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121.
M. Terrones P.M. Ajayan F. Banhart X. Blase D.L. Carroll J.C. Charlier R. Czerw B. Foley N. Grobert R. Kamalakaran P. Kohler-Redlich M. Rühle T. Seeger H. Terrones 《Applied Physics A: Materials Science & Processing》2002,74(3):355-361
Self-assembly pyrolytic routes to large arrays (<2.5 cm2) of aligned CNx nanotubes (15–80 nm OD and <100 μm in length) are presented. The method involves the thermolysis of ferrocene/melamine mixtures
(5:95) at 900–1000 °C in the presence of Ar. Electron energy loss spectroscopy (EELS) reveals that the N content varies from
2–10%, and can be bonded to C in two different fashions (double-bonded and triple-bonded nitrogen). The electronic densities
of states (DOS) of these CNx nanotubes, using scanning tunneling spectroscopy (STS), are presented. The doped nanotubes exhibit strong features in the
conduction band close to the Fermi level (0.18 eV). Using tight-binding and ab initio calculations, we confirm that pyridine-like
(double-bonded) N is responsible for introducing donor states close to the Fermi Level. These electron-rich structures are
the first example of n-type nanotubes. Finally, it will be shown that moderate electron irradiation at 700–800 °C is capable
of coalescing single-walled nanotubes (SWNTs). The process has also been studied using tight-binding molecular dynamics (TBMD).
Vacancies induce the coalescence via a zipper-like mechanism, which has also been observed experimentally. These vacancies
trigger the organization of atoms on the tube lattices within adjacent tubes. These results pave the way to the fabrication
of nanotube heterojunctions, robust composites, contacts, nanocircuits and strong 3D composites using N-doped tubes as well
as SWNTs.
Received: 10 October 2001 / Accepted: 3 December 2001 / Published online: 4 March 2002 相似文献
122.
J. J. Carroll J. Burnett T. Drummond J. Lepak R. Propri D. Smith S. A. Karamian J. Adam F. Stedile F. J. Agee 《Hyperfine Interactions》2002,143(1-4):37-54
Experiments with the long-lived, high-K isomer 178Hfm2 have been recognized as intriguing tests of multi-quasiparticle state structures and their interactions with external radiation.
A triggered release of the energy stored by this isomer, 2.5 MeV per nucleus or 1.2 GJ/gram, in the form of a gamma-ray burst
might prove valuable for numerous applications. The observation of “accelerated” decay of 178Hfm2 during irradiation by 90-keV bremsstrahlung has already been reported, but with poor statistical accuracy due to the experimental
approach. That approach employed single Ge detectors to seek increases in the areas of peaks at energies corresponding to
transitions in the spontaneous decay of the isomer. The need for better quality data to confirm those results has motivated
the development of improved detection concepts. One such concept was utilized here to perform an initial search for low-energy
(<20 keV) triggered gamma emission from 178Hfm2 using the YSU miniball detector array.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
123.
The triggering of long-lived isomeric nuclei by non-radiative excitation to a relatively short-lived mediating state is considered.
Coulomb triggering in inelastic scattering of heavy ions, a transfer of triggering energy from resonant electron transitions
of atomic shell (NEET) and triggering by capture of a free electron into a bound atomic state (NEEC) are discussed. Cross
sections for the above processes of non-radiative triggering are presented and the relative efficiencies of these different
triggering mechanisms are discussed. Numerical estimates are presented for the selected isomers.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
124.
Bottorff JL Blaine S Carroll JC Esplen MJ Evans J Nicolson Klimek ML Meschino W Ritvo P 《Community genetics》2005,8(2):80-87
OBJECTIVE: To investigate the knowledge, professional involvement and confidence of Canadian nurses and physicians in providing genetic services for adult onset hereditary disease. METHODS: 1,425 physicians and 1,425 nurses received a mailed questionnaire with reminders. The response rates were 50% (n = 543) and 79% (n = 975), respectively. RESULTS: Forty-eight percent of physicians and 31% of nurses lacked formal education in genetics. Respondents reported being involved in caring for people at risk for adult onset hereditary disease. Their levels of confidence that they could perform tasks, such as counselling about predictive genetic tests, however, were lower than their levels of expectation that it would be important for them to provide these services. CONCLUSIONS: The expected roles and educational needs of Canadian nurses and physicians have broad areas of overlap suggesting the possibility of combined professional education programs and multiple ways of organizing teams to provide genetic services to people at risk for adult onset hereditary disease. 相似文献
125.
