXS(X=Cl, Br and I) and 1-alkynes in MeCN-H₂O (9:1 v/v) catalyzed by LiOAc/CuI–sodium ascorbate system.

大气湍流外尺度对倾斜跟踪系统跟踪精度的影响

从G倾斜功率谱和倾斜跟踪残余误差两个方面分析了大气湍流外尺度对倾斜跟踪系统跟踪精度的影响。详细推导了G倾斜功率谱以及倾斜跟踪残差与大气湍流外尺度的函数关系式。数值计算结果表明大气湍流外尺度对G倾斜功率谱以及倾斜跟踪残余误差的低频段影响较大,而对高频段的影响可以忽略不计。     

Modal wavefront reconstruction for radial shearing interferometer with lateral shear

In a radial shearing interferometer, a portion of the test beam is magnified and used as the reference for the tested wavefront. However, the reference portion is always off center (lateral shear), which complicates the wavefront reconstruction. A modal method for solving this problem is presented here. This method uses orthogonal Zernike polynomials and its matrix formalism to calculate the Zernike coefficient of the wavefront under test. This approach has easier implementation, is better filtering, and has a more adaptive practical situation. The corresponding mathematical formula is deduced, and a computer simulation is also made to verify operation of the algorithm. The result of simulation analysis shows that the proposed method is correct and accurate.     

Binary Level Set Methods for Dynamic Reservoir Characterization by Operator Splitting Scheme

In this paper, operator splitting scheme for dynamic reservoir characterization by binary level set method is employed. For this problem, the absolute permeability of the two-phase porous medium flow can be simulated by the constrained augmented Lagrangian optimization method with well data and seismic time-lapse data. By transforming the constrained optimization problem in an unconstrained one, the saddle point problem can be solved by Uzawas algorithms with operator splitting scheme, which is based on the essence of binary level set method. Both the simple and complicated numerical examples demonstrate that the given algorithms are stable and efficient and the absolute permeability can be satisfactorily recovered.     

金属参与的正电子放射性药物的合成进展

随着正电子发射断层显像技术的高速发展,正电子放射性药物的合成近年来已成为药物合成领域的热点之一.本文综述了金属参与的放射性同位素标记药物及中间体的合成方法,反应类型包括Stille偶联反应、Suzuki偶联反应、Heck偶联反应、Sonogashira偶联反应、羰基化反应、金属-卤素置换反应和点击反应等.     

ZnS∶Cu水溶胶的光致发光研究

研究了硫脲和硫代硫酸钠体系中ＺｎＳ∶Ｃｕ 纳米微粒的光致发光性能随Ｃｕ＋ 离子掺杂浓度及生长时间的变化． 在３２５ｎｍ 的紫外光激发下, ＺｎＳ∶Ｃｕ 纳米微粒产生位于５００～５４０ｎｍ 的宽带发射, Ｃｕ＋ 掺杂浓度为０．６％ 时发射达到最强． 该发射峰随掺杂浓度的提高和微粒生长时间的延长而红移; 当Ｃｕ＋ 掺杂浓度为０．２％ 时, ＺｎＳ∶Ｃｕ 纳米微粒还产生一个位于４５０ｎｍ 的蓝色发射带, 该发射在掺杂浓度更高时被猝灭． 硫脲和硫代硫酸钠体系中ＺｎＳ∶Ｃｕ 的发光性质较为相似, 但后者的发射强度明显高于前者．     

7-安替吡啉偶氮-8-羟基喹啉-5-磺酸与钪的显色反应

本文研究了7-安替吡啉偶氮-8-羟基喹啉-5-磺酸（AQS）与钪（Ⅲ）的显色反应。在高酸度下该试剂与钪（Ⅲ）所成配合物具有较好的选择性,其最大吸收波长在490nm处,摩尔吸光系数为1.37×104 L·ctn-1·mol-1,Sc2O3含量在2.5μg～40μg/25mL范围内符合比尔定律。100倍的镧和30倍的