ICP-MS法测定不同采收时间宽叶荨麻中微量元素含量

采用微波消解,ICP-MS法分析不同采收时间宽叶荨麻中18种微量元素Al,Ba,Ca,Co,Cr,Cu,Fe,K,Li,Mg,Mn,Mo,Na,Ni,P,Pb,S和Zn的含量。该方法的相对标准偏差在1.2%～5.3%之间,加标回收率在95.4%～101.2%之间。结果表明宽叶荨麻中K,P,S,Ca,Na含量较高;Fe,Mg,Mn,Zn含量次之;有潜在生理毒性的元素Al,Cr,Pb的含量较低,并且在宽叶荨麻中微量元素呈现明显的季节性动态变化,此结果为进一步研究宽叶荨麻药理药效与微量元素的关系以及更好的开发这一资源提供理论数据。     

拱形激光二极管侧抽运Nd:YAG固体激光器的实验研究

详细阐述了同心抽运、同心冷却的激光二极管紧包侧抽运Nd：YAG激光器的实验研究工作。这种抽运结构使晶体内的增益场与谐振腔基模实现了良好的匹配,易于得到良好的光束质量和大能量输出,基模提取效率高。模拟分析了晶体内的增益场以及横截面内的温度分布,从不同角度探讨了激光二极管的温度特性对器件工作的影响。研究了晶体的热致退偏效应对器件调Q工作的影响．并且初步探讨了不同腔长、不同腔型下器件的工作情况,这些实验结果对进一步优化使用这种抽运结构有指导意义。所设计的激光器在工作频率6Hz时．得到了斜效率为44．3％的多模调Q输出。在抽运能量735mJ时,得到最大输出能量135mJ,脉宽7．6ns的调Q脉冲,光光效率为18．4％,插头效率为11．0％,光束发散角小于1．5mrad。     

Spectroscopy of stripe order in La1.8Sr0.2NiO4 using resonant soft x-ray diffraction

Strong resonant enhancements of the charge-order and spin-order superstructure-diffraction intensities in La1.8Sr0.2NiO4 are observed when x-ray energies in the vicinity of the Ni L2,3 absorption edges are used. The pronounced photon-energy and polarization dependences of these diffraction intensities allow for a critical determination of the local symmetry of the ordered spin and charge carriers. We found that not only the antiferromagnetic order but also the charge-order superstructure resides within the NiO2 layers; the holes are mainly located on in-plane oxygens surrounding a Ni2+ site with the spins coupled antiparallel in close analogy to Zhang-Rice singlets in the cuprates.     

Local trimer orbital ordering in LiNiO2 studied by quantitative convergent beam electron diffraction technique

A local trimer orbital ordering model of LiNiO₂ was studied by means of theoretical calculation and experimental measurement of electron structure factors. Based on the trimer model, the electron structure factors were calculated by using the scattering factor of non-spherical Ni³⁺ ion. From these results, it is found that the effect of local orbital ordering on the electron structure factors of several subtle reflections, such as (202) and (107), is very large. The electron structure factors of these subtle reflections were measured by quantitative convergent beam electron diffraction method. The experimentally measured electron structure factor values of these reflections indicate that the trimer orbital ordering model is more close to the true structure of LiNiO₂.     

Use of hyperpolarized [1-C]pyruvate and [2-C]pyruvate to probe the effects of the anticancer agent dichloroacetate on mitochondrial metabolism in vivo in the normal rat

Development of hyperpolarized technology utilizing dynamic nuclear polarization has enabled the measurement of ¹³C metabolism in vivo at very high signal-to-noise ratio (SNR). In vivo mitochondrial metabolism can, in principle, be monitored with pyruvate, which is catalyzed to acetyl-CoA via pyruvate dehydrogenase (PDH). The purpose of this work was to determine whether the compound sodium dichloroacetate (DCA) could aid the study of mitochondrial metabolism with hyperpolarized pyruvate. DCA stimulates PDH by inhibiting its inhibitor, pyruvate dehydrogenase kinase. In this work, hyperpolarized [1-¹³C]pyruvate and [2-¹³C]pyruvate were used to probe mitochondrial metabolism in normal rats. Increased conversion to bicarbonate (+ 181±69%, P=.025) was measured when [1-¹³C]pyruvate was injected after DCA administration, and increased glutamate (+ 74±23%, P=.004), acetoacetate (+ 504±281%, P=.009) and acetylcarnitine (+ 377±157%, P=.003) were detected when [2-¹³C]pyruvate was used.     

准相位型光子筛设计

提出了一种准相位型光子筛。该准相位型光子筛通过改变暗环上小孔直径与带宽的比值,对焦点处的相位分布进行调制,使通过亮环和暗环上小孔的光波在焦点处发生相长干涉,生成聚焦光斑。该准相位型光子筛无需对基底进行特殊处理,即可完成相位型光子筛的制作,降低了加工难度。和普通振幅型光子筛相比,在相同最小加工尺寸的条件下,准相位型光子筛具有较大的数值孔径,可降低聚焦光斑尺寸。并且,和多区光子筛相比,在同样的最小加工尺寸及数值孔径的条件下,准相位型光子筛光斑尺寸及质量均优于对方。为大数值孔径光子筛设计提供了一种新的设计方法。     

长腰内锥流量计的特性研究

内锥式流量计在多相流测量中的应用逐渐受到广大多相流研究工作者的重视。针对内锥式流量计在多相流测量中存在的一些问题,提出一种新型的环形通道式差压流量计—长腰内锥流量计。通过理论推导得出流量方程及永久压损与流量的关系式,并通过在水相、油相、气相条件下的标定实验,定量分析流出系数与永久压损等特性。结果表明:在长腰内锥体腰部取低压可以在保证差压信号幅值的情况下提高其稳定性、重复性;长腰内锥流量计节流件的轮廓及固定方式可以显著地减小永久压损。为后期开发新型多相流测量仪器提供理论依据与设计基础。     

Measurement of the parity-violating asymmetry in inclusive electroproduction of π- near the Δ0 resonance

The parity-violating (PV) asymmetry of inclusive π- production in electron scattering from a liquid deuterium target was measured at backward angles. The measurement was conducted as a part of the G0 experiment, at a beam energy of 360 MeV. The physics process dominating pion production for these kinematics is quasifree photoproduction off the neutron via the Δ0 resonance. In the context of heavy-baryon chiral perturbation theory, this asymmetry is related to a low-energy constant d(Δ)- that characterizes the parity-violating γNΔ coupling. Zhu et al. calculated d(Δ)- in a model benchmarked by the large asymmetries seen in hyperon weak radiative decays, and predicted potentially large asymmetries for this process, ranging from A(γ)-=-5.2 to +5.2 ppm. The measurement performed in this work leads to A(γ)-=-0.36±1.06±0.37±0.03 ppm (where sources of statistical, systematic and theoretical uncertainties are included), which would disfavor enchancements considered by Zhu et al. proportional to V(ud)/V(us). The measurement is part of a program of inelastic scattering measurements that were conducted by the G0 experiment, seeking to determine the N-Δ axial transition form factors using PV electron scattering.     

Tunable self-shifting Bloch modes in anisotropic hexagonal photonic lattices

We study controllable self-shifting Bloch modes in anisotropic hexagonal photonic lattices. The shifting results from a deformed band structure due to deformation of the index distribution in each unit cell. By reconfiguration of the index profile of the unit cell, the direction in which the Bloch modes move can be controlled. Our theoretical predictions are experimentally demonstrated in hexagonal lattices optically induced in an anisotropic nonlinear crystal.