Finite strain solutions in compressible isotropic elasticity 总被引:6,自引:0,他引:6
M. M. Carroll 《Journal of Elasticity》1988,20(1):65-92
Three classes of compressible isotropic elastic solids are introduced, for each of which the strain energy, expressed as a function of the three principal invariants of the stretch tensors, is linear in two of its arguments and nonlinear in the third argument. One of these is the class of harmonic materials. Several deformation fields are examined, for which the governing equations, for general compressible isotropic elastic response, reduce to a nonlinear ordinary differential equation. For the three special classes of materials, this differential equation may be solved in closed form, giving a deformation field which is independent of the material response function, or its solution may be reduced to a single quadrature, involving the nonlinear material response function. 相似文献
126.
Julianne C. Griepenburg Teresa L. Rapp Patrick J. Carroll James Eberwine Ivan J. Dmochowski 《Chemical science》2015,6(4):2342-2346
Photochemical approaches afford high spatiotemporal control over molecular structure and function, for broad applications in materials and biological science. Here, we present the first example of a visible light responsive ruthenium-based photolinker, Ru(bipyridine)2(3-ethynylpyridine)2 (RuBEP), which was reacted stoichiometrically with a 25mer DNA or morpholino (MO) oligonucleotide functionalized with 3′ and 5′ terminal azides, via Cu(i)-mediated [3+2] Huisgen cycloaddition reactions. RuBEP-caged circular morpholinos (Ru-MOs) targeting two early developmental zebrafish genes, chordin and notail, were synthesized and tested in vivo. One-cell-stage zebrafish embryos microinjected with Ru-MO and incubated in the dark for 24 h developed normally, consistent with caging, whereas irradiation at 450 nm dissociated one 3-ethynylpyridine ligand (Φ = 0.33) and uncaged the MO to achieve gene knockdown. As demonstrated, Ru photolinkers provide a versatile method for controlling structure and function of biopolymers. 相似文献
127.
M. M. Carroll 《Journal of Elasticity》1977,7(4):411-424
A plane standing wave solution is obtained for homogeneous, isotropic, incompressible nonlinearly elastic solids. The motion describes the nonlinear interaction of two oppositely propagating, circularly polarized waves. It is used to obtain exact steady state solutions for nonlinear vibrations of a plate and for reflection and transmission of finite amplitude, circularly polarized waves at a plane interface. 相似文献
128.
Gichinga MG Olson JP Butala E Gilmour BP Navarro HH Carroll FI 《Tetrahedron letters》2011,52(26):3345-3346
Procedures for the synthesis of thirty-six 5-methyl-3-(substituted)-[1,2,4]triazines have been described. These compounds were evaluated for antagonism at metabotropic glutamate receptor subtype 5 (mGluR5). Two compounds, 5b and 3c, were determined to be low micromolar inhibitors of mGluR5. 相似文献
129.
A concise stereoselective route to the dysiherbaine tetrahydropyran core was achieved in nine steps and 39% overall yield. Donohoe’s improved tethered aminohydroxylation conditions were employed to concurrently install the amino and alcohol groups and construct the tetrahydropyran ring, which features four contiguous cis-stereocenters. 相似文献
130.
We consider the problem of testing for a constant nonparametric effect in a general semiparametric regression model when there is a potential for interaction between the parametrically and nonparametrically modeled variables. The work was originally motivated by a unique testing problem in genetic epidemiology (Chatterjee et al., 2006) that involved a typical generalized linear model but with an additional term reminiscent of the Tukey 1-degree-of-freedom formulation, and their interest was in testing for main effects of the genetic variables, while gaining statistical power by allowing for a possible interaction between genes and the environment. Later work (Maity et al., 2009) involved the possibility of modeling the environmental variable nonparametrically, but they focused on whether there was a parametric main effect for the genetic variables. In this paper, we consider the complementary problem, where the interest is in testing for the main effect of the nonparametrically modeled environmental variable. We derive a generalized likelihood ratio test for this hypothesis, show how to implement it, and provide evidence that our method can improve statistical power when compared to standard partially linear models with main effects only. We use the method for the primary purpose of analyzing data from a case-control study of colorectal adenoma. 相似文献