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131.
空穴传输基团修饰的吡嗪铱配合物的合成及其发光性质 总被引:1,自引:0,他引:1
设计合成了空穴传输性咔唑基团修饰的吡嗪配体, 2,3-二(4-(9-咔唑基甲基)苯基)-5-甲基吡嗪(CzMPMP)及其铱配合物Ir(CzMPMP)2(acac)(acac: 乙酰丙酮). 用核磁共振(NMR)、质谱、元素分析等方法对其进行了表征, 并用紫外-可见吸收光谱、液相和固相光致发光光谱对其光学性质进行了研究. 通过与没有咔唑取代基的2,3-二苯基-5-甲基吡嗪铱配合物Ir(DPMP)2(acac)进行对照, 说明咔唑基团对配合物的光学性质有显著影响. 不含咔唑取代基的配合物Ir(DPMP)2(acac)的固态光致发光光谱中存在很强的激活双体(excimer)峰, 而Ir(CzMPMP)2(acac)的固态光致发光光谱中未发现有激活双体峰; 并且在溶液中, 含有咔唑取代基的配合物Ir(CzMPMP)2(acac)较Ir(DPMP)2(acac)的光致发光强度有显著提高. 这些结果说明咔唑基团的空间位阻可以有效阻止配合物成膜时产生激活双体, 从而消除发射峰红移现象并提高发光效率. 相似文献
132.
WU HaiTao LU XiaoChun ZOU DeCai & HAN Tao National Time Service Center Chinese Academy of Sciences Xi'an China Key Laboratory of Precision Navigation Timing Technology 《中国科学:物理学 力学 天文学(英文版)》2011,(6)
Navigation augmentation technology is one of the most common methods to increase the continuity,reliability and integrity of the global satellite navigation system.The concept of volunteer augmentation navigation (VNA) is proposed and the elements and topological structure of VNA are also analyzed in this paper.The study focuses on the neural network model that volunteers and ordinary users use modern communication information network to exchange self-organizing information.The neural cell model of Voluntee... 相似文献
133.
ZHOU ShanShi HU XiaoGong WU Bin LIU Li QU WeiJing GUO Rui HE Feng CAO YueLing Wu XiaoLi ZHU LingFeng SHI Xin & TAN HongLi Shanghai Astronomical Observatory Chinese Academy of Sciences Shanghai China Graduate University of Chinese Academy of Sciences Beijing Beijing Global Information Application Development Center Beijing 《中国科学:物理学 力学 天文学(英文版)》2011,(6)
Aiming at regional services,the space segment of COMPASS (Phase I) satellite navigation system is a constellation of Geostationary Earth Orbit (GEO),Inclined Geostationary Earth Orbit (IGSO) and Medium Earth Orbit (MEO) satellites.Precise orbit determination (POD) for the satellites is limited by the geographic distribution of regional tracking stations.Independent time synchronization (TS) system is developed to supplement the regional tracking network,and satellite clock errors and orbit data may be obtai... 相似文献
134.
YANG YuJuan & YAN Biao School of Materials Science Engineering Tongji University Shanghai China Shanghai Key Lab of Development Application for Metal Functional Materials 《中国科学:物理学 力学 天文学(英文版)》2011,(5)
With the multi-phase field model, the unidirectional solidification with constant velocity growth and variable velocity growth of the CBr4-C2Cl6 eutectic alloy is simulated in three dimensions. The simulated results with constant velocity growth show that with the increase of pulling velocity, the morphology of the CBr4-C2Cl6 alloy evolves in the sequence of lamellar merging →lamellar-rod transition→stable lamellar growth→oscillating growth→lamellar branching. A morphology selection map is established with ... 相似文献
135.
CHEN RunFeng MA Cong PAN JingFang ZHENG Chao & HUANG Wei Key Laboratory for Organic Electronics & Information Displays 《中国科学:物理学 力学 天文学(英文版)》2011,(5)
The electronic structures and optical properties of oligothiophene substituted spirofluorenes are investigated theoretically with semi-empirical quantum chemical calculations. A theoretical investigation of the interaction between two perpendicular π-systems of various oligothiophene substituted spirofluorenes is conducted. The results demonstrate that the interaction between two perpendicular branches is reduced by oligothiophene substitutions. Photoexcitation induced relaxation is mainly located on one of... 相似文献
136.
HAO Liang & LONG GuiLu Key Laboratory for Atomic Molecular NanoSciences 《中国科学:物理学 力学 天文学(英文版)》2011,(5)
In this work, we demonstrated a fixed-point quantum search algorithm in the nuclear magnetic resonance (NMR) system. We constructed the pulse sequences for the pivotal operations in the quantum search protocol. The experimental results agree well with the theoretical predictions. The generalization of the scheme to the arbitrary number of qubits has also been given. 相似文献
137.
Modelling of multi-bodies in close proximity under water waves——Fluid resonance in narrow gaps 总被引:1,自引:0,他引:1
LU Lin TENG Bin CHENG Liang SUN Liang & CHEN XiaoBo Center for Deepwater Engineering Dalian University of Technology Dalian China State Key Laboratory of Structural Analysis for Industrial Equipment State Key Laboratory of Coastal Offshore Engineering School of Civil Resource Engineering The University of Western Australia Crawly Australia Centre for Offshore Research... 《中国科学:物理学 力学 天文学(英文版)》2011,(1)
Viscous fluid model and potential flow model with and without artificial damping force(f=-μV,μ the damping coefficient and V the local averaging flow velocity) are employed in this work to investigate the phenomenon of fluid resonance in narrow gaps between multi-bodies in close proximity under water waves.The numerical results are compared with experimental data available in the literature.The comparison demonstrates that both the viscous fluid model and the potential flow model are able to predict the res... 相似文献
138.
LONG LiuRong LI HongWei ZHOU Ping FAN Chao & YIN CaiLiu College of Physics Electronic Engineering Guangxi University for Nationalities Nanning China 《中国科学:物理学 力学 天文学(英文版)》2011,(3)
We present a scheme for multiparty-controlled teleportation of an arbitrary high-dimensional GHZ-class state with a d-dimensional (N+2)-particle GHZ state following some ideas from the teleportation (Chinese Physics B, 2007, 16: 2867). This scheme has the advantage of transmitting much fewer particles for controlled teleportation of an arbitrary multiparticle GHZ-class state. Moreover,we discuss the application of this scheme by using a nonmaximally entangled state as its quantum channel. 相似文献
139.
The accumulation effects in high-reflectivity(HR) HfO2/SiO2 coatings under laser irradiation are investigated.The HR HfO2/SiO2 coatings are prepared by electron beam evaporation at 1 064 nm.The laser-induced damage threshold(LIDT) are measured at 1 064 nm and at a pulse duration of 12 ns,in 1-on-1 and S-on-1 modes.Multi-shot LIDT is lower than single-shot LIDT.The laser-induced and native defects play an important role in the multi-shot mode.A correlative theory model based on critical conduction band electron density is constructed to elucidate the experimental phenomena. 相似文献
140.
Using differential detection,we perform polarization-multiplexing 160-Gb/s optical non-return-to-zero(NRZ) differential quadrature phase shift keying(DQPSK) signal transmission over 100-km standard single mode fiber at a bit error rate(BER) of less than 10-9.The enabling technology includes clock recovery,fine dispersion compensation,and polarization tracking for de-multiplexing.Furthermore,a hybrid clock recovery scheme is proposed.The scheme is realized with ordinary devices using an optoelectrical modula... 相似文